Scaling of spin-echo amplitudes with frequency, diffusion coefficient, pore size, and susceptibility difference for the NMR of fluids in porous media and biological tissues

1995 ◽  
Vol 51 (3) ◽  
pp. 2104-2114 ◽  
Author(s):  
Giulio C. Borgia ◽  
Robert J. S. Brown ◽  
Paola Fantazzini
2006 ◽  
Vol 258-260 ◽  
pp. 207-212
Author(s):  
Miranda M.N.N. ◽  
M.A. Silva

In the drying of porous media, the mass transport occurs in the pores as well as on the surface of the solid. The mechanisms involved can take place simultaneously, influenced by the predominant one and can change depending on the moisture content. In this work, the moisture effective diffusivity was estimated in solids with distinct structural properties in order to verify the predominant mechanisms according to the moisture content, analyzing the influence of the physical properties. The materials studied were NaY Zeolite, Kaolin, Silica and Alumina. The results of diffusion coefficient present a minimum at low moisture content that can be related to pore size.


Fractals ◽  
2015 ◽  
Vol 23 (02) ◽  
pp. 1550012 ◽  
Author(s):  
QIAN ZHENG ◽  
XIANGPENG LI

Gas diffusion behavior in fractal porous media is simulated by Monte Carlo technique in this work. Based on the fractal character of pore size in porous media, the probability model of the effective gas diffusion coefficient is derived. The proposed model of the effective gas diffusion coefficient is explicitly expressed as a function of structural parameters of porous media, such as porosity, pore size, the fractal dimensions for pore area and tortuosity. The effect of structural parameters of porous media has been studied in detail. The results show that the present results from the Monte Carlo simulations present a good agreement with those from the available analytical model and the available experimental data. The proposed Monte Carlo simulation technique may have the potential in predictions of other gas transport properties in fractal porous media.


2018 ◽  
Vol 21 (12) ◽  
pp. 1253-1263
Author(s):  
Ruifei Wang ◽  
Hongqing Song ◽  
Jiulong Wang ◽  
Yuhe Wang

2019 ◽  
Vol 6 (6) ◽  
pp. 181902 ◽  
Author(s):  
Junchen Lv ◽  
Yuan Chi ◽  
Changzhong Zhao ◽  
Yi Zhang ◽  
Hailin Mu

Reliable measurement of the CO 2 diffusion coefficient in consolidated oil-saturated porous media is critical for the design and performance of CO 2 -enhanced oil recovery (EOR) and carbon capture and storage (CCS) projects. A thorough experimental investigation of the supercritical CO 2 diffusion in n -decane-saturated Berea cores with permeabilities of 50 and 100 mD was conducted in this study at elevated pressure (10–25 MPa) and temperature (333.15–373.15 K), which simulated actual reservoir conditions. The supercritical CO 2 diffusion coefficients in the Berea cores were calculated by a model appropriate for diffusion in porous media based on Fick's Law. The results show that the supercritical CO 2 diffusion coefficient increases as the pressure, temperature and permeability increase. The supercritical CO 2 diffusion coefficient first increases slowly at 10 MPa and then grows significantly with increasing pressure. The impact of the pressure decreases at elevated temperature. The effect of permeability remains steady despite the temperature change during the experiments. The effect of gas state and porous media on the supercritical CO 2 diffusion coefficient was further discussed by comparing the results of this study with previous study. Based on the experimental results, an empirical correlation for supercritical CO 2 diffusion coefficient in n -decane-saturated porous media was developed. The experimental results contribute to the study of supercritical CO 2 diffusion in compact porous media.


Geosciences ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 119
Author(s):  
Vincenzo Guerriero ◽  
Stefano Mazzoli

The effective stress principle (ESP) plays a basic role in geology and engineering problems as it is involved in fundamental issues concerning strain and failure of rock and soil, as well as of other porous materials such as concrete, metal powders, biological tissues, etc. Although since its introduction in the 1920s the main ESP aspects have been unravelled and theoretically derived, these do not appear to have been always entirely perceived by many in the science community dealing with ESP-related topics but having little familiarity with the complex theories of porous media and poroelasticity. The purpose of this review is to provide a guidance for the reader who needs an updated overview of the different theoretical and experimental approaches to the ESP and related topics over the past century, with particular reference to geological fracturing processes. We begin by illustrating, after some introductive historical remarks, the basic theory underlying the ESP, based on theory of elasticity methods. Then the different ESP-related theories and experimental results, as well as main interpretations of rock jointing and fracturing phenomena, are discussed. Two main classical works are then revisited, and a rigorous ESP proof is derived. Such a proof is aimed at geologists, engineers and geophysicists to become more familiar with theories of porous media and poroelasticity, being based on the classical theory of elasticity. The final part of this review illustrates some still open issues about faulting and hydraulic fracturing in rocks.


2012 ◽  
Vol 550-553 ◽  
pp. 158-163 ◽  
Author(s):  
Zi Yuan Liu ◽  
Sheng Li Chen ◽  
Peng Dong ◽  
Xiu Jun Ge

Through the measured effective diffusion coefficients of Dagang vacuum residue supercritical fluid extraction and fractionation (SFEF) fractions in FCC catalysts and SiO2model catalysts, the relation between pore size of catalyst and effective diffusion coefficient was researched and the restricted diffusion factor was calculated. The restricted diffusion factor in FCC catalysts is less than 1 and it is 1~2 times larger in catalyst with polystyrene (PS) template than in conventional FCC catalyst without template, indicating that the diffusion of SFEF fractions in the two FCC catalysts is restricted by the pore. When the average molecular diameter is less than 1.8 nm, the diffusion of SFEF fractions in SiO2model catalyst which average pore diameter larger than 5.6 nm is unrestricted. The diffusion is restricted in the catalyst pores of less than 8 nm for SFEF fractions which diameter more than 1.8 nm. The tortuosity factor of SiO2model catalyst is obtained to be 2.87, within the range of empirical value. The effective diffusion coefficient of the SFEF fractions in SiO2model catalyst is two orders of magnitude larger than that in FCC catalyst with the same average pore diameter. This indicate that besides the ratio of molecular diameter to the pore diameter λ, the effective diffusion coefficient is also closely related to the pore structure of catalyst. Because SiO2model catalyst has uniform pore size, the diffusion coefficient can be precisely correlated with pore size of catalyst, so it is a good model material for catalyst internal diffusion investigation.


2013 ◽  
Vol 80 (2) ◽  
Author(s):  
Minh H. Tran ◽  
Younane N. Abousleiman

The porochemoelectroelastic analytical models have been used to describe the response of chemically active and electrically charged saturated porous media such as clay soils, shales, and biological tissues. However, existing studies have ignored the anisotropic nature commonly observed on these porous media. In this work, the anisotropic porochemoelectroelastic theory is presented. Then, the solution for an inclined wellbore drilled in transversely isotropic shale formations subjected to anisotropic far-field stresses with time-dependent down-hole fluid pressure and fluid activity is derived. Numerical examples illustrating the combined effects of porochemoelectroelastic behavior and anisotropy on wellbore responses are also included. The analysis shows that ignoring either the porochemoelectroelastic effects or the formation anisotropy leads to inaccurate prediction of the near-wellbore pore pressure and effective stress distributions. Finally, wellbore responses during a leak-off test conducted soon after drilling are analyzed to demonstrate the versatility of the solution in simulating complex down-hole conditions.


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