Mutarotation of some biologically important 2-substituted hexoses
1974 ◽
Vol 337
(1610)
◽
pp. 317-332
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Keyword(s):
Catalysis by water, hydronium ion, acetate ion, acetic acid, pyridine and 3-hydroxypyridine of the mutarotation of D-glucose, 2-deoxy-D-glucoso, 2-amino-2-deoxy-D-glucose and 2-acetamido-2-deoxy-n-glucose has been studied polarimetrically. Rate constants were measured at 298 and 308 K and the thermodynamic activation parameters have been calculated for each case. It is concluded that the mutarotation reaction probably takes place by a concerted mechanism in which two or more water molecules are involved in the transition state.
Kinetic Studies of [4n+2]π-Thermal Cyclodimerization of 1-(3-Pyridazinyl)-3-oxidopyridinium Betaines
1992 ◽
Vol 57
(9)
◽
pp. 1951-1959
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1993 ◽
Vol 58
(8)
◽
pp. 1777-1781
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1979 ◽
Vol 44
(12)
◽
pp. 3588-3594
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Keyword(s):
1979 ◽
Vol 44
(4)
◽
pp. 1052-1059
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2005 ◽
Vol 04
(04)
◽
pp. 1101-1117
◽
Keyword(s):