The explosion of silver azide in an electric field
Recently McLaren & Rogers (1957) reported that silver azide could be made to explode if placed between two electrodes and an electric field of ca . 250 V/cm applied. In an attempt to determine the nature of the process of the initiation of explosion, a preliminary study of the conductivity of single crystals of silver azide has been made. The current has been measured as a function of time for a constant field, and as a function of field strength at temperatures from 50 °C down to -100 °C. Measurements have also been made of the time to explosion as a function of the frequency of the applied field. The results suggest that the breakdown is due to field emission from the cathode, and that electrons may enter the crystal with sufficient energy to produce decomposition, followed by self-heating and explosion.