Coupling and decoupling of spin crossover and ferroelastic distortion: Unsymmetric hysteresis loop, phase diagram, and sequence of phases

Acicular micro-rods of the novel [Fe(Htrz)3](CF3SO3)2 complex exhibiting large hysteretic spin crossover behavior perfectly centered at room temperature.

Download Full-text

Dynamical control of the spin transition inside the thermal hysteresis loop of a spin-crossover single crystal

Physica B Condensed Matter ◽

10.1016/j.physb.2015.09.054 ◽

2016 ◽

Vol 486 ◽

pp. 187-191 ◽

Cited By ~ 7

Author(s):

Kamel Boukheddaden ◽

Mouhamadou Sy ◽

Miguel Paez-Espejo ◽

Ahmed Slimani ◽

François Varret

Keyword(s):

Single Crystal ◽

Hysteresis Loop ◽

Spin Crossover ◽

Thermal Hysteresis ◽

Spin Transition ◽

Thermal Hysteresis Loop ◽

Dynamical Control

Download Full-text

Molecular dynamics of spin crossover: The (P,T) phase diagram of [Fe(PM-BIA)2(NCS)2]

Chemical Physics ◽

10.1016/j.chemphys.2013.04.013 ◽

2013 ◽

Vol 420 ◽

pp. 25-34 ◽

Cited By ~ 9

Author(s):

A. Marbeuf ◽

S.F. Matar ◽

P. Négrier ◽

L. Kabalan ◽

J.F. Létard ◽

...

Keyword(s):

Molecular Dynamics ◽

Phase Diagram ◽

Spin Crossover ◽

T Phase

Download Full-text

Compensation effects and relation between the activation energy of spin transition and the hysteresis loop width for an iron(ii) complex

Physical Chemistry Chemical Physics ◽

10.1039/c6cp01892k ◽

2016 ◽

Vol 18 (25) ◽

pp. 16690-16699 ◽

Cited By ~ 11

Author(s):

Mark B. Bushuev ◽

Denis P. Pishchur ◽

Elena B. Nikolaenkova ◽

Viktor P. Krivopalov

Keyword(s):

Hysteresis Loop ◽

Spin Crossover ◽

Thermal Hysteresis ◽

Activation Barrier ◽

Spin Transition ◽

Hysteresis Loops ◽

High Activation ◽

Activation Barriers ◽

Spin Crossover Complexes ◽

Hysteresis Loop Width

Wide thermal hysteresis loops for iron(ii) spin crossover complexes are associated with high activation barriers: the higher the activation barrier, the wider the hysteresis loop for a series of related spin crossover systems.

Download Full-text

Mechanism of reversible spin transition with a thermal hysteresis loop in [FeIII(qsal)2][Ni(dmise)2]·2CH3CN: Selenium analogue of the precursor of an Fe(III) spin-crossover molecular conducting system

Polyhedron ◽

10.1016/j.poly.2008.11.047 ◽

2009 ◽

Vol 28 (9-10) ◽

pp. 1776-1781 ◽

Cited By ~ 30

Author(s):

Kazuyuki Takahashi ◽

Hatsumi Mori ◽

Hayao Kobayashi ◽

Osamu Sato

Keyword(s):

Hysteresis Loop ◽

Spin Crossover ◽

Thermal Hysteresis ◽

Spin Transition ◽

Conducting System ◽

Thermal Hysteresis Loop

Download Full-text

Bidirectional photo-switching of the spin state of iron(II) ions in a triazol based spin crossover complex within the thermal hysteresis loop

Chemical Physics Letters ◽

10.1016/j.cplett.2009.06.065 ◽

2009 ◽

Vol 477 (1-3) ◽

pp. 156-159 ◽

Cited By ~ 37

Author(s):

Nawel Ould Moussa ◽

Denis Ostrovskii ◽

Victor Martinez Garcia ◽

Gábor Molnár ◽

Koichiro Tanaka ◽

...

Keyword(s):

Hysteresis Loop ◽

Spin State ◽

Spin Crossover ◽

Thermal Hysteresis ◽

Thermal Hysteresis Loop

Download Full-text

Влияние межатомного обменного взаимодействия на магнитные фазовые переходы в условиях спинового кроссовера при высоких давлениях

Физика твердого тела ◽

10.21883/ftt.2018.06.45994.01m ◽

2018 ◽

Vol 60 (6) ◽

pp. 1166

Author(s):

С.Г. Овчинников ◽

Ю.С. Орлов ◽

С.В. Николаев ◽

А.И. Нестеров ◽

Т.М. Овчинникова

Keyword(s):

Experimental Data ◽

Phase Diagram ◽

High Spin ◽

Spin State ◽

Pressure Dependence ◽

Spin Crossover ◽

External Pressure ◽

Exchange Integral

AbstractThe phase diagram of an antiferromagnet with the spin crossover from the high-spin to low-spin state with S = 0 with increasing external pressure has been calculated with regard to the pressure dependence of the exchange integral. The calculated results are compared with the experimental data on ferropericlase Fe_ x Mg_1 – x O.

Download Full-text