Dense and Sparse Stress Corrosion Crack Initiation in an X65 Pipeline Steel With Mill Scale

Author(s):  
Shidong Wang ◽  
Lyndon Lamborn ◽  
Karina Chevil ◽  
Erwin Gamboa ◽  
Weixing Chen

Abstract Near-neutral pH stress corrosion cracking (SCC) is a significant threat to the operational safety and reliability of gas and oil pipelines. The SCC cracks are typically formed in colonies with different crack density populations on the external surface of the pipe. The density of SCC cracks affect how pipeline integrity and remaining lifetime are assessed. Although sparse and dense crack colonies are commonly observed on pipelines, it has not been well established how these crack colonies with different crack populations were developed in the field. This research was made in an attempt to replicate near-neutral pH SCC cracks with different crack densities in the laboratory with realistic loading conditions commonly found during field operation. An X65 pipeline steel with different surface preparations was used. The results showed that the dense near-neutral pH SCC cracks were successfully reproduced on the primer-coated samples, whereas sparse cracks were reproduced on the mill-scaled and polished samples. The densely spaced cracks could transform into sparsely spaced cracks when most of the primer layer and mill scale had been removed during the long period of corrosion under cyclic loading and further corrosion occurred thinning the crack density. The results of crack initiation obtained from this investigation have also been found to be quite consistent with crack initiation scenarios found during field operation.

CORROSION ◽  
2004 ◽  
Vol 60 (3) ◽  
pp. 275-283 ◽  
Author(s):  
R. Chu ◽  
W. Chen ◽  
S.-H. Wang ◽  
F. King ◽  
T. R. Jack ◽  
...  

Abstract A study was carried out to understand mechanisms of stress corrosion crack initiation in an X-65 pipeline steel exposed to a near-neutral pH soil environment under a mechanical loading condition typical of a pipeline operating in the field. Microcracks initiated on the polished surface of the X-65 pipeline steel after long-term exposure at open-circuit potential in a near-neutral pH synthetic soil solution. It was found that these microcracks were initiated mostly from pits at metallurgical discontinuities such as grain boundaries, pearlitic colonies, and banded phases in the steel. Strong preferential dissolution was observed along planes of the banded structures in the steel. Selective corrosion at these metallurgical discontinuities is attributed to the anodic nature of those areas relative to the neighboring steel surface. Consistent with previous observations, no increased susceptibility to crack initiation was found at physical discontinuities mechanically introduced into the surface of steel exposed to synthetic soil solution at open-circuit potential.


2015 ◽  
Vol 50 (3) ◽  
pp. 196-202 ◽  
Author(s):  
Z. Shirband ◽  
R. L. Eadie ◽  
W. Chen ◽  
J. L. Luo ◽  
R. Kania ◽  
...  

2012 ◽  
Vol 48 (10) ◽  
pp. 1267 ◽  
Author(s):  
Zhiying WANG ◽  
Jianqiu WANG ◽  
En-hou HAN ◽  
Wei KE ◽  
Maocheng YAN ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (59) ◽  
pp. 36876-36885 ◽  
Author(s):  
Bingying Wang ◽  
Yu Yin ◽  
Zhiwei Gao ◽  
Zhenbo Hou ◽  
Wenchun Jiang

A developed surface enhancement technique, USRP, was applied on X80 pipeline steel and the stress corrosion cracking susceptibility was studied.


Author(s):  
Pellumb Jakupi ◽  
Bill Santos ◽  
Wilfred Binns ◽  
Ivan Barker ◽  
Jenny Been

Newly designed miniature Compact Tension (CT) specimens, designed according to standard ASTM dimension ratios, and machined out of previously in-service X65 pipeline steel were exposed to super-imposed cyclic loading at high mean stresses in NS4 solution to determine the behaviour of X65 steel to ripple loading under near neutral pH conditions. Electron Back-Scatter Diffraction (EBSD) was used to study the microstructural grain geometry to determine if it influences stress-corrosion cracking (SCC) initiation and propagation. Prior to ripple load testing, finely polished X65 surfaces were subjected to EBSD measurements to characterize the microstructure’s geometry; i.e., grain and grain boundary orientations and texture. On the same locations where EBSD maps were recorded, a grid of cross-shaped resist markings — approximately 1–5 μm in size — were deposited every 15 μm across the analyzed surfaces. Following microscopic analyses the specimens were pre-cracked and re-examined to determine whether the crack initiation procedure preconditions the residual strain (quantified by grain misorientations) around an induced crack. Then, ripple load testing at stress levels characterized by load ratios (R) greater than 0.9 was performed, while simultaneously monitoring the open-circuit potential (OCP) at room temperature. The originally characterized surface was again re-examined to determine if the crack tip propagated preferably along a specific crystallographic grain orientation by comparing the shifts in each cross-shaped grid. Results from this investigation will help determine if there is a link between microstructural grain geometries and transgranular stress corrosion cracking.


2005 ◽  
Vol 297-300 ◽  
pp. 939-944 ◽  
Author(s):  
Wu Yang ◽  
Guang Fu Li ◽  
Hao Guo ◽  
Jian Jiang Zhou ◽  
Chun Bo Huang ◽  
...  

Effects of some environmental factors on stress corrosion cracking (SCC) of pipeline steel X-70 both in near-neutral pH environments, including NS4 solution and several solutions containing main types of soil in the eastern part of China, and in high pH solution were studied by means of electrochemical measurement and slow strain rate testing (SSRT). The anodic polarization curves showed different features in near-neutral pH and high pH solutions in terms of active-passive transition behavior. In near-neutral pH solutions, the cracking mode was transgranular with the feature of quasi-cleavage, the susceptibility to SCC increased with decreasing potential, pH and temperature as well as increasing CO2, indicating a dominant mechanism of hydrogen induced cracking (HIC). In high pH solutions, the cracking behavior was similar to that in near-neutral pH solutions when the specimens were polarized at cathodic potentials, but quite different at anodic potentials. A comparison of the electrochemical behavior with the SCC potential region indicated a dominant SCC mechanism associated with anodic dissolution (AD) of X70 in high pH solution at anodic potentials. A preliminary experimental potential (E)-pH-SCC diagram has been established for X70 in near-neutral pH environments.


2011 ◽  
Vol 239-242 ◽  
pp. 2091-2095
Author(s):  
Zhi Ying Wang ◽  
Jian Qiu Wang ◽  
En Hou Han ◽  
Wei Ke

The effect of applied potential on the stress corrosion cracking (SCC) initiation of X-70 pipeline steel in near-neutral pH solution has been investigated by using a slow strain rate testing (SSRT) apparatus and electric potential drop (EPD) method. It was found from the SSRT results that the initiation stress decreased with the decrease in the potential from -790mVSCE to -950mVSCE. But the initiation stress increased when the applied potential was at -1100mVSCE and then decreased at -1200mVSCE. The initiation stress also decreased when the anodic potentials were applied to the samples. SEM observations favored the above SSRT results.


Sign in / Sign up

Export Citation Format

Share Document