Trace gas flux measurements at the landscape scale using boundary-layer budgets

1995 ◽  
Vol 351 (1696) ◽  
pp. 357-369 ◽  
Keyword(s):  
Boundary Layer ◽  
Local Area ◽  
Surface Fluxes ◽  
Trace Gas ◽  
Significant Heterogeneity ◽  
Methane Fluxes ◽  
Flux Measurements ◽  
The Mean ◽  
Nocturnal Inversion ◽  
One Year

Methane effluxes from wetland areas of Scotland were estimated by using the boundary-layer budget method by collecting air samples with an aircraft upwind and downwind of an area of extensive peatland. Nocturnal local area methane fluxes were also estimated at a peat bog site, Loch More, located at 58° 24' N 03° 36' W, using the concentration build up under the nocturnal inversion and from profiles of methane concentration using a tethered balloon. The mean daytime flux for the Loch More case studies in 1993 was found to be 128 ± 57 μ mol m -2 h -1 for the NE region of Scotland, comparable to but generally larger than those obtained for the same region one year earlier. The fluxes are smaller than those obtained in Caithness by the same technique. In 1993 the nocturnal fluxes were found to be 38 ± 7 μ mol m -2 h -1 , significantly smaller than those found during 1992. The daytime fluxes measured by the aircraft were generally larger than fluxes measured by micrometeorological techniques at the same time. These differences can be explained in terms of the significant heterogeneity in surface fluxes that exist on scales of a few hundred metres or less and the possibility of additional sources other than peatland in this region.

scholarly journals The influence of idealized surface heterogeneity on virtual turbulent flux measurements

2018 ◽  
Vol 18 (7) ◽  
pp. 5059-5074 ◽  
Author(s):  
Frederik De Roo ◽  
Matthias Mauder
Keyword(s):  
Energy Budget ◽  
Turbulent Flux ◽  
Surface Heterogeneity ◽  
Surface Fluxes ◽  
Convective Conditions ◽  
Mean Flow ◽  
Flux Divergence ◽  
Length Scales ◽  
Flux Measurements ◽  
The Mean

Abstract. The imbalance of the surface energy budget in eddy-covariance measurements is still an unsolved problem. A possible cause is the presence of land surface heterogeneity, which affects the boundary-layer turbulence. To investigate the impact of surface variables on the partitioning of the energy budget of flux measurements in the surface layer under convective conditions, we set up a systematic parameter study by means of large-eddy simulation. For the study we use a virtual control volume approach, which allows the determination of advection by the mean flow, flux-divergence and storage terms of the energy budget at the virtual measurement site, in addition to the standard turbulent flux. We focus on the heterogeneity of the surface fluxes and keep the topography flat. The surface fluxes vary locally in intensity and these patches have different length scales. Intensity and length scales can vary for the two horizontal dimensions but follow an idealized chessboard pattern. Our main focus lies on surface heterogeneity of the kilometer scale, and one order of magnitude smaller. For these two length scales, we investigate the average response of the fluxes at a number of virtual towers, when varying the heterogeneity length within the length scale and when varying the contrast between the different patches. For each simulation, virtual measurement towers were positioned at functionally different positions (e.g., downdraft region, updraft region, at border between domains, etc.). As the storage term is always small, the non-closure is given by the sum of the advection by the mean flow and the flux-divergence. Remarkably, the missing flux can be described by either the advection by the mean flow or the flux-divergence separately, because the latter two have a high correlation with each other. For kilometer scale heterogeneity, we notice a clear dependence of the updrafts and downdrafts on the surface heterogeneity and likewise we also see a dependence of the energy partitioning on the tower location. For the hectometer scale, we do not notice such a clear dependence. Finally, we seek correlators for the energy balance ratio in the simulations. The correlation with the friction velocity is less pronounced than previously found, but this is likely due to our concentration on effectively strongly to freely convective conditions.

scholarly journals Modeling the diurnal cycle of conserved and reactive species in the convective boundary layer

2015 ◽  
Vol 8 (10) ◽  
pp. 9323-9372 ◽  
Author(s):  
D. H. Lenschow ◽  
D. Gurarie ◽  
E. G. Patton
Keyword(s):  
Boundary Layer ◽  
Planetary Boundary Layer ◽  
Chemical Reactions ◽  
Climate Models ◽  
Initial Conditions ◽  
Reactive Species ◽  
Second Order ◽  
Surface Fluxes ◽  
Great Promise ◽  
The Mean

