scholarly journals Effects of Vitiation on Axial Catalyst Bed Temperature Profiles

Author(s):  
I. T. Osgerby ◽  
B. A. Olson ◽  
H. G. Lew ◽  
A. Cohn

Studies have been conducted at Engelhard Research Laboratories under an EPRI sponsored subcontract from Westinghouse to experimentally determine performance characteristics of Catcom* catalysts at simulated gas turbine combustion conditions using No. 2 fuel. A comparison study was carried out using a 1-in. diameter laboratory reactor and a 9-in, diameter burner. 5-in. and 6-in, catalysts lengths were tested in the laboratory reactor and the 6-in, length in the burner. Effects of vitiated versus indirect preheat were investigated together with varying adiabatic flame temperature (based on fuel/air ratios), catalyst inlet reference velocity and catalyst length. Process variable upset conditions were simulated in the 9-in, burner and over fueling was simulated in the 1-in. reactor. The temperature profiles, combustion efficiencies and pressure drop data obtained can be used to assess performance of anticipated catalytic combustor designs for gas turbine systems. These results continue to show that CATCOM catalysts and the Catathermal* mode of combustion can be applied practically to large scale gas turbine equipment.

1978 ◽  
Vol 100 (3) ◽  
pp. 508-513 ◽  
Author(s):  
J. L. Hodges ◽  
R. C. Hoke ◽  
R. Bertrand

Data acquired in the Exxon Research and Engineering Company’s fluid bed boiler program indicate that the arrangement and orientation of internal boiler tubes has a strong effect on the measured bed temperature profile. Horizontally oriented tubes yield much steeper temperature gradients than do vertical tubes. Excessive vertical temperature gradients in coal fired fluid bed boilers can either limit coal feed rates or result in the formation of agglomerates of solid material which are destructive of bed internals. This study represents an attempt to understand the influence of orientation on vertical temperature profiles in fluid bed boilers. A back-mixing model for solids recirculation was developed and applied to the prediction of bed temperatures. Bubbling bed theory is not suitable for estimating solids circulation rates in pressurized beds of large particles with immersed tubes. However, by introducing the concept of a solids mixing height it was possible to estimate solid movement. The solids mixing height and vertical boiler tube dimensions were correlated in a manner which resulted in good agreement between theoretical and experimental bed temperature profiles. It is felt that this simple model may prove quite useful in the design of large scale commercial fluid bed boilers.


Author(s):  
D. N. Anderson

Three noble-metal monolithic catalysts were tested in a 12-cm-dia combustion test rig to obtain emissions and performance data at conditions simulating the operation of a catalytic combustor for an automotive gas turbine engine. Tests with one of the catalysts at 800 K inlet mixture temperature, 3 × 105 Pa (3 atm) pressure, and a reference velocity (catalyst bed inlet velocity) of 10 m/sec demonstrated greater than 99 percent combustion efficiency for reaction temperatures higher than 1300 K. With a reference velocity of 25 m/sec the reaction temperature required to achieve the same combustion efficiency increased to 1380 K. The exit temperature pattern factors for all three catalysts were below 0.1 when adiabatic reaction temperatures were higher than 1400 K. The highest pressure drop was 4.5 percent at 25 m/sec reference velocity. Nitrogen oxides emissions were less than 0.1 g NO2/kg fuel for all test conditions.


Author(s):  
G. C. Snow ◽  
S. L. Pessagno

Catalytic combustion has demonstrated the ability to provide low NOx emissions while maintaining high combustion efficiency. Recently, under joint NASA Lewis, EPA, and Acurex sponsorship, a catalytic reactor was tested for 1000 hours to demonstrate durability in combustion environments representative of advanced automotive gas turbine engines. At a 740K air preheat temperature and a propane fuel/air ratio of 0.028 by mass (ϕFA = 0.44), the adiabatic flame temperature was held at about 1700K. The graded cell monolithic reactor measured 5 cm in diameter by 10.2 cm in length and was operated at a reference velocity of 13.4 m/s at 1 atmosphere pressure. Measured NOx levels remained below 5 ppm while unburned hydrocarbon concentrations registered near zero and carbon monoxide levels were nominally below 20 ppm. The durability test included several parametric turndown studies and ended with a series of on/off cycling tests to further characterize reactor performance.


