The Effect of H2S on Production of Carbon Black From Sub-Quality Natural Gas

2008 ◽  
Author(s):  
M. Moghiman ◽  
M. Javadi ◽  
M. H. Raad ◽  
N. Hosseini ◽  
M. Soleimani
Keyword(s):  
Natural Gas ◽  
Carbon Black ◽  
Flow Rate ◽  
Soot Formation ◽  
Mass Density ◽  
Mixture Fraction ◽  
Reaction Model ◽  
Particle Number Density ◽  
Reactor Temperature ◽  
Carbon Black Production

The objective of this paper is computational investigation of the carbon black production through thermal decomposition of waste gases containing CH4 and H2S, without requiring a H2S separation process. The chemical reaction model, which involves solid carbon, sulfur compounds and precursor species for formation carbon black, based on an assumed Probability Density Function (PDF) parameterized by the mean and variance of mixture fraction and β-PDF shape. The soot formation is modeled by using the soot particle number density and the mass density based on acetylene concentrations. The effects of feedstock mass flow rate and reactor temperature on carbon black, soot, CO, S2, SO2, COS and CS2 formation are investigated. The results show that the major factor influencing CH4 and H2S conversions is reactor temperature. The results reveal that at any temperature, H2S conversion is less than that of CH4. For temperatures higher than 1100°K, the reactor CH4 conversion reaches 100%. At temperatures below 1300°K, H2S conversion is too low and usually less than 5%. For temperatures higher than 1300°K, H2S conversion increases sharply with temperature and the major products of the process are S2 and SO2 while COS and CS2 are minor products. The results also show that the production of carbon black from sub-quality natural gas, process involving the formation of carbon monoxide which is occurring in parallel, play a very significant role. For lower values of feedstock flow rate, CH4 mostly burns to CO and consequently, the production of carbon black is low.

The Effect of H2S on Hydrogen and Carbon Black Production from Sour Natural Gas

2011 ◽  
Vol 110-116 ◽  
pp. 2131-2138
Author(s):  
Mostafa Tazimi ◽  
Seyyed Mohammad Javadi ◽  
S. Sobhan Nabavi
Keyword(s):  
Natural Gas ◽  
Carbon Black ◽  
Chemical Reactions ◽  
Flow Reactor ◽  
Influencing Factor ◽  
Axial Flow ◽  
Small Scale ◽  
Reactor Temperature ◽  
Carbon Black Production ◽  
Sour Gas

Hydrogen and carbon black production via thermal decomposition of natural gas have been achieved using a carbon black furnace. Direct heat transfer from inert hot gases (argon) introduced into sour gas. The carbon black furnace is a small-scale axial flow reactor. There are 3 main chemical reactions through which carbon black is produced. Finally results indicate that the most influencing factor over these chemical reactions and CH4 and H2S conversions is reactor temperature.

Numerical Analysis of Carbon Black Production from Sub‐Quality Natural Gas

2008 ◽  
Author(s):  
M. Moghiman ◽  
M. Javadi ◽  
M. H. Ghodsirad ◽  
N. Hosseini ◽  
M. Soleimani
Keyword(s):  
Numerical Analysis ◽  
Natural Gas ◽  
Carbon Black ◽  
Carbon Black Production

Effect of Raw-Fuel Flow Rate on Soot Formation Reaction in Carbon Black Furnace.

1998 ◽  
Vol 31 (2) ◽  
pp. 244-252 ◽  
Author(s):  
Shinji Hayashi ◽  
Yutaka Hisaeda ◽  
Hideyuki Aoki ◽  
Takatoshi Miura ◽  
Tomohiko Furuhata ◽  
...  
Keyword(s):  
Carbon Black ◽  
Flow Rate ◽  
Soot Formation ◽  
Fuel Flow Rate ◽  
Formation Reaction ◽  
Fuel Flow

Novel epoxy/anhydride alternatives for biological electron microscopy: Physical and performance characteristis of embed 812 and LX 112 in combination with NSA/NMA/DMAE

