Failure Mechanism of Cementitious Nanocomposites Reinforced by Multi-Walled and Single-Walled Carbon Nanotubes Under Splitting Tensile Test

Author(s):  
Robabeh Jazaei ◽  
Moses Karakouzian ◽  
Brendan O’Toole ◽  
Jaeyun Moon ◽  
Samad Gharehdaghi

Sudden concrete failure is due to inelastic deformations of concrete subjected to tension. However, synthesizing nanomaterials reinforcements has significant impact on cement-based composites failure mechanism. Nanomaterials morphology bridges cement crystals as homogeneous and ductile matrix. In this experiment, cement matrix with water to cement ratio of 0.5 reinforced by 0.2–0.6 wt% of functionalized (COOH group) multi-walled and single-walled carbon nanotubes were used. After sonication of carbon nanotubes in water solution for an hour, the cementitious nanocomposites were casted in cylindrical molds (25 mm diameter and 50 mm height). Failure mechanism of cementitious nanocomposite showed considerable ductility throughout splitting tensile test compared to cement mortar. Additionally, the failure pattern after developing the initial crack provided additional time before ultimate failure occurred in cement-based nanocomposites. The evolution of crack propagation was assessed until ultimate specimen failure during splitting-tensile test on cementitious nanocomposite surface. The deformation of cross section from circle to oval shape augmented tensile strength by 50% in cementitious nanocomposite compared to conventional cement mortar.

2015 ◽  
Vol 29 (09) ◽  
pp. 1550031
Author(s):  
Cai-Ping Cheng ◽  
Hui-Fang Hu ◽  
Zhao-Jin Zhang ◽  
Xiaowei Wang ◽  
Ying Chen ◽  
...  

By applying density functional theory (DFT) combined with nonequilibrium Green's function method, we have investigated the electronic structures and quantum transport properties of (6, 3) spiral chiral single-walled carbon nanotubes (SCSWCNTs) in the presence of carboxyl ( COOH )-containing defect complexes. COOH - B - MV complex defect in (6, 3) single-walled carbon nanotubes (SWCNT) was energetically favorable than COOH - B - SW and COOH - B - Per complexes. Our calculated results proved that the complex partially improved the transport properties of (6, 3) SWCNTs with COOH - B - MV complex, but reduced the efficient transmission channels of (6, 3) SWCNTs with COOH - B - SW and COOH - B - Per complexes. It is anticipated that metallic-like (6, 3) SWCNT with COOH -containing complex defects can exhibit large range variations in transport behaviors, which are strongly dependent on the coupling between COOH group and B - MV complex defect. These tremendous properties suggest potential application of COOH -containing B -doped complexes in CNTs-based nanoelectronic devices.


2013 ◽  
Vol 51 (2) ◽  
pp. 137-144
Author(s):  
Naesung Lee ◽  
Jeung Choon Goak ◽  
Tae Yang Kim ◽  
Jongwan Jung ◽  
Young-Soo Seo ◽  
...  

2012 ◽  
Vol 2 (2) ◽  
pp. 200-209 ◽  
Author(s):  
Jurgen Bachl ◽  
Thimo Huber ◽  
Dennis Kuhbeck ◽  
Eva-Maria Schon ◽  
Gabriele Brunner ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3808 ◽  
Author(s):  
Blazej Podlesny ◽  
Bogumila Kumanek ◽  
Angana Borah ◽  
Ryohei Yamaguchi ◽  
Tomohiro Shiraki ◽  
...  

Single-walled carbon nanotubes (SWCNTs) remain one of the most promising materials of our times. One of the goals is to implement semiconducting and metallic SWCNTs in photonics and microelectronics, respectively. In this work, we demonstrated how such materials could be obtained from the parent material by using the aqueous two-phase extraction method (ATPE) at a large scale. We also developed a dedicated process on how to harvest the SWCNTs from the polymer matrices used to form the biphasic system. The technique is beneficial as it isolates SWCNTs with high purity while simultaneously maintaining their surface intact. To validate the utility of the metallic and semiconducting SWCNTs obtained this way, we transformed them into thin free-standing films and characterized their thermoelectric properties.


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