Author(s):  
Pablo Diaz Gomez Maqueo ◽  
Philippe Versailles ◽  
Gilles Bourque ◽  
Jeffrey M. Bergthorson

This study investigates the increase in methane and biogas flame reactivity enabled by the addition of syngas produced through fuel reforming. To isolate thermodynamic and chemical effects on the reactivity of the mixture, the burner simulations are performed with a constant adiabatic flame temperature of 1800 K. Compositions and temperatures are calculated with the chemical equilibrium solver of CANTERA® and the reactivity of the mixture is quantified using the adiabatic, freely-propagating premixed flame, and perfectly-stirred reactors of the CHEMKIN-Pro® software package. The results show that the produced syngas has a content of up to 30 % H2 with a temperature up to 950 K. When added to the fuel, it increases the laminar flame speed while maintaining a burning temperature of 1800 K. Even when cooled to 300 K, the laminar flame speed increases up to 30 % from the baseline of pure biogas. Hence, a system can be developed that controls and improves biogas flame stability under low reactivity conditions by varying the fraction of added syngas to the mixture. This motivates future experimental work on reforming technologies coupled with gas turbine exhausts to validate this numerical work.


Author(s):  
Yonatan Cadavid ◽  
Andres Amell ◽  
Juan Alzate ◽  
Gerjan Bermejo ◽  
Gustavo A. Ebratt

The wet compressor (WC) has become a reliable way to reduce gas emissions and increase gas turbine efficiency. However, fuel source diversification in the short and medium terms presents a challenge for gas turbine operators to know how the WC will respond to changes in fuel composition. For this study, we assessed the operational data of two thermal power generators, with outputs of 610 MW and 300 MW, in Colombia. The purpose was to determine the maximum amount of water that can be added into a gas turbine with a WC system, as well as how the NOx/CO emissions vary due to changes in fuel composition. The combustion properties of different gaseous hydrocarbon mixtures at wet conditions did not vary significantly from each other—except for the laminar burning velocity. It was found that the fuel/air equivalence ratio in the turbine reduced with lower CH4 content in the fuel. Less water can be added to the turbine with leaner combustion; the water/fuel ratio was decreased over the range of 1.4–0.4 for the studied case. The limit is mainly due to a reduction in flame temperature and major risk of lean blowout (LBO) or dynamic instabilities. A hybrid reaction mechanism was created from GRI-MECH 3.0 and NGIII to model hydrocarbons up to C5 with NOx formation. The model was validated with experimental results published previously in literature. Finally, the effect of atmospheric water in the premixed combustion was analyzed and explained.


1974 ◽  
Vol 96 (1) ◽  
pp. 32-48 ◽  
Author(s):  
W. R. Wade ◽  
P. I. Shen ◽  
C. W. Owens ◽  
A. F. McLean

This first part, of a two part paper, reviews the NOx emission problem of the regenerative gas turbine engine for automotive application. It discusses the problem of fuel droplet burning, which causes heterogenous combustion with resulting high flame temperatures and high levels of oxides of nitrogen. The paper proposes means to achieve homogeneous combustion and shows that, even with this approach, flame temperatures need to be closely controlled to effect a compromise between NOx, CO, and HC emissions in order to meet the stringent numerical levels of emissions specified by the Federal standards for 1976 and subsequent model year automobiles. The paper shows that combustor inlet temperature of a homogeneous system has little effect, theoretically, on computed NOx emissions expressed as grams per mile, thereby strengthening the case for the regenerative turbine engine. A design concept for homogeneous combustion with controlled flame temperature is discussed.


2021 ◽  
Author(s):  
Daniele Pampaloni ◽  
Antonio Andreini ◽  
Alessandro Marini ◽  
Giovanni Riccio ◽  
Gianni Ceccherini

Abstract Thermoacoustic characterization of gas turbine combustion systems is of primary importance for successful development of gas turbine technology, to meet the stringent targets on pollutant emissions. In this context, it becomes more and more necessary to develop reliable tools to be used in the industrial design process. The dynamics of a lean-premixed full-annular combustor for heavy-duty applications has been numerically studied in this work. The well-established CFD-SI method has been used to investigate the flame response varying operational parameters such as the flame temperature (global equivalence ratio) and the fuel split between premixed and pilot fuel injections: such a wide range experimental characterization represents an opportunity to validate the employed numerical methods and to give a deeper insight into the flame dynamics. URANS simulations have been performed, due to their affordable computational costs from the industrial perspective, after validating their accuracy through the comparison against LES results. Furthermore, an approach where the pilot and the premixed flame responses are analyzed separately is proposed, exploiting the independence of their evolution. The calculated FTFs have been implemented in a 3D FEM model of the chamber, in order to perform linear stability analysis and to validate the numerical approach. A boundary condition for rotational periodicity based on Bloch-Wave theory has been implemented into the Helmholtz solver and validated against full-annular chamber simulations, allowing a significant reduction in computational time. The reliability of the numerical procedure has been assessed through the comparison against full-annular experimental results.