1989 ◽  
Vol 47 ◽  
pp. 1000-1001
Author(s):  
Joe A. Mascorro ◽  
Gerald S. Kirby
Keyword(s):  
Electron Microscopy ◽  
Flow Rate ◽  
Succinic Anhydride ◽  
Volume Flow Rate ◽  
Mass Density ◽  
Uranyl Acetate ◽  
Volume Flow ◽  
Base Resin ◽  
And Performance ◽  
Acid Anhydrides

Embedding media based upon an epoxy resin of choice and the acid anhydrides dodecenyl succinic anhydride (DDSA), nadic methyl anhydride (NMA), and catalyzed by the tertiary amine 2,4,6-Tri(dimethylaminomethyl) phenol (DMP-30) are widely used in biological electron microscopy. These media possess a viscosity character that can impair tissue infiltration, particularly if original Epon 812 is utilized as the base resin. Other resins that are considerably less viscous than Epon 812 now are available as replacements. Likewise, nonenyl succinic anhydride (NSA) and dimethylaminoethanol (DMAE) are more fluid than their counterparts DDSA and DMP- 30 commonly used in earlier formulations. This work utilizes novel epoxy and anhydride combinations in order to produce embedding media with desirable flow rate and viscosity parameters that, in turn, would allow the medium to optimally infiltrate tissues. Specifically, embeding media based on EmBed 812 or LX 112 with NSA (in place of DDSA) and DMAE (replacing DMP-30), with NMA remaining constant, are formulated and offered as alternatives for routine biological work.Individual epoxy resins (Table I) or complete embedding media (Tables II-III) were tested for flow rate and viscosity. The novel media were further examined for their ability to infilftrate tissues, polymerize, sectioning and staining character, as well as strength and stability to the electron beam and column vacuum. For physical comparisons, a volume (9 ml) of either resin or media was aspirated into a capillary viscocimeter oriented vertically. The material was then allowed to flow out freely under the influence of gravity and the flow time necessary for the volume to exit was recored (Col B,C; Tables). In addition, the volume flow rate (ml flowing/second; Col D, Tables) was measured. Viscosity (n) could then be determined by using the Hagen-Poiseville relation for laminar flow, n = c.p/Q, where c = a geometric constant from an instrument calibration with water, p = mass density, and Q = volume flow rate. Mass weight and density of the materials were determined as well (Col F,G; Tables). Infiltration schedules utilized were short (1/2 hr 1:1, 3 hrs full resin), intermediate (1/2 hr 1:1, 6 hrs full resin) , or long (1/2 hr 1:1, 6 hrs full resin) in total time. Polymerization schedules ranging from 15 hrs (overnight) through 24, 36, or 48 hrs were tested. Sections demonstrating gold interference colors were collected on unsupported 200- 300 mesh grids and stained sequentially with uranyl acetate and lead citrate.

SCIENTIFIC AND ENGINEERING PRINCIPLES OF EFFICIENT FUEL USE AND ENVIRONMENTALLY FRIENDLY GAS COMBUSTION IN STOVE PLATES. PART 1. MODERN STATE-OF-THE-ART AND DIRECTIONS FOR IMPROVEMENT THE GAS BURNING IN DOMESTIC GAS COOKERS

2017 ◽  
pp. 3-18 ◽  
Author(s):  
B.S. Soroka ◽  
V.V. Horupa
Keyword(s):  
Natural Gas ◽  
Flow Rate ◽  
Gas Flow ◽  
Renewable Energy Sources ◽  
Combustion Process ◽  
Orifice Diameter ◽  
Firing Process ◽  
Gas Flow Rate ◽  
Gas Combustion ◽  
Gas Stoves