Abstract. We have developed a one-dimensional second-order closure numerical model to study the vertical turbulent transport of trace reactive species in the convective (daytime) planetary boundary layer (CBL), which we call the Second-Order Model for Conserved and Reactive Unsteady Scalars (SOMCRUS). The temporal variation of the CBL depth is calculated using a simple mixed-layer model with a constant entrainment coefficient and zero-order discontinuity at the CBL top. We then calculate time-varying continuous profiles of mean concentrations and vertical turbulent fluxes, variances, and covariances of both conserved and chemically-reactive scalars in a diurnally-varying CBL. The set of reactive species is the O3–NO–NO2 triad. The results for both conserved and reactive species are compared with large-eddy simulations (LES) for the same free-convection case using the same boundary and initial conditions. For the conserved species, we compare three cases with different combinations of surface fluxes, and CBL and free-troposphere concentrations. We find good agreement of SOMCRUS with LES for the mean concentrations and fluxes of both conserved and reactive species except near the CBL top, where SOMCRUS predicts a somewhat shallower depth, and has sharp transitions in both the mean and turbulence variables, in contrast to more smeared out variations in the LES due to horizontal averaging. Furthermore, SOMCRUS generally underestimates the variances and species-species covariances. SOMCRUS predicts temperature-species covariances similar to LES near the surface, but much smaller magnitude peak values near the CBL top, and a change in sign of the covariances very near the CBL top, while the LES predicts a change in sign of the covariances in the lower half of the CBL. SOMCRUS is also able to estimate the intensity of segregation (the ratio of the species-species covariance to the product of their means), which can alter the rates of second-order chemical reactions; however, for the case considered here, this effect is small. The simplicity and extensibility of SOMCRUS means that it can be utilized for a broad range of turbulence mixing scenarios and sets of chemical reactions in the planetary boundary layer; it therefore holds great promise as a tool to incorporate these processes within air quality and climate models.

scholarly journals Constraining regional greenhouse gas emissions using geostationary concentration measurements: a theoretical study

2014 ◽  
Vol 7 (2) ◽  
pp. 1367-1392 ◽  
Author(s):  
P. J. Rayner ◽  
S. R. Utembe ◽  
S. Crowell
Keyword(s):  
Theoretical Study ◽  
Regional Scale ◽  
Surface Fluxes ◽  
Trace Gas ◽  
Science And Policy ◽  
Maximum Resolution ◽  
Methane Fluxes ◽  
Gas Measurements ◽  
Urban Emissions ◽  
East West

Abstract. We investigate the ability of column-integrated trace gas measurements from a geostationary satellite to constrain surface fluxes at regional scale. The proposed geoCARB instrument measures CO2, CO and CH4 at a maximum resolution of 3 km east–west × 2.7 km north–south. Precisions are 3 ppm for CO2, 10 ppb for CO and 18 ppb for CH4. Sampling frequency is flexible. Here we sample a region at the location of Shanghai every 2 daylight hours for 6 days in June. We test the observing system by calculating the posterior uncertainty covariance of fluxes. We are able to constrain urban emissions at 3 km resolution including an isolated power-plant. The CO measurement plays the strongest role; without it our effective resolution falls to 5 km. Methane fluxes are similarly well-estimated at 5 km resolution. Estimating the errors for a full year suggests such an instrument would be a useful tool for both science and policy applications.

scholarly journals Areal-averaged trace gas emission rates from long-range open-path measurements in stable boundary layer conditions

2012 ◽  
Vol 5 (1) ◽  
pp. 1459-1496 ◽  
Author(s):  
K. Schäfer ◽  
R. H. Grant ◽  
S. Emeis ◽  
A. Raabe ◽  
C. von der Heide ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Land Surface ◽  
Stable Boundary Layer ◽  
Gradient Methods ◽  
Trace Gas ◽  
Emission Rates ◽  
Stable Boundary ◽  
Flux Gradient ◽  
Surface Emission ◽  
Flux Measurements

