U.S. Operating Experience With Thermally Treated Alloy 600 Steam Generator Tubes

Author(s):  
April Smith ◽  
Kenneth J. Karwoski

Steam generators placed in service in the 1960s and 1970s were primarily fabricated from mill-annealed Alloy 600. Over time, this material proved to be susceptible to stress corrosion cracking in the highly pure primary and secondary water chemistry environments of pressurized-water reactors. The corrosion ultimately led to the replacement of steam generators at numerous facilities, the first U.S. replacement occurring in 1980. Many of the steam generators placed into service in the 1980s used tubes fabricated from thermally treated Alloy 600. This tube material was thought to be less susceptible to corrosion. Because of the safety significance of steam generator tube integrity, this paper evaluates the operating experience of thermally treated Alloy 600 by looking at the extent to which it is used and recent results from steam generator tube examinations.

Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 899 ◽  
Author(s):  
Soon-Hyeok Jeon ◽  
Geun Song ◽  
Do Hur

In secondary coolant system of the pressurized water reactors, the reduced corrosion products such as metallic Cu and Pb particles were accumulated in the pores of the magnetite flakes and electrically contacted to the steam generator materials. The micro-galvanic corrosion behavior of steam generator materials (steam generator tube materials: Alloy 600 and Alloy 690, steam generator tube sheet materials: SA508 Gr.3) contacted to the corrosion products (magnetite, Cu, and Pb) was investigated in an alkaline solution. The steam generator materials considered in this study were all the anodic elements of the galvanic pair because their corrosion potentials were lower than those of the corrosion products. The corrosion rate of the steam generator materials was increased by the galvanic coupling with the each corrosion products, and was more accelerated with increasing the area ratio of the corrosion products to the steam generator materials. Among the corrosion products, Cu has the largest galvanic effect on steam generator materials in the pores when area ratio of cathode to anode is 10.


2005 ◽  
Vol 475-479 ◽  
pp. 1387-1392 ◽  
Author(s):  
Jesse Lumsden ◽  
Allan McIlree ◽  
Richard Eaker ◽  
Rocky Thompson ◽  
Steve Slosnerick

Intergranular attack/stress corrosion cracking of Alloy 600 continues to be an issue in the tube/tube support plate crevices and top of tubesheet locations of recirculating steam generators and in the upper bundle of free span superheated regions of once through steam generators (OTSG). Recent examinations of degraded pulled tubes from several plants suggest possible lead involvement in the degradation. Laboratory investigations have been performed to determine the factors influencing lead cracking in Alloy 600 and Alloy 690 steam generator tubes. The test environment is believed to be prototypical, with the addition of lead oxide, of a concentrated liquid phase existing in the pores of thin deposits on upper bundle tubes of an OTSG. Highly strained reverse U-bend specimens were tested at controlled electrochemical potentials. Maximum susceptibility was at open circuit potential, unlike cracking of Alloy 600 in caustic and acid sulfate environments where maximum susceptibility occurs when specimens are polarized above the open circuit potential. Transgranular, intergranular and mixed mode cracking was observed and in all Alloy 600 conditions tested (mill annealed, sensitized, thermally treated) while thermally treated Alloy 690 has so far resisted cracking. A film rupture/anodic dissolution model with displacement plating of Pb preceding passive film formation is consistent with the experimental observations


Kerntechnik ◽  
2020 ◽  
Vol 85 (1) ◽  
pp. 54-67
Author(s):  
A. Hamedani ◽  
O. Noori-Kalkhoran ◽  
R. Ahangari ◽  
M. Gei

Abstract Steam generators are one of the most important components of pressurized-water reactors. This component plays the role of heat transfer and pressure boundary between primary and secondary side fluids. The Once Through Steam Generator (OTSG) is an essential component of the integrated nuclear power system. In this paper, steady-state analysis of primary and secondary fluids in the Integral Economizer Once Through Steam Generator (IEOTSG) have been presented by Single Heated Channel (SHC) and subchannel modelling. Models have been programmed by MATLAB and FORTRAN. First, SHC model has been used for this purpose (changes are considered only in the axial direction in this model). Second, the subchannel approach that considers changes in the axial and also radial directions has been applied. Results have been compared with Babcock and Wilcox (B&W) 19- tube once through steam generator experimental data. Thermal- hydraulic profiles have been presented for steam generator using both of models. Accuracy and simplicity of SHC model and importance of localization of thermal-hydraulic profiles in subchannel approach have been proved.


Author(s):  
Christian Phalippou ◽  
Franck Ruffet ◽  
Emmanuel Herms ◽  
François Balestreri

Flow-induced vibrations of steam generator tubes in nuclear power plants may result in wear damage at support locations. The steam generators in EPR power plants have a design life of 60 years; as wear is an identified ageing damage in steam generators, it is therefore important to collect experimental results on wear of tube and support due to dynamic interactions at EPR secondary side temperature. In this study, wear tests were performed between a steam generator tube (Alloy 690) and two flat opposite anti-vibration bars (AVB in 410s stainless steel) at different impact force levels. Tests were performed in pressurized water at 290°C in wear machines for long term repeated predominant impact motions. The worn surfaces were observed by SEM, the wear coefficients of tube and AVB were evaluated using the work rate approach. Significant scoring, due to the importance of sliding when impacts occur, was shown on wear scar patterns. There were greater wear volumes and depths on tubes than on AVBs, but dynamic forced conditions and rigid mounting of AVB in the rigs have prevailed for finally getting an upper bound of the wear rates. Alloy 690 for tubes and 410s for AVB remain a satisfactory material combination considering comparative wear results with other published data.


Author(s):  
Jongmin Kim ◽  
Min-Chul Kim ◽  
Joonyeop Kwon

Abstract The materials used previously for steam generator tubes around the world have been replaced and will be replaced by Alloy 690 given its improved corrosion resistance relative to that of Alloy 600. However, studies of the high- temperature creep and creep-rupture characteristics of steam generator tubes made of Alloy 690 are insufficient compared to those focusing on Alloy 600. In this study, several creep tests were conducted using half tube shape specimens of the Alloy 690 material at temperatures ranging from 650 to 850C and stresses in the range of 30 to 350 MPa, with failure times to creep rupture ranging from 3 to 870 hours. Based on the creep test results, creep life predictions were then made using the well-known Larson Miller Parameter method. Steam generator tube rupture tests were also conducted under the conditions of a constant temperature and pressure ramp using steam generator tube specimens. The rupture test equipment was designed and manufactured to simulate the transient state (rapid temperature and pressure changes) in the event of a severe accident condition. After the rupture test, the damage to the steam generator tubes was predicted using a creep rupture model and a flow stress model. A modified creep rupture model for Alloy 690 steam generator tube material is proposed based on the experimental results. A correction factor of 1.7 in the modified creep rupture model was derived for the Alloy 690 material. The predicted failure pressure was in good agreement with the experimental failure pressure.


2021 ◽  
Vol 1016 ◽  
pp. 819-825
Author(s):  
Li Na Yu ◽  
Kazuyoshi Saida ◽  
Masahito Mochizuki ◽  
Kazutoshi Nishimoto ◽  
Naoki Chigusa

Stress corrosion cracking (SCC) is one of serious aging degradation problems for the Alloy 600 components of pressurized water reactors (PWRs). In order to prevent SCC, various methods such as water jet peening (WJP), laser peening (LP), surface polishing have been used to introduce compressive stresses at the surfaces of the PWR components. However, it has been reported that such compressive residual stress introduced by these methods might be relaxed during the practical operation, because of high temperature environment. In this study, the hardness reduction behavior of the Alloy 600 processed by LP, Buff and WJP in the thermal aging process has been investigated to estimate the stability of the residual stress improving effect by each method, based on the fact that there is a correlation between the compressive residual stress relaxation and the decrease of hardness. The behavior of the residual stress relaxation in the processed materials in the high temperature environment has been discussed with kinetic analysis.


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