Heteroepitaxial growth of C70 films on MoS2(0001) and their characterization by low energy electron diffraction and photoelectron spectroscopy

1995 ◽  
Vol 13 (3) ◽  
pp. 1036-1039 ◽  
Author(s):  
Bo‐ying Han ◽  
K. Hevesi ◽  
Li‐ming Yu ◽  
G. Gensterblum ◽  
J.‐J. Pireaux ◽  
...  
1997 ◽  
Vol 36 (Part 1, No. 5A) ◽  
pp. 2833-2836 ◽  
Author(s):  
Ki-Seok An ◽  
Chan-Cuk Hwang ◽  
Rae-Jun Park ◽  
Ju-Bong Lee ◽  
Jeong-Seon Kim ◽  
...  

The chemisorption of dinitrogen, ammonia and hydrogen on the Fe (111) single crystal surface has been studied by low energy electron diffraction and high - and low - energy photoelectron spectroscopy. The clean surface is shown to be unreconstructed. Dinitrogen is chemisorbed with a low sticking probability of ca . 1 x 10 -7 at 420 K and 2 x 10 -7 at 470 K and an activation energy of ca . 20 kJ mol -1 ; evidence is presented that dinitrogen is completely dissociated at the surface. The ‘nitride’ layer shows no reaction when exposed to hydrogen at pressures of up to 10 -5 torr and temperatures up to 650 K. The chemisorption régime of ammonia is a mixed one: extensive dehydrogenation occurs at low coverage with associative sorption at higher coverage. Studies of the effects of preadsorption of hydrogen on the chemisorption of ammonia are summarized.


Sign in / Sign up

Export Citation Format

Share Document