Jamming in Liquids and Granular Materials

2000 ◽  
Vol 627 ◽  
Author(s):  
C. S. O'Hern ◽  
S. A. Langer ◽  
A. J. Liu ◽  
S. R. Nagel

Many systems can develop a yield stress while in an amorphous state. For example, a supercooled liquid, when cooled sufficiently, forms a glass - an amorphous solid with a yield stress. Another common example is a granular material which will remain solid and not move even under the influence of moderate stresses. This accounts for why piles of grain or sand can exist with a non-zero slope even though gravity is acting to flatten out the upper surface. The solidity in that case is due to the system having become jammed. Similar jamming often inhibits flow out of a hopper or in conduits transporting material across a factory floor. Jamming is a ubiquitous phenomenon occurring in many different systems such as colloidal suspensions, foams and, of course, traffic. We tend to think of the jamming transition as being stress-induced. A “fluid” at constant density (or under a confining pressure) flows if the stress is above the yield stress but becomes stuck in an amorphous configuration if the stress is too low. The idea of temperature, per se, does not seem to be crucial to the transition. This makes it seems quite different from the formation of a glass out of a supercooled liquid by lowering the temperature. However, there are similarities between these two types of transitions, aside from the obvious fact that they both have to do with the complete arrest of dynamics and flow. An exploration of these similarities was the subject of a program at the Institute for Theoretical Physics in Santa Barbara held in the Autumn of 1997. A synopsis of this program was published that details some of the interesting ideas now current in that field.[1]

AIChE Journal ◽  
1998 ◽  
Vol 44 (3) ◽  
pp. 538-544 ◽  
Author(s):  
Peter J. Scales ◽  
Stephen B. Johnson ◽  
Thomas W. Healy ◽  
Prakash C. Kapur

2009 ◽  
Vol 23 (06n07) ◽  
pp. 1294-1299 ◽  
Author(s):  
YONGLI CHEN ◽  
AIMIN WANG ◽  
HAIFENG ZHANG ◽  
ZHUANGQI HU

A new kind of composite with a bi -continuous structure was produced by pressure infiltrating melt Zr 41.2 Ti 13.8 Cu 12.5 Ni 10 Be 22.5 into porous SiC which was made by powder metallurgy. Microstructure investigations of the composite show that the melt alloy was fully infiltrated into the voids of porous SiC and quenched into amorphous state. Both the amorphous alloy and the porous SiC exhibit a three-dimensional interconnected net structure. The study of thermal properties reveals that the addition of porous SiC reduces the width of supercooled liquid region of the composite. The bi -continuous composite presents 2% plastic strain and ultimate strength of 1250MPa.


1995 ◽  
Vol 32 (3) ◽  
pp. 428-451 ◽  
Author(s):  
Glen R. Andersen ◽  
Christopher W. Swan ◽  
Charles C. Ladd ◽  
John T. Germaine

The stress–strain behavior of frozen Manchester fine sand has been measured in a high-pressure low-temperature triaxial compression testing system developed for this purpose. This system incorporates DC servomotor technology, lubricated end platens, and on-specimen axial strain devices. A parametric study has investigated the effects of changes in strain rate, confining pressure, sand density, and temperature on behavior for very small strains (0.001%) to very large (> 20%) axial strains. This paper presents constitutive behavior for strain levels up to 1%. On-specimen axial strain measurements enabled the identification of a distinct upper yield stress (knee on the stress–strain curve) and a study of the behavior in this region with a degree of precision not previously reported in the literature. The Young's modulus is independent of strain rate and temperature, increases slightly with sand density in a manner consistent with Counto's model for composite materials, and decreases slightly with confining pressure. In contrast, the upper yield stress is independent of sand density, slightly dependent on confining pressure (considered a second order effect), but is strongly dependent on strain rate and temperature in a fashion similar to that for polycrystalline ice. Key words : frozen sand, high-pressure triaxial compression, strain rate, temperature, modulus, yield stress.


2021 ◽  
pp. FSO677
Author(s):  
Helmy Yusuf ◽  
Rizka Arifa Rahmawati ◽  
M Agus Syamsur Rijal ◽  
Dewi Isadiartuti

Background: Therapeutic activities of curcumin (CUR) via oral administration are hampered by the lack of bioavailability due to its poor water solubility and rapid degradation in GI tract. Materials & methods: This preliminary study developed CUR micelle-eudragit S100 (EUD) dry powder (CM-EDP) spray-dried formulations. Poloxamer 407 was used as a micelle-forming agent and EUD as an entrapping matrix for protection over hydrolysis and enzymes in the GI tract. Results: The morphology of CM-EDP showed agglomeration with cratering on the surface of particles. Differential thermal analysis and x-ray diffractometry data exhibited evidence that CUR was converted into amorphous solid. An increased concentration of micelle-forming and dispersion matrix polymers resulted in a high fraction of drug being converted into the amorphous state. A significant increase in dissolution by 7–10 times was achieved compared with that of raw CUR. Conclusion: The present study disclosed the CM-EDP potency for future development of CUR oral formulation.


Pharmaceutics ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 1023
Author(s):  
Houli Li ◽  
Meimei Zhang ◽  
Lilong Xiong ◽  
Weiyi Feng ◽  
Robert O. Williams

The purpose of this study was to improve the bioavailability of carbamazepine (CBZ), a poorly water-soluble antiepileptic drug, via modified-release amorphous solid dispersions (mr-ASD) by a thin film freezing (TFF) process. Three types of CBZ-mr-ASD with immediate-, delayed-, and controlled-release properties were successfully prepared with HPMC E3 (hydrophilic), L100-55 (enteric), and cellulose acetate (CA, lipophilic), defined as CBZ-ir-ASD, CBZ-dr-ASD, and CBZ-cr-ASD, respectively. A dry granulation method was used to prepare CBZ-mr-ASD capsule formulations. Various characterization techniques were applied to evaluate the physicochemical properties of CBZ-mr-ASD and the related capsules. The drug remained in an amorphous state when encapsulated within CBZ-mr-ASD, and the capsule formulation progress did not affect the performance of the dispersions. In dissolution tests, the preparations and the corresponding dosage forms similarly showed typical immediate-, delayed-, and controlled-release properties depending on the solubility of the polymers. Moreover, single-dose 24 h pharmacokinetic studies in rats indicated that CBZ-mr-ASD significantly enhanced the oral absorption of CBZ compared to that of crude CBZ. Increased oral absorption of CBZ was observed, especially in the CBZ-dr-ASD formulation, which showed a better pharmacokinetic profile than that of crude CBZ with 2.63- and 3.17-fold improved bioavailability of the drug and its main active metabolite carbamazepine 10,11-epoxide (CBZ-E).


1998 ◽  
Vol 554 ◽  
Author(s):  
A. S. Bains ◽  
C. A. Gordon ◽  
A. V. Granato ◽  
R. B. Schwarz

AbstractWe have measured the shear modulus and its temperature dependence of Pd40Ni40P20 using an EMAT technique. The room temperature value of 3.92(1011) d/cm2 is in fair agreement with that of 3.66(1011) d/cm2 given earlier by He and Schwarz, using a resonant ultrasound spectroscopy technique. The relative change with temperature coefficient for T << Tg is 3.4(10−4) K−1. For the heating rate of ∼1 K/min used here, Tg = 565 K compared with a value of 575 K reported earlier. The shear modulus is continuous at Tg , but its temperature coefficient is larger by a factor of 6.5 for T >> Tg. During temperature cycling near but below Tg , irreversible aging effects are found showing that the amorphous state is not an equilibrium state. Near but above Tg, the cycling effects are reversible for time scales of the order of hours but not for time scales of the order of days, showing that metastable equilibrium states have not yet been fully attained. The results are in overall agreement with the predictions of the Interstitialcy Theory.


2021 ◽  
pp. 276-315
Author(s):  
Andrew Zangwill

This chapter gives an overview of Anderson’s life at the top of the theoretical condensed matter world. He became very influential at Bell Labs and retired as a Consulting Director of the Physical Science Laboratory. He moved his half-time professorship from Cambridge to Princeton in 1975, but it took a decade to break down the resistance there to condensed matter physics. He was heavily involved with the Aspen Center and turned down an offer of the Directorship of the Institute for Theoretical Physics in Santa Barbara. He wrote the magisterial “Basic Notions of Condensed Matter Physics” but was widely regarded as a poor classroom instructor. His Nobel Prize gave him a platform to oppose the ABM and Star Wars ballistic missile systems, and the Superconducting Super Collider.


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