Production and characterization of organic solar cells

2018 ◽  
Vol 15 (4) ◽  
pp. 540-548 ◽  
Author(s):  
Kindness A.M. Uyanga ◽  
Modestus Okechukwu Okwu ◽  
A.O. Adeoye ◽  
S.E. Ogbeide
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Short Circuit ◽  
Active Material ◽  
Soda Lime Glass ◽  
Content Type ◽  
Different Temperatures

Purpose The study aims to carry out the production of a bulk heterojunction organic solar cell in a laboratory scale using a blend of poly (3-hexylthiopene) (P3HT) and [6, 6]-phenyl (C61) butyric acid methyl ether (PCBM). Design/methodology/approach Four inverted geometry organic solar cells were prepared based on 1:1 ratio of P3HT to PCBM and subjected to post annealing at different temperatures of 32, 120, 130 and 140°C. Solar cells were fabricated with structure glass/ITO/P3HT:PCBM/PEDOT:PSS/Au and characterized using Keithley 2400 series sourcemeter and a multimeter interfaced to a computer system with a LabVIEW software, which showed both dark and illumination current–voltage characteristic curves. Four reference cells were also fabricated with structure soda lime glass/P3HT:PCBM and annealed at different temperatures of 32, 120, 130 and 140°C. Findings The third organic solar cell prepared, Sample CITO, had the best performance with power conversion efficiency (PCE) of 2.0281 per cent, fill factor (FF) of 0.392, short circuit current of −0.0133 A and open circuit voltage of 0.389 V. Annealing of active layer was found to improve cell morphology, FF and PCE. Annealing of the active layer at 140°C resulted in a decrease of the PCE to 2.01 per cent. Research limitations/implications These findings are in good agreement with previous investigation in literature which reported that best annealing temperature for a 1:1 ratio blend of active material is 130°C. Ultraviolet–visible spectra on reference cells showed that sample CITO had wider absorption spectra with peak absorbance at a wavelength of 508 nm. Originality/value This research is purely original.

scholarly journals Air-processed active-layer of organic solar cells investigated by conducting AFM for precise defect detection

RSC Advances ◽  
2020 ◽  
Vol 10 (42) ◽  
pp. 24882-24892 ◽  
Author(s):  
Anjusree S. ◽  
Arya K. R. ◽  
Bikas C. Das
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Active Layer ◽  
Defect Detection ◽  
Organic Solar Cells ◽  
Organic Solar Cell

Current imaging by C-AFM is demonstrated as a very effective tool to probe the defects in the organic solar cell active layer.

Improving the charge transport of the ternary blend active layer for efficient semitransparent organic solar cells

2020 ◽  
Vol 13 (12) ◽  
pp. 5177-5185
Author(s):  
Pan Yin ◽  
Zhigang Yin ◽  
Yunlong Ma ◽  
Qingdong Zheng
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Charge Transport ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Ternary Blend ◽  
Visible Transmittance

With the aid of a suitable third component acceptor material, the best-performance semitransparent organic solar cell shows an outstanding efficiency of 13.49% at an average visible transmittance of 22.58%.

scholarly journals PREPARATION AND CHARACTERIZATION OF P3HT-PCBM ORGANIC SOLAR CELLS

2013 ◽  
pp. 23-25
Author(s):  
ANUBHAV GUPTA ◽  
PRAVEEN S ◽  
ABHISHEK KUMAR ◽  
PRIYANKA SHREE ◽  
SUCHANA MISHRA
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Silicon Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Glass Substrates

Organic solar cells using P3HT: PCBM as an active layer on ITO coated glass substrates were fabricated and characterized. Different air annealing procedures and cathode materials were tried and the characteristics were compared with that of a standard thin film polycrystalline silicon solar cell. It was found that the sample prepared with post-deposition air annealing at 130 oC improves the open circuit voltage (Voc) considerably. Besides, short circuit current (Isc) and the efficiency (η) were highest for the sample with a non annealed active layer. Series resistance (Rs) for this sample was lowest, but 103 times higher than that of the silicon solar cell, which in turn may have reduced the efficiency value for the organic cell compared to silicon.

Study of Al/Organic/ITO Polymer Solar Cell on Glass Substrate

2013 ◽  
Vol 448-453 ◽  
pp. 1446-1451
Author(s):  
Yi Tsung Chang ◽  
Jen Hong Su ◽  
Yi Ting Shih ◽  
Yen Lin Shih
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Glass Substrate ◽  
Polymer Solar Cells ◽  
Short Circuit ◽  
Single Layer ◽  
Short Circuit Current ◽  
Open Circuit

A single layer of organic solar cells with the Al/P3HT/PEDOT: PSS/ITO structure on glass substrate was investigated in this paper, and examined the performance of the polymer solar cells by changing 60, 70 and 80 nm thickness of the P3HT active layer. These devices had better absorption in the active layer and poor charges collect in the electrode with increase thickness of active layer were observed. It is found that the best properties that the single layer organic solar cell with open-circuit voltage 0.457 V, short-circuit current 1.05E-4 mA and power conversion efficiency of 3.3E-5% was achieved under illumination 100 mW/cm2 when the thickness of P3HT active layer is about 80 nm.

scholarly journals Increased short circuit current in an azafullerene-based organic solar cell

2015 ◽  
Vol 51 (6) ◽  
pp. 1128-1130 ◽  
Author(s):  
Werther Cambarau ◽  
Urs F. Fritze ◽  
Aurélien Viterisi ◽  
Emilio Palomares ◽  
Max von Delius
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current

We report azafullerene monoadduct DPC59N, which in organic solar cells outperforms benchmark acceptor PC60BM in respect to JSC and EQE.

High-performance ternary organic solar cells with thick active layer exceeding 11% efficiency

2017 ◽  
Vol 10 (4) ◽  
pp. 885-892 ◽  
Author(s):  
Nicola Gasparini ◽  
Luca Lucera ◽  
Michael Salvador ◽  
Mario Prosa ◽  
George D. Spyropoulos ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Charge Carrier ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
High Performance ◽  
Power Conversion ◽  
Carrier Recombination ◽  
Charge Carrier Recombination

We present a novel ternary organic solar cell with an uncommonly thick active layer (∼300 nm), featuring thickness invariant charge carrier recombination and delivering 11% power conversion efficiency (PCE).

On the short circuit resilience of organic solar cells: prediction and validation

2015 ◽  
Vol 17 (33) ◽  
pp. 21501-21506 ◽  
Author(s):  
A. Jolt Oostra ◽  
Edsger C. P. Smits ◽  
Dago M. de Leeuw ◽  
Paul W. M. Blom ◽  
Jasper J. Michels
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Fault Tolerance ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Short Circuit ◽  
Cell Performance ◽  
Solar Cell Performance ◽  
Short Circuits

As flexible organic solar cell performance suffers from processing-related short-circuits, quantitative insight in the effect of flaws is eminent. This work provides such insight and explains how an intrinsic healing mechanism significantly enhances fault-tolerance.

Boron-Nitrogen Doped Dihydroindeno[1,2-b]fluorene Derivatives as Acceptors in Organic Solar Cells

2019 ◽  
Author(s):  
Matthew Morgan ◽  
Maryam Nazari ◽  
Thomas Pickl ◽  
J. Mikko Rautiainen ◽  
Heikki M. Tuononen ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Broad Absorption ◽  
Nitrogen Doped ◽  
Large Depth ◽  
End Products ◽  
Boron Nitrogen ◽  
The Way

The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron-nitrogen doped dihydroindeno[1,2-<i>b</i>]fluorene which can be synthesized via mildly air-sensitive techniques and the end products handled readily under atmosphereic conditions. Through transmetallation via diarylzinc reagents a series of derivatives were sythesized which show broad absorption profiles that highlight the versatility of this backbone to be used in organic solar cell devices. These compounds can be synthesized in large yields, in alow number of steps and functionalized at many stages along the way providing a large depth of possibilities. Exploratory device paramaters were studied and show PCE of 2%.

Additive-induced Miscibility Regulation and Hierarchical Morphology Enables 17.5% Binary Organic Solar Cells

2021 ◽  
Author(s):  
Jie Lv ◽  
Hua Tang ◽  
Jiaming Huang ◽  
Cenqi Yan ◽  
Kuan Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Power Conversion ◽  
Charge Trapping ◽  
Free Charge ◽  
Charge Generation ◽  
Low Charge ◽  
Hierarchical Morphology

Due to the barrierless free charge generation, low charge trapping, and high charge mobilities, the PM6:Y6 organic solar cell (OSC) achieves excellent power conversion efficiency (PCE) of 15.7%. However, the...

Fabrication and characterization of CuPc and PCBM based organic solar cell with metal interlayer

2015 ◽  
Vol 12 (5) ◽  
pp. 413-420
Author(s):  
Muhammad Ahsan Naveed ◽  
A. Hussain ◽  
K. Islam ◽  
P. Akhter
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Impedance Spectroscopy ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Silver Layer ◽  
Absorbance Spectrum ◽  
Heterojunction Solar Cells ◽  
Processing Cost ◽  
Donor Acceptor

Organic solar cells have potential as an alternative to conventional inorganic solar cell due to low processing cost, flexibility and easy fabrication technique. The goal of this paper is to study the characteristics of the CuPc and PCBM based organic solar cell by introducing a thin layer of Ag at the interface of donor (CuPc) and Acceptor (PCBM), their photovoltaic and optical properties were investigated. The heterojunction solar cells with and without silver inter layer were fabricated through thermal deposition in HR vacuum. The OPV solar cells were characterized using current-voltage graphs, absorbance spectrum and Impedance spectroscopy. Impedance spectroscopy was taken to identify the traps using series resistance, parallel resistance, and Impedance spectrums under different frequencies. Optical behaviors of these devices have been investigated with absorbance spectrum. Introducing Ag to interfacing point produced traps and these traps causes to decreased Voc, Isc, FF, and efficiency. The effect of silver layer at donor acceptor interface was studied.

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