Natural gas NG consumption in industry and energy of Ukraine, in recent years falls down as a result of the crisis in the country’s economy, to a certain extent due to the introduction of renewable energy sources along with alternative technologies, while in the utility sector the consumption of fuel gas flow rate enhancing because of an increase the number of consumers. The natural gas is mostly using by domestic purpose for heating of premises and for cooking. These items of the gas utilization in Ukraine are already exceeding the NG consumption in industry. Cooking is proceeding directly in the living quarters, those usually do not meet the requirements of the Ukrainian norms DBN for the ventilation procedures. NG use in household gas stoves is of great importance from the standpoint of controlling the emissions of harmful components of combustion products along with maintenance the satisfactory energy efficiency characteristics of NG using. The main environment pollutants when burning the natural gas in gas stoves are including the nitrogen oxides NOx (to a greater extent — highly toxic NO2 component), carbon oxide CO, formaldehyde CH2O as well as hydrocarbons (unburned UHC and polyaromatic PAH). An overview of environmental documents to control CO and NOx emissions in comparison with the proper norms by USA, EU, Russian Federation, Australia and China, has been completed. The modern designs of the burners for gas stoves are considered along with defining the main characteristics: heat power, the natural gas flow rate, diameter of gas orifice, diameter and spacing the firing openings and other parameters. The modern physical and chemical principles of gas combustion by means of atmospheric ejection burners of gas cookers have been analyzed from the standpoints of combustion process stabilization and of ensuring the stability of flares. Among the factors of the firing process destabilization within the framework of analysis above mentioned, the following forms of unstable combustion/flame unstabilities have been considered: flashback, blow out or flame lifting, and the appearance of flame yellow tips. Bibl. 37, Fig. 11, Tab. 7.

Phase changes in the lining of reactors used for carbon black production

Refractories ◽  
1965 ◽  
Vol 6 (9-10) ◽  
pp. 452-457 ◽  
Author(s):  
Z. D. Zhukova ◽  
N. V. Pitak ◽  
V. G. �ntin
Keyword(s):  
Carbon Black ◽  
Phase Changes ◽  
Carbon Black Production

4643880 Apparatus and process for carbon black production

Carbon ◽  
1988 ◽  
Vol 26 (2) ◽  
pp. II
Author(s):  
William R King ◽  
C Jack Hart
Keyword(s):  
Carbon Black ◽  
Carbon Black Production

Design Analysis of a Micro Gas Turbine Combustion Chamber Burning Natural Gas

2012 ◽  
Author(s):  
André Perpignan V. de Campos ◽  
Fernando L. Sacomano Filho ◽  
Guenther C. Krieger Filho
Keyword(s):  
Experimental Data ◽  
Natural Gas ◽  
Combustion Chamber ◽  
Gas Turbines ◽  
Low Cost ◽  
Mixture Fraction ◽  
Combustion Model ◽  
Inlet Temperature ◽  
Gas Combustion ◽  
Micro Turbine

Gas turbines are reliable energy conversion systems since they are able to operate with variable fuels and independently from seasonal natural changes. Within that reality, micro gas turbines have been increasing the importance of its usage on the onsite generation. Comparatively, less research has been done, leaving more room for improvements in this class of gas turbines. Focusing on the study of a flexible micro turbine set, this work is part of the development of a low cost electric generation micro turbine, which is capable of burning natural gas, LPG and ethanol. It is composed of an originally automotive turbocompressor, a combustion chamber specifically designed for this application, as well as a single stage axial power turbine. The combustion chamber is a reversed flow type and has a swirl stabilized combustor. This paper is dedicated to the diagnosis of the natural gas combustion in this chamber using computational fluid dynamics techniques compared to measured experimental data of temperature inside the combustion chamber. The study emphasizes the near inner wall temperature, turbine inlet temperature and dilution holes effectiveness. The calculation was conducted with the Reynolds Stress turbulence model coupled with the conventional β-PDF equilibrium along with mixture fraction transport combustion model. Thermal radiation was also considered. Reasonable agreement between experimental data and computational simulations was achieved, providing confidence on the phenomena observed on the simulations, which enabled the design improvement suggestions and analysis included in this work.

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