Abstract. Measurements of land-surface emission rates of greenhouse and other gases at large spatial scales (10 000 m2) are needed to assess the spatial distribution of emissions. This can be more readily done using spatial-integrating micro-meteorological methods than the widely-utilized small chamber measurements. Several micro-meteorological flux-gradient methods utilizing a non-intrusive path-averaging measurement method were evaluated for determining land-surface emission rates of trace gases under stable boundary layers. Successful application of a flux-gradient method requires confidence in the gradients of trace gas concentration and wind and in the applicability of boundary-layer turbulence theory. While there is relatively high confidence in flux measurements made under unstable atmospheres with mean winds greater than 1 m s−1, there is greater uncertainty in flux measurements made under free convective or stable conditions. The study involved quality-assured determinations of fluxes under low wind, stable or night-time atmospheric conditions when the continuous "steady-state" turbulence of the surface boundary layer breaks down and the layer has intermittent turbulence. Results indicate that the Monin-Obukhov similarity theory (MOST) flux-gradient methods that assume a log-linear profile of the wind speed and concentration gradient incorrectly determine vertical profiles and thus fluxes in the stable boundary layer.

scholarly journals Constraining regional greenhouse gas emissions using geostationary concentration measurements: a theoretical study

2014 ◽  
Vol 7 (10) ◽  
pp. 3285-3293 ◽  
Author(s):  
P. J. Rayner ◽  
S. R. Utembe ◽  
S. Crowell
Keyword(s):  
Theoretical Study ◽  
Regional Scale ◽  
Surface Fluxes ◽  
Trace Gas ◽  
Science And Policy ◽  
Maximum Resolution ◽  
Methane Fluxes ◽  
Gas Measurements ◽  
Urban Emissions ◽  
East West

Abstract. We investigate the ability of column-integrated trace gas measurements from a geostationary satellite to constrain surface fluxes at regional scale. The proposed GEOCARB instrument measures CO2, CO and CH4 at a maximum resolution of 3 km east–west × 2.7 km north–south. Precisions are 3 ppm for CO2, 10 ppb for CO and 18 ppb for CH4. Sampling frequency is flexible. Here we sample a region at the location of Shanghai every 2 daylight hours for 6 days in June. We test the observing system by calculating the posterior uncertainty covariance of fluxes. We are able to constrain urban emissions at 3 km resolution including an isolated power plant. The CO measurement plays the strongest role; without it our effective resolution falls to 5 km. Methane fluxes are similarly well estimated at 5 km resolution. Estimating the errors for a full year suggests such an instrument would be a useful tool for both science and policy applications.

scholarly journals Modeling the diurnal cycle of conserved and reactive species in the convective boundary layer using SOMCRUS

2016 ◽  
Vol 9 (3) ◽  
pp. 979-996 ◽  
Author(s):  
Donald H. Lenschow ◽  
David Gurarie ◽  
Edward G. Patton
Keyword(s):  
Boundary Layer ◽  
Planetary Boundary Layer ◽  
Chemical Reactions ◽  
Climate Models ◽  
Initial Conditions ◽  
Reactive Species ◽  
Second Order ◽  
Surface Fluxes ◽  
Great Promise ◽  
The Mean

Abstract. We have developed a one-dimensional second-order closure numerical model to study the vertical turbulent transport of trace reactive species in the convective (daytime) planetary boundary layer (CBL), which we call the Second-Order Model for Conserved and Reactive Unsteady Scalars (SOMCRUS). The temporal variation of the CBL depth is calculated using a simple mixed-layer model with a constant entrainment coefficient and zero-order discontinuity at the CBL top. We then calculate time-varying continuous profiles of mean concentrations and vertical turbulent fluxes, variances, and covariances of both conserved and chemically reactive scalars in a diurnally varying CBL. The set of reactive species is the O3–NO–NO2 triad. The results for both conserved and reactive species are compared with large-eddy simulations (LES) for the same free-convection case using the same boundary and initial conditions. For the conserved species, we compare three cases with different combinations of surface fluxes, and CBL and free-troposphere concentrations. We find good agreement of SOMCRUS with LES for the mean concentrations and fluxes of both conserved and reactive species except near the CBL top, where SOMCRUS predicts a somewhat shallower depth, and has sharp transitions in both the mean and turbulence variables, in contrast to more smeared-out variations in the LES due to horizontal averaging. Furthermore, SOMCRUS generally underestimates the variances and species–species covariances. SOMCRUS predicts temperature–species covariances similar to LES near the surface, but much smaller magnitude peak values near the CBL top, and a change in sign of the covariances very near the CBL top, while the LES predicts a change in sign of the covariances in the lower half of the CBL. SOMCRUS is also able to estimate the intensity of segregation (the ratio of the species–species covariance to the product of their means), which can alter the rates of second-order chemical reactions; however, for the case considered here, this effect is small. The simplicity and extensibility of SOMCRUS means that it can be utilized for a broad range of turbulence-mixing scenarios and sets of chemical reactions in the planetary boundary layer; it therefore holds great promise as a tool to incorporate these processes within air quality and climate models.

