<p>Physicochemical characteristics of the atmospheric boundary layer over North Plain China during the comprehensive observation experiment from 10 to 21 December 2018 were investigated in this paper. The observation data are obtained from the large tethered balloon, Doppler wind lidar, ground-level instruments. The maximum concentration of PM<sub>2.5</sub> exceeded 200 &#181;g m-3, and the ratio value of PM<sub>2.5</sub>/PM<sub>10</sub> was basically around 0.4 (maximum has reached approximately 0.8) during the whole observation period, indicating that explosive growth of fine ode dominant aerosols during the winter heating season. The peak solar irradiance was slightly larger on the clean day, compared with the value during the pollution process. The correlation coefficient between the concentration of PM<sub>2.5</sub> and CO was highest (0.725) among the gas pollutants, and the relationship between O<sub>3</sub> and PM<sub>2.5</sub> was basically negative correlated, not simple linear relationship. Three distinctly different vertical profile types of the PM<sub>2.5</sub> were categorized according to the vertical changes based on the total 33 vertical profiles obtained by the tethered balloon. Type 1 was mainly observed in the daytime, accounted for nearly 51.5%, the PM<sub>2.5</sub> concentration decreased nearly linearly as a function of height below approximate 600 m; Type 2 shows a sharp decreasing trend from the ground to about 200 m; Type 3 shows multi-layer structure of pollutants, some pollutants suspended aloft in upper air. The vertical profile of PM<sub>2.5</sub> was closely related to the atmospheric vertical structure such as the wind, temperature and turbulent kinetic energy, caused by the diurnal variation of the boundary layer. Small wind layer and the weak turbulence activities contributed to the accumulation of pollutants. Vertical patterns of the concentration of PM<sub>2.5</sub> were also greatly affected by the local ground emission sources and regional transport processes.</p>