Structural Analysis of Inclusions in β-Silicon Carbide Whiskers Grown from Rice Hulls

2005 ◽  
Vol 80 (5) ◽  
pp. 1165-1173 ◽  
Author(s):  
Kevin M. Knowles ◽  
Maharajapuram V. Ravichandran
Author(s):  
L. F. Allard ◽  
T. A. Nolan

The internal structure and surface crystallography of ceramic whiskers are of interest because of their increasing importance as second phase reinforcements in a variety of matrix materials. Whiskers are typically 0.5 to 5 um in diameter with aspect ratios of 10 to 100 or more. Silicon carbide whiskers are the best known; they are usually grown by vapor-liquid-solid (VLS) or other processes from either natural (e.g. rice hulls) or synthetic materials. Titanium nitride whiskers are also of interest because of their potential for applications where SiC whiskers are not suitable (e.g. ferrous alloys). This paper highlights some of the details of SiC and TiN whisker ultrastructure.


1984 ◽  
Vol 67 (11) ◽  
pp. 715-720 ◽  
Author(s):  
N. K. SHARMA ◽  
WENDELL S. WILLIAMS ◽  
A. ZANGVIL

Author(s):  
S.R. Nutt ◽  
R.W. Carpenter

Silicon carbide whiskers can be grown by pyrolysis of silica and cellulose derived from rice hulls. Whiskers grown by this process are useful as composite reinforcements in a wide range of matrix materials. Due to the scarcity of published information regarding the crystal growth mechanism, research was devoted to analysis of inclusions and defects in the whiskers. Most SiC whiskers exhibited microinclusions (<10nm in size) confined to a central core region (Fig. 1). The distribution implies a two-stage growth process in which the core region grows in the first stage, followed by lateral growth in the second stage. An HREM image of a single twinned inclusion is shown in Fig. 2. The whisker orientation is [0001] and the inclusion exhibits crossed 0.45nm lattice fringes running parallel to type II prism planes in the SiC lattice. The lattice fringes often did not span the entire inclusion diameter, and radiation damage to the inclusion was observed with increasing dose using a 200 kV electron beam.


2019 ◽  
Vol 9 (20) ◽  
pp. 4388 ◽  
Author(s):  
Artyom Plyushch ◽  
Jan Macutkevič ◽  
Polina Kuzhir ◽  
Aliaksei Sokal ◽  
Konstantin Lapko ◽  
...  

Hybrid composite materials based on an aluminium phosphate matrix with silicon carbide whiskers and multi-walled carbon nanotubes were studied in a wide frequency range (20 Hz to 36 GHz). It was demonstrated, that the addition of the silicon carbide whiskers enhances the dielectric permittivity and conductivity. This was explained by the difference in tunnelling parameters. Hybrid ceramics with nanotubes and whiskers also exhibits substantially improved electromagnetic shielding properties. The hybrid ceramics with 10 wt. % silicon carbide whiskers and a 1 mm thick 1.5 wt. % carbon nanotube layer, show higher than 50% absorption of electromagnetic radiation.


2020 ◽  
Vol 54 (29) ◽  
pp. 4611-4620 ◽  
Author(s):  
Akm Samsur Rahman ◽  
Chirag Shah ◽  
Nikhil Gupta

The current research is focused on developing a geopolymer binder using rice husk ash–derived silica nanoparticles. Four types of rice husks were collected directly from various rice fields of Bangladesh in order to evaluate the pozzolanic activity and compatibility of the derived rice husk ashes with precursors of sodium-based geopolymers. Silicon carbide whiskers were introduced into sodium-based geopolymers in order to evaluate the response of silicon carbide whiskers to the interfacial bonding and strength of sodium-based geopolymers along with rice husk ashes. Compression, flexural and short beam shear tests were performed to investigate the synergistic effect of rice husk ashes–derived silica and commercially available silicon carbide whiskers. Results show that rice husk ashes–derived spherical silica nanoparticles reduced nano-porosity of the geopolymers by ∼20% and doubled the compressive strength. The simultaneous additions of rice husk ashes and silicon carbide whiskers resulted in flexural strength improvement by ∼27% and ∼97%, respectively. The increase in compressive strength due to the inclusion of silica nanoparticles is related to the reduction in porosity. The increase in flexural strength due to simultaneous inclusion of silica and silicon carbide whiskers suggest that silica particles are compatible with the metakaolin-based geopolymers, which is effective in consolidation. Finally, microscopy suggest that silicon carbide whiskers are effective in increasing bridged network and crack resistance.


Author(s):  
Ftema W. Aldbea ◽  
Subhiyah Aboulqasim Alameen ◽  
Carlos Vázquez Vázquez ◽  
A. Sharma ◽  
Mabrouk Kraini ◽  
...  

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