Surface geochemical measurements applied to monitoring, verification, and accounting of leakage from sequestration projects

2015 ◽  
Vol 3 (2) ◽  
pp. SM1-SM21 ◽  
Author(s):  
Ronald W. Klusman
Keyword(s):  
Shallow Groundwater ◽  
Control Area ◽  
Surface Fluxes ◽  
Soil Gas ◽  
Inert Gases ◽  
Gas Composition ◽  
Teapot Dome ◽  
Shallow Soil ◽  
Methane Fluxes ◽  
Flux Measurements

A detailed study of [Formula: see text] and [Formula: see text] surface fluxes, shallow soil gas composition, 10-m hole soil gas composition was made at Rangely, Colorado, Teapot Dome, Wyoming, USA, and the results of geochemical verification measurements at Weyburn, Saskatchewan, Canada. Summer and winter soil gas and gas flux measurements were made at Rangely, and winter only at Teapot Dome. The objectives were to determine if leakage of [Formula: see text] and/or [Formula: see text] could be detected in the overpressured Rangely and the underpressured Teapot Dome systems. At Weyburn, the objective was the determination of the presence or absence of an alleged leak. Seasonal surface [Formula: see text] fluxes at Rangely were similar at on-field locations and an off-field control area. Methane fluxes were much higher at on-field locations than in the control area, suggesting a reservoir source. Seasonal differences in [Formula: see text] fluxes suggested methanotrophic oxidation was occurring in the soils. Shallow soil gas concentration measurements of [Formula: see text] were similar at a 100-cm depth, on-field and in the control area. Methane soil gas concentrations were higher on-field than in the control area; summer and winter. These data were used to select locations with and without evidence for seepage allowing nested sampling up to a 10-m depth. More complex chemical and isotopic measurements were made in 10-m holes at Rangely and Teapot Dome. Methanotrophy was operational at the active Rangely and the passive Teapot Dome systems. A small methane leakage rate of 400–700 tonnes [Formula: see text] and [Formula: see text] of [Formula: see text] tonnes [Formula: see text] were determined at Rangely, and rates near zero at Teapot Dome. Inert gases, carbon-containing gases, as well as isotopic ratios supported the presence of pathways at geochemically anomalous locations at Teapot Dome. Measurements of soil gas and inert gas isotopes in shallow groundwater by other authors at Weyburn, Saskatchewan, found no evidence of leakage.

scholarly journals Evaluation of Boundary Layer Depth Estimates at Summit Station, Greenland

2013 ◽  
Vol 52 (10) ◽  
pp. 2356-2362 ◽  
Author(s):  
B. Van Dam ◽  
D. Helmig ◽  
W. Neff ◽  
L. Kramer
Keyword(s):  
Boundary Layer ◽  
Layer Structure ◽  
Surface Fluxes ◽  
Lower Atmosphere ◽  
Trace Gas ◽  
Polar Regions ◽  
Stable Conditions ◽  
Sonic Anemometers ◽  
Turbulence Data ◽  
Atmospheric Trace Gas

AbstractBoundary layer conditions in polar regions have been shown to have a significant impact on the levels of trace gases in the lower atmosphere. The ability to properly describe boundary layer characteristics (e.g., stability, depth, and variations on diurnal and seasonal scales) is essential to understanding the processes that control chemical budgets and surface fluxes in these regions. Surface turbulence data measured from 3D sonic anemometers on an 8-m tower at Summit Station, Greenland, were used for estimating boundary layer depths (BLD) in stable to weakly stable conditions. The turbulence-derived BLD estimates were evaluated for June 2010 using direct BLD measurements from an acoustic sounder located approximately 50 m away from the tower. BLDs during this period varied diurnally; minimum values were less than 10 m, and maximum values were greater than 150 m. BLD estimates provided a better comparison with sodar observations during stable conditions. Ozone and nitrogen oxides were also measured at the meteorological tower and investigated for their dependency on boundary layer structure. These analyses, in contrast to observations from South Pole, Antarctica, did not show a clear relation between surface-layer atmospheric trace-gas levels and the stable boundary layer.

scholarly journals Areal-averaged trace gas emission rates from long-range open-path measurements in stable boundary layer conditions

2012 ◽  
Vol 5 (7) ◽  
pp. 1571-1583 ◽  
Author(s):  
K. Schäfer ◽  
R. H. Grant ◽  
S. Emeis ◽  
A. Raabe ◽  
C. von der Heide ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Land Surface ◽  
Gradient Methods ◽  
Trace Gas ◽  
Emission Rates ◽  
Stable Boundary ◽  
Flux Gradient ◽  
Surface Emission ◽  
Stable Conditions ◽  
Flux Measurements

Abstract. Measurements of land-surface emission rates of greenhouse and other gases at large spatial scales (10 000 m2) are needed to assess the spatial distribution of emissions. This can be readily done using spatial-integrating micro-meteorological methods like flux-gradient methods which were evaluated for determining land-surface emission rates of trace gases under stable boundary layers. Non-intrusive path-integrating measurements are utilized. Successful application of a flux-gradient method requires confidence in the gradients of trace gas concentration and wind, and in the applicability of boundary-layer turbulence theory; consequently the procedures to qualify measurements that can be used to determine the flux is critical. While there is relatively high confidence in flux measurements made under unstable atmospheres with mean winds greater than 1 m s−1, there is greater uncertainty in flux measurements made under free convective or stable conditions. The study of N2O emissions of flat grassland and NH3 emissions from a cattle lagoon involves quality-assured determinations of fluxes under low wind, stable or night-time atmospheric conditions when the continuous "steady-state" turbulence of the surface boundary layer breaks down and the layer has intermittent turbulence. Results indicate that following the Monin-Obukhov similarity theory (MOST) flux-gradient methods that assume a log-linear profile of the wind speed and concentration gradient incorrectly determine vertical profiles and thus flux in the stable boundary layer. An alternative approach is considered on the basis of turbulent diffusivity, i.e. the measured friction velocity as well as height gradients of horizontal wind speeds and concentrations without MOST correction for stability. It is shown that this is the most accurate of the flux-gradient methods under stable conditions.

scholarly journals Incomplete Kawasaki disease - a diagnostic and therapeutic challenge

2014 ◽  
Vol 9 (4) ◽  
pp. 30-35
Author(s):  
S Datta ◽  
S Maiti ◽  
G Das ◽  
A Chatterjee ◽  
P Ghosh
Keyword(s):  
Kawasaki Disease ◽  
Intravenous Immunoglobulin ◽  
Incomplete Kawasaki Disease ◽  
Duration Of Symptoms ◽  
Clinical Criteria ◽  
Echocardiographic Finding ◽  
2D Echocardiography ◽  
Acquired Heart Disease ◽  
The Mean ◽  
One Year

Background The diagnosis of classical Kawasaki Disease was based on clinical criteria. The conventional criteria is particularly useful in preventing over diagnosis, but at the same time it may result in failure to recognize the incomplete form of Kawasaki Disease. Objective To suspect incomplete Kawasaki Disease, because early diagnosis and proper treatment may reduce substantial risk of developing coronary artery abnormality which is one of the leading causes of acquired heart disease in children. Method Nine cases of incomplete Kawasaki Disease were diagnosed over a period of one year. The diagnosis of incomplete Kawasaki Disease was based on fever for five days with less than four classical clinical features and cardiac abnormality detected by 2D- echocardiography. A repeat echocardiography was done after 6 weeks of onset of illness. The patients were treated with Intravenous Immunoglobulin and/or aspirin. Result The mean age of the patients was 3.83 years and the mean duration of symptoms before diagnosis was 12.1 days. Apart from other criteria all of our patients had edema and extreme irritability. All the patients had abnormal echocardiographic finding. Five patients received only aspirin due to nonaffordability of Intravenous Immunoglobulin and four patients received both aspirin and Intravenous Immunoglobulin, but the outcome was excellent in all the cases. Conclusion Incomplete Kawasaki Disease can be diagnosed with more awareness and aspirin alone may be used as a second line therapy in case of non affordability of Intravenous Immunoglobulin. Journal of College of Medical Sciences-Nepal, 2013, Vol-9, No-4, 30-35 DOI: http://dx.doi.org/10.3126/jcmsn.v9i4.10234

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