Author(s):  
Daniel Moëll ◽  
Daniel Lörstad ◽  
Annika Lindholm ◽  
David Christensen ◽  
Xue-Song Bai

DLE (Dry Low Emission) technology is widely used in land based gas turbines due to the increasing demands on low NOx levels. One of the key aspects in DLE combustion is achieving a good fuel and air mixing where the desired flame temperature is achieved without too high levels of combustion instabilities. To experimentally study fuel and air mixing it is convenient to use water along with a tracer instead of air and fuel. In this study fuel and air mixing and flow field inside an industrial gas turbine burner fitted to a water rig has been studied experimentally and numerically. The Reynolds number is approximately 75000 and the amount of fuel tracer is scaled to represent real engine conditions. The fuel concentration in the rig is experimentally visualized using a fluorescing dye in the water passing through the fuel system of the burner and recorded using a laser along with a CCD (Charge Couple Device) camera. The flow and concentration field in the burner is numerically studied using both the scale resolving SAS (Scale Adaptive Simulation) method and the LES (Large Eddy Simulation) method as well as using a traditional two equation URANS (Unsteady Reynolds Average Navier Stokes) approach. The aim of this study is to explore the differences and similarities between the URANS, SAS and LES models when applied to industrial geometries as well as their capabilities to accurately predict relevant features of an industrial burner such as concentration and velocity profiles. Both steady and unsteady RANS along with a standard two equation turbulence model fail to accurately predict the concentration field within the burner, instead they predict a concentration field with too sharp gradients, regions with almost no fuel tracer as well as regions with far too high concentration of the fuel tracer. The SAS and LES approach both predict a more smooth time averaged concentration field with the main difference that the tracer profile predicted by the LES has smoother gradients as compared to the tracer profile predicted by the SAS. The concentration predictions by the SAS model is in reasonable agreement with the measured concentration fields while the agreement for the LES model is excellent. The LES shows stronger fluctuations in velocity over time as compared to both URANS and SAS which is due to the reduced amounts of eddy viscosity in the LES model as compared to both URANS and SAS. This study shows that numerical methods are capable of predicting both velocity and concentration in a gas turbine burner. It is clear that both time and scale resolved methods are required to accurately capture the flow features of this and probably most industrial DLE gas turbine burners.


Author(s):  
Tomoki Taniguchi ◽  
Ryoji Tamai ◽  
Yoshihiko Muto ◽  
Satoshi Takami ◽  
Ryozo Tanaka ◽  
...  

Kawasaki Heavy Industries, Ltd (KHI) has started a comprehensive program to further improve performance and availability of existing Kawasaki gas turbines. In the program, one of the Kawasaki’s existing gas turbine was selected from the broad product line and various kinds of technology were investigated and adopted to further improve its thermal performance and availability. The new technologies involve novel film cooling of turbine nozzles, advanced and large-scale numerical simulations, new thermal barrier coating. The thermal performance target is combined cycle efficiency of 51.6% and the target ramp rate is 20% load per minute. The program started in 2015 and engine testing has just started. In this paper, details of the program are described, focusing on design procedure.


Author(s):  
G. Arvind Rao ◽  
Yeshayahou Levy ◽  
Ephraim J. Gutmark

Flameless combustion (FC) is one of the most promising techniques of reducing harmful emissions from combustion systems. FC is a combustion phenomenon that takes place at low O2 concentration and high inlet reactant temperature. This unique combination results in a distributed combustion regime with a lower adiabatic flame temperature. The paper focuses on investigating the chemical kinetics of an prototype combustion chamber built at the university of Cincinnati with an aim of establishing flameless regime and demonstrating the applicability of FC to gas turbine engines. A Chemical reactor model (CRM) has been built for emulating the reactions within the combustor. The entire combustion chamber has been divided into appropriate number of Perfectly Stirred Reactors (PSRs) and Plug Flow Reactors (PFRs). The interconnections between these reactors and the residence times of these reactors are based on the PIV studies of the combustor flow field. The CRM model has then been used to predict the combustor emission profile for various equivalence ratios. The results obtained from CRM model show that the emission from the combustor are quite less at low equivalence ratios and have been found to be in reasonable agreement with experimental observations. The chemical kinetic analysis gives an insight on the role of vitiated combustion gases in suppressing the formation of pollutants within the combustion process.


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