scholarly journals Yield Stress Aging in Attractive Colloidal Suspensions

2022 ◽  
Vol 128 (1) ◽  
Author(s):  
Francesco Bonacci ◽  
Xavier Chateau ◽  
Eric M. Furst ◽  
Julie Goyon ◽  
Anaël Lemaître
AIChE Journal ◽  
1998 ◽  
Vol 44 (3) ◽  
pp. 538-544 ◽  
Author(s):  
Peter J. Scales ◽  
Stephen B. Johnson ◽  
Thomas W. Healy ◽  
Prakash C. Kapur

2020 ◽  
Author(s):  
James A. Richards ◽  
Rory E. O’Neill ◽  
Wilson C. K. Poon

AbstractWe show that a suspension of non-Brownian calcite particles in glycerol-water mixtures can be tuned continuously from being a yield-stress suspension to a shear-thickening suspension—without a measurable yield stress—by the addition of various surfactants. We interpret our results within a recent theoretical framework that models the rheological effects of stress-dependent constraints on inter-particle motion. Bare calcite particle suspensions are found to have finite yield stresses. In these suspensions, frictional contacts that constrain inter-particle sliding form at an infinitesimal applied stress and remain thereafter, while adhesive bonds that constrain inter-particle rotation are broken as the applied stress increases. Adding surfactants reduces the yield stress of such suspensions. We show that, contrary to the case of surfactant added to colloidal suspensions, this effect in non-Brownian suspensions is attributable to the emergence of a finite onset stress for the formation of frictional contacts. Our data suggest that the magnitude of this onset stress is set by the strength of surfactant adsorption to the particle surfaces, which therefore constitutes a new design principle for using surfactants to tune the rheology of formulations consisting of suspensions of adhesive non-Brownian particles.


Author(s):  
Johannes A. Botha ◽  
Wei Ding ◽  
Timothy N. Hunter ◽  
Simon Biggs ◽  
Graham A. Mackay ◽  
...  

2000 ◽  
Vol 627 ◽  
Author(s):  
C. S. O'Hern ◽  
S. A. Langer ◽  
A. J. Liu ◽  
S. R. Nagel

Many systems can develop a yield stress while in an amorphous state. For example, a supercooled liquid, when cooled sufficiently, forms a glass - an amorphous solid with a yield stress. Another common example is a granular material which will remain solid and not move even under the influence of moderate stresses. This accounts for why piles of grain or sand can exist with a non-zero slope even though gravity is acting to flatten out the upper surface. The solidity in that case is due to the system having become jammed. Similar jamming often inhibits flow out of a hopper or in conduits transporting material across a factory floor. Jamming is a ubiquitous phenomenon occurring in many different systems such as colloidal suspensions, foams and, of course, traffic. We tend to think of the jamming transition as being stress-induced. A “fluid” at constant density (or under a confining pressure) flows if the stress is above the yield stress but becomes stuck in an amorphous configuration if the stress is too low. The idea of temperature, per se, does not seem to be crucial to the transition. This makes it seems quite different from the formation of a glass out of a supercooled liquid by lowering the temperature. However, there are similarities between these two types of transitions, aside from the obvious fact that they both have to do with the complete arrest of dynamics and flow. An exploration of these similarities was the subject of a program at the Institute for Theoretical Physics in Santa Barbara held in the Autumn of 1997. A synopsis of this program was published that details some of the interesting ideas now current in that field.[1]


Author(s):  
John G. Sheehan

Improvements in particulate coatings for printable paper require understanding mechanisms of colloidal interactions in paper coating suspensions. One way to deduce colloidal interactions is to mage particle spacings and orientations at high resolution with cryo-SEM. Recent improvements in cryo-SEM technique have increased resolution enough to image particles in coating paints,vhich are sometimes smaller than 100 nm. In this report, a metal-coating chamber is described for preparation of colloidal suspensions for cryo-SEM at resolution down to 20 nm. It was found that etching is not necessary to achieve this resolution.A 120 K cryo-SEM sample will remain in an SEM for hours without noticeable condensation of imorphous ice. This is due to the high vapor pressure of vapor-condensed amorphous ice, measured by Kouchi. However, clean vacuum is required to coat samples with the thinnest possible continuous metal films which are required for high magnification SEM. Vapor contaminants, especially hrydrocarbons, are known to interfere with thin-film nucleation and growth so that more metal is needed to form continuous films, and resolution is decreased. That is why the metal-coating chamber in fig. 1 is designed for the cleanest possible vacuum. Feedthroughs for the manipulator md the shutter, which are operated during metal coating, are sealed with leak-proof stainless-steel Dellows. The transfer rod slides through a baseplate feedthrough that is double o-ring sealed.


1998 ◽  
Vol 536 ◽  
Author(s):  
E. M. Wong ◽  
J. E. Bonevich ◽  
P. C. Searson

AbstractColloidal chemistry techniques were used to synthesize ZnO particles in the nanometer size regime. The particle aging kinetics were determined by monitoring the optical band edge absorption and using the effective mass model to approximate the particle size as a function of time. We show that the growth kinetics of the ZnO particles follow the Lifshitz, Slyozov, Wagner theory for Ostwald ripening. In this model, the higher curvature and hence chemical potential of smaller particles provides a driving force for dissolution. The larger particles continue to grow by diffusion limited transport of species dissolved in solution. Thin films were fabricated by constant current electrophoretic deposition (EPD) of the ZnO quantum particles from these colloidal suspensions. All the films exhibited a blue shift relative to the characteristic green emission associated with bulk ZnO. The optical characteristics of the particles in the colloidal suspensions were found to translate to the films.


Author(s):  
Khalid Elhasnaoui ◽  
◽  
A. Maarouf ◽  
M. Badia ◽  
M. Benhamou ◽  
...  

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