Influence of Equation-of-States on Supercritical CO2 Combustion Mixtures

2020 ◽  
Vol 143 (6) ◽  
Author(s):  
K.R.V. (Raghu) Manikantachari ◽  
Ramees K. Rahman ◽  
Scott M. Martin ◽  
Carlos Velez ◽  
Subith S. Vasu
Keyword(s):  
Supercritical Co2 ◽  
Carbon Capture ◽  
Flame Structure ◽  
Compressibility Factor ◽  
Operating Conditions ◽  
Binary Interaction ◽  
Binary Interaction Parameter ◽  
Combustion Modeling ◽  
Equation Of States ◽  
Supercritical Combustion

Abstract Fossil fuel based direct-fired supercritical CO2 (sCO2) cycles are gaining the attention of industry, academia, and government due to their remarkable efficiency and carbon capture at high-source temperatures. Modeling plays an important role in the development of sCO2 combustors because experiments are very expensive at the designed operating conditions of these direct-fired cycles. Inaccurate density estimates are detrimental to the simulation output. Hence, this work focuses on comprehensive evaluation of the influence and applicability of various equation-of-states (EOS) which are being used in the supercritical combustion modeling literature. A state-of-the-art supercritical combustion modeling methodology is used to simulate counter-flow supercritical CO2 flames by using various equation-of-states. The results show that using the corresponding state principle to evaluate compressibility factor is not accurate. Also, van der Waal type EOSs predictions can be as accurate as complex Benedict–Webb–Rubin EOSs; hence van der Waal EOSs are more suitable to simulate sCO2 combustor simulations. Non-ideal effects are significant under the operating conditions considered in this work. The choice of EOS significantly influences the flame structure and heat release rate. Also, assuming the binary interaction parameter as zero is reasonable in sCO2 combustion simulations.

Influence of Equation-of-States on Supercritical CO2 Combustion

2020 ◽  
Author(s):  
K. R. V. (Raghu) Manikantachari ◽  
Scott M. Martin ◽  
Ramees K. Rahman ◽  
Carlos Velez ◽  
Subith S. Vasu
Keyword(s):  
Supercritical Co2 ◽  
Carbon Capture ◽  
Flame Structure ◽  
Compressibility Factor ◽  
Operating Conditions ◽  
Binary Interaction ◽  
Binary Interaction Parameter ◽  
Combustion Modeling ◽  
Equation Of States ◽  
Supercritical Combustion

Abstract Fossil fuel based direct-fired supercritical CO2 (sCO2) cycles are gaining the attention of industry, academia and government due to their remarkable efficiency and carbon capture at high-source temperatures. Modeling plays an important role in the development of sCO2 combustors because experiments are very expensive at the designed operating conditions of these direct-fired cycles. Inaccurate density estimates are detrimental to the simulation output. Hence, this work focuses on comprehensive evaluation of the influence and applicability various equation-of-states (EOS) which are being used in the supercritical combustion modeling literature. A state-of-the-art supercritical combustion modeling methodology is used to simulate counter-flow supercritical CO2 flames by using various equation-of-states. The results show that, using the corresponding state principle to evaluate compressibility factor is not accurate. Also, van der Waal type EOSs predictions can be as accurate as complex Benedict-Webb-Rubin EOSs; hence van der Waal EOSs are more suitable to simulate sCO2 combustor simulations. Non-ideal effects are significant under the operating conditions considered in this work. The choice of EOS significantly influences the flame structure and heat release rate. Also, assuming the binary interaction parameter as zero is reasonable in sCO2 combustion simulations.

scholarly journals Numerical Investigation of Turbulent Premixed Combustion of Methane / Air in Low Swirl Burner under Elevated Pressures and Temperatures

2021 ◽  
Vol 39 (1) ◽  
pp. 155-160
Author(s):  
Akram Ben Ali ◽  
Mansour Karkoub ◽  
Mouldi Chrigui
Keyword(s):  
Flame Structure ◽  
Elevated Pressure ◽  
Operating Conditions ◽  
Premixed Combustion ◽  
Combustion Model ◽  
Swirl Burner ◽  
Combustion Modeling ◽  
Eddy Simulation ◽  
Elevated Pressures ◽  
First Case

Turbulent combustion modeling of lean premixed methane/air gas mixture in a low swirl burner is carried out using Large Eddy Simulation (LES). The operating conditions of the experiment as well as simulation are carried out at elevated pressure and temperature. The first case-simulation is a premixed combustion model based on C-equation formulation, the second one is based on species transport – Eddy Dissipation Concept (EDC) model. Numerical results for axial velocity and turbulence intensity along the centerline showed a good agreement against the experimental data. Quantitative results of OH mass fraction contour showing the flame structure are in a plausible agreement compared to the experimental measurement.

scholarly journals Modelling Sorption Thermodynamics and Mass Transport of n-Hexane in a Propylene-Ethylene Elastomer

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1157
Author(s):  
Daniele Tammaro ◽  
Lorenzo Lombardi ◽  
Giuseppe Scherillo ◽  
Ernesto Di Maio ◽  
Navanshu Ahuja ◽  
...  
Keyword(s):  
Mass Transport ◽  
Interaction Parameter ◽  
Sorption Isotherms ◽  
Binary Interaction ◽  
Binary Interaction Parameter ◽  
Theoretical Interpretation ◽  
Sorption Behavior ◽  
Solvent Mixtures ◽  
Random Lattice ◽  
Hexane Vapor

Optimization of post polymerization processes of polyolefin elastomers (POE) involving solvents is of considerable industrial interest. To this aim, experimental determination and theoretical interpretation of the thermodynamics and mass transport properties of POE-solvent mixtures is relevant. Sorption behavior of n-hexane vapor in a commercial propylene-ethylene elastomer (V8880 VistamaxxTM from ExxonMobil, Machelen, Belgium) is addressed here, determining experimentally the sorption isotherms at temperatures ranging from 115 to 140 °C and pressure values of n-hexane vapor up to 1 atm. Sorption isotherms have been interpreted using a Non Random Lattice Fluid (NRLF) Equation of State model retrieving, from data fitting, the value of the binary interaction parameter for the n-hexane/V8880 system. Both the cases of temperature-independent and of temperature-dependent binary interaction parameter have been considered. Sorption kinetics was also investigated at different pressures and has been interpreted using a Fick’s model determining values of the mutual diffusivity as a function of temperature and of n-hexane/V8880 mixture composition. From these values, n-hexane intra-diffusion coefficient has been calculated interpreting its dependence on mixture concentration and temperature by a semi-empiric model based on free volume arguments.

scholarly journals Viscosity Data of Aqueous MDEA–[Bmim][BF 4 ] Solutions Within Carbon Capture Operating Conditions

2017 ◽  
Vol 105 ◽  
pp. 4581-4586 ◽  
Author(s):  
Worrada Nookuea ◽  
Fu Wang ◽  
Jie Yang ◽  
Yuting Tan ◽  
Hailong Li ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Operating Conditions ◽  
Viscosity Data

Finite Element Volume Analysis of Propane Preheated Air Flame Passing Through a Minichannel

2014 ◽  
Author(s):  
Masoud Darbandi ◽  
Majid Ghafourizadeh ◽  
Gerry E. Schneider
Keyword(s):  
Finite Element ◽  
Radiation Effects ◽  
Mixture Fraction ◽  
Flame Structure ◽  
Current Method ◽  
Reacting Flow ◽  
Wall Functions ◽  
Flamelet Model ◽  
Combustion Modeling ◽  
Detailed Kinetics

A hybrid finite-element-volume FEV method is extended to simulate turbulent non-premixed propane air preheated flame in a minichannel. We use a detailed kinetics scheme, i.e. GRI mechanism 3.0, and the flamelet model to perform the combustion modeling. The turbulence-chemistry interaction is taken into account in this flamelet modeling using presumed shape probability density functions PDFs. Considering an upwind-biased physics for the current reacting flow, we implement the physical influence upwinding scheme PIS to estimate the cell-face mixture fraction variance in this study. To close the turbulence closure, we employ the two-equation standard κ-ε turbulence model incorporated with suitable wall functions. Supposing an optically thin limit, it needs to take into account radiation effects of the most important radiating species in the current modeling. Despite facing with so many flame instabilities in such small size configuration, the current method performs suitably with proper convergence, and the encountered instabilities are damped out automatically. Comparing with the experimental measurements, the current extended method accurately predicts the flame structure in the minichannel configuration.

Designing CO2 Transmission Pipelines Without Crack Arrestors

2010 ◽  
Author(s):  
Graeme G. King ◽  
Satish Kumar
Keyword(s):  
Wall Thickness ◽  
Carbon Capture ◽  
Power Plants ◽  
Oil And Gas ◽  
Cost Optimization ◽  
Operating Conditions ◽  
Operating Pressure ◽  
Design Work ◽  
Industrial Facilities ◽  
Pipeline Network

Masdar is developing several carbon capture projects from power plants, smelters, steel works, industrial facilities and oil and gas processing plants in Abu Dhabi in a phased series of projects. Captured CO2 will be transported in a new national CO2 pipeline network with a nominal capacity of 20×106 T/y to oil reservoirs where it will be injected for reservoir management and sequestration. Design of the pipeline network considered three primary factors in the selection of wall thickness and toughness, (a) steady and transient operating conditions, (b) prevention of longitudinal ductile fractures and (c) optimization of total project owning and operating costs. The paper explains how the three factors affect wall thickness and toughness. It sets out code requirements that must be satisfied when choosing wall thickness and gives details of how to calculate toughness to prevent propagation of long ductile fracture in CO2 pipelines. It then uses cost optimization to resolve contention between the different requirements and arrive at a safe and economical pipeline design. The design work selected a design pressure of 24.5 MPa, well above the critical point for CO2 and much higher than is normally seen in conventional oil and gas pipelines. Despite its high operating pressure, the proposed network will be one of the safest pipeline systems in the world today.

Preliminarily Design of Supercritical CO2 Compression Test System

2021 ◽  
Author(s):  
Geng Teng ◽  
Laijie Chen ◽  
Xin Shen ◽  
Hua Ouyang ◽  
Yubo Zhu ◽  
...  
Keyword(s):  
Simulation Model ◽  
Compression Test ◽  
Thermodynamic Model ◽  
Supercritical Co2 ◽  
Operating Performance ◽  
Test System ◽  
Operating Conditions ◽  
Working Fluid ◽  
Stable Operation ◽  
Test Loop

Abstract The centrifugal compressor is the core component of the supercritical carbon dioxide (SCO2) power cycle. It is essential to carry out component-level experimental research on it and test the working characteristics of the compressor and its auxiliary equipment. Building an accurate closed-loop simulation model of closed SCO2 compression loop is a necessary preparation for selecting loop key parameters and establishing system control strategy, which is also an important prerequisite for the stable operation of compressor under test parameters. In this paper, the thermodynamic model of compressor, pre-cooler, orifice plate and other components in supercritical CO2 compression test system is studied, and the simulation model of compression test system is established. Moreover, based on the system enthalpy equations and physical property model of real gas, the compressor, pre-cooler and other components in the test loop are preliminarily designed by using the thermodynamic model of components. Since the operating conditions are in the vicinity of the critical point, when the operating conditions change slightly, the physical properties of the working fluid will change significantly, which might have a greater impact on the operating performance of the system. So the operating performance and the parameter changes of key nodes in the test loop under different operating conditions are calculated, which will provide theoretical guidance for the construction of subsequent experimental loops.

A Comprehensive Review of Recent Advances in the Estimation of Natural Gas Compressibility Factor

2021 ◽  
Author(s):  
Oluwasegun Cornelious Omobolanle ◽  
Oluwatoyin Olakunle Akinsete
Keyword(s):  
Artificial Intelligence ◽  
Equation Of State ◽  
Compressibility Factor ◽  
Operating Conditions ◽  
Measurement Equation ◽  
Comprehensive Review ◽  
Holistic Understanding ◽  
Deviation Factor ◽  
Gas Compressibility ◽  
Limited Accuracy

Abstract Accurate prediction of gas compressibility factor is essential for the evaluation of gas reserves, custody transfer and design of surface equipment. Gas compressibility factor (Z) also known as gas deviation factor can be evaluated by experimental measurement, equation of state and empirical correlation. However, these methods have been known to be expensive, complex and of limited accuracy owing to the varying operating conditions and the presence of non-hydrocarbon components in the gas stream. Recently, newer correlations with extensive application over wider range of operating conditions and crude mixtures have been developed. Also, artificial intelligence is now being deployed in the evaluation of gas compressibility factor. There is therefore a need for a holistic understanding of gas compressibility factor vis-a-vis the cause-effect relations of deviation. This paper presents a critical review of current understanding and recent efforts in the estimation of gas deviation factor.

Numerical Approach for Real Gas Simulations: Part II — Flow Simulation for Supercritical CO2 Centrifugal Compressor

2017 ◽  
Author(s):  
Swati Saxena ◽  
Ramakrishna Mallina ◽  
Francisco Moraga ◽  
Douglas Hofer
Keyword(s):  
Critical Point ◽  
Centrifugal Compressor ◽  
Supercritical Co2 ◽  
Operating Conditions ◽  
Inlet Guide Vane ◽  
Thermodynamic Quantities ◽  
3D Flow ◽  
Real Gas ◽  
The Real ◽  
Operating Range

This paper is presented in two parts. Part I (Tabular fluid properties for real gas analysis) describes an approach to creating a tabular representation of the equation of state that is applicable to any fluid. This approach is applied to generating an accurate and robust tabular representation of the RefProp CO2 properties. Part II (this paper) presents numerical simulations of a low flow coefficient supercritical CO2 centrifugal compressor developed for a closed loop power cycle. The real gas tables presented in part I are used in these simulations. Three operating conditions are simulated near the CO2 critical point: normal day (85 bar, 35C), hot day (105 bar, 50 C) and cold day (70 bar, 20C) conditions. The compressor is a single stage overhung design with shrouded impeller, 155 mm impeller tip diameter and a vaneless diffuser. An axial variable inlet guide vane (IGV) is used to control the incoming swirl into the impeller. An in-house three-dimensional computational fluid dynamics (CFD) solver named TACOMA is used with real gas tables for the steady flow simulations. The equilibrium thermodynamic modeling is used in this study. The real gas effects are important in the desired impeller operating range. It is observed that both the operating range (minimum and maximum volumetric flow rate) and the pressure ratio across the impeller are dependent on the inlet conditions. The compressor has nearly 25% higher operating range on a hot day as compared to the normal day conditions. A condensation region is observed near the impeller leading edge which grows as the compressor operating point moves towards choke. The impeller chokes near the mid-chord due to lower speed of sound in the liquid-vapor region resulting in a sharp drop near the choke side of the speedline. This behavior is explained by analyzing the 3D flow field within the impeller and thermodynamic quantities along the streamline. The 3D flow analysis for the flow near the critical point provides useful insight for the designers to modify the current compressor design for higher efficiency.

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