Helical self-assembly of 2-(1,4,7,10-tetraazacyclododecan-1-yl)cyclohexan-1-ol (cycyclen)
2012 ◽
Vol 68
(10)
◽
pp. o383-o386
◽
Keyword(s):
The title macrocyclic amino alcohol compound, C14H30N4O, is investigated as a solid-state synthon for the design of a self-assembled tubular structure. It crystallizes in a helical column constructed by stereospecific O—H...N and N—H...N interactions. The hydrogen-bonding interactions, dependent upon macrocyclic ring helicity and molecular conformation, linkR,RandS,Senantiomers in a head-to-tail fashion, forming a continuous hydrophilic inner core.
2018 ◽
Vol 74
(8)
◽
pp. 1151-1154
2006 ◽
Vol 62
(4)
◽
pp. o1431-o1432
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2006 ◽
Vol 62
(7)
◽
pp. o2765-o2767
Keyword(s):
2014 ◽
Vol 70
(11)
◽
pp. 1040-1045
◽
Keyword(s):
2009 ◽
Vol 65
(6)
◽
pp. o1429-o1429