scholarly journals Hot-Electron Intraband Luminescence from Single Hot Spots in Noble-Metal Nanoparticle Films

2015 ◽  
Vol 115 (6) ◽  
Author(s):  
Tobias Haug ◽  
Philippe Klemm ◽  
Sebastian Bange ◽  
John M. Lupton
Nano Letters ◽  
2002 ◽  
Vol 2 (10) ◽  
pp. 1067-1071 ◽  
Author(s):  
Lon A. Porter ◽  
Hee Cheul Choi ◽  
Alexander E. Ribbe ◽  
Jillian M. Buriak

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1249
Author(s):  
Ajay P. Manuel ◽  
Karthik Shankar

Plasmonic photocatalysis enables innovation by harnessing photonic energy across a broad swathe of the solar spectrum to drive chemical reactions. This review provides a comprehensive summary of the latest developments and issues for advanced research in plasmonic hot electron driven photocatalytic technologies focusing on TiO2–noble metal nanoparticle heterojunctions. In-depth discussions on fundamental hot electron phenomena in plasmonic photocatalysis is the focal point of this review. We summarize hot electron dynamics, elaborate on techniques to probe and measure said phenomena, and provide perspective on potential applications—photocatalytic degradation of organic pollutants, CO2 photoreduction, and photoelectrochemical water splitting—that benefit from this technology. A contentious and hitherto unexplained phenomenon is the wavelength dependence of plasmonic photocatalysis. Many published reports on noble metal-metal oxide nanostructures show action spectra where quantum yields closely follow the absorption corresponding to higher energy interband transitions, while an equal number also show quantum efficiencies that follow the optical response corresponding to the localized surface plasmon resonance (LSPR). We have provided a working hypothesis for the first time to reconcile these contradictory results and explain why photocatalytic action in certain plasmonic systems is mediated by interband transitions and in others by hot electrons produced by the decay of particle plasmons.


2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Giyaullah Habibullah ◽  
Jitka Viktorova ◽  
Tomas Ruml

AbstractNoble metals have played an integral part in human history for centuries; however, their integration with recent advances in nanotechnology and material sciences have provided new research opportunities in both academia and industry, which has resulted in a new array of advanced applications, including medical ones. Noble metal nanoparticles (NMNPs) have been of great importance in the field of biomedicine over the past few decades due to their importance in personalized healthcare and diagnostics. In particular, platinum, gold and silver nanoparticles have achieved the most dominant spot in the list, thanks to a very diverse range of industrial applications, including biomedical ones such as antimicrobial and antiviral agents, diagnostics, drug carriers and imaging probes. In particular, their superior resistance to extreme conditions of corrosion and oxidation is highly appreciated. Notably, in the past two decades there has been a tremendous advancement in the development of new strategies of more cost-effective and robust NMNP synthesis methods that provide materials with highly tunable physicochemical, optical and thermal properties, and biochemical functionalities. As a result, new advanced hybrid NMNPs with polymer, graphene, carbon nanotubes, quantum dots and core–shell systems have been developed with even more enhanced physicochemical characteristics that has led to exceptional diagnostic and therapeutic applications. In this review, we aim to summarize current advances in the synthesis of NMNPs (Au, Ag and Pt).


2021 ◽  
pp. 2101178
Author(s):  
Shay Goff Wallace ◽  
Nathan P. Bradshaw ◽  
Nicholas X. Williams ◽  
Justin H. Qian ◽  
Karl W. Putz ◽  
...  

2019 ◽  
Vol 463 ◽  
pp. 968-975 ◽  
Author(s):  
N. Nedyalkov ◽  
M.E. Koleva ◽  
R. Nikov ◽  
N.E. Stankova ◽  
E. Iordanova ◽  
...  

2019 ◽  
Vol 538 ◽  
pp. 569-577 ◽  
Author(s):  
Jianhao Qiu ◽  
Xingguang Zhang ◽  
Kailuo Xie ◽  
Xiong-Fei Zhang ◽  
Yi Feng ◽  
...  

2006 ◽  
Vol 78 (1) ◽  
pp. 107-112 ◽  
Author(s):  
Edward T. Castellana ◽  
Sho Kataoka ◽  
Fernando Albertorio ◽  
Paul S. Cremer

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