Microwave Discharge in Liquid Hydrocarbons: Study of a Liquid Hydrocarbon after Exciting the Discharge

2018 ◽  
Vol 52 (4) ◽  
pp. 324-329 ◽  
Author(s):  
Yu. A. Lebedev ◽  
K. A. Averin ◽  
R. S. Borisov ◽  
A. R. Garifullin ◽  
E. S. Bobkova ◽  
...  
2017 ◽  
Vol 149 ◽  
pp. 02002 ◽  
Author(s):  
Yu.A. Lebedev ◽  
K.A. Averin ◽  
A.V. Tatarinov ◽  
I.L. Epstein

2012 ◽  
Vol 38 (6) ◽  
pp. 503-512 ◽  
Author(s):  
P. V. Kopyl ◽  
O. S. Surkont ◽  
V. M. Shibkov ◽  
L. V. Shibkova

GeoArabia ◽  
2004 ◽  
Vol 9 (4) ◽  
pp. 107-138
Author(s):  
Karl Ramseyer ◽  
Joachim E. Amthor ◽  
Christoph Spötl ◽  
Jos M.J. Terken ◽  
Albert Matter ◽  
...  

ABSTRACT Sandstones of the Early Paleozoic Miqrat Formation and Barik Sandstone Member (Haima Supergroup) are the most prolific gas/condensate containing units in the northern part of the Interior Oman Sedimentary Basin (IOSB). The reservoir-quality of these sandstones, buried to depths exceeding 5 km, is critically related to the depositional environment, burial-related diagenetic reactions, the timing of liquid hydrocarbon charge and the replacement of liquid hydrocarbon by gas/condensate. The depositional environment of the sandstones controls the net-sand distribution which results in poorer reservoir properties northwards parallel to the axis of the Ghaba Salt Basin. The sandy delta deposits of the Barik Sandstone Member have a complex diagenetic history, with early dolomite cementation, followed by compaction, chlorite formation, hydrocarbon charge, quartz and anhydrite precipitation and the formation of pore-filling and pore-lining bitumen. In the Miqrat Formation sandstone, which is comprised of inland sabkha deposits, similar authigenic minerals occur, but with higher abundances of dolomite and anhydrite, and less quartz cement. The deduced pore water evolution from deposition to recent, in both the Miqrat Formation and the Barik Sandstone Member, reflects an early addition of saline continental waters and hydrocarbon-burial related mineral reactions with the likely influx of lower-saline waters during the obduction of the Oman Mountains. Four structural provinces are recognized in the IOSB based on regional differences in the subsidence/uplift history: the Eastern Flank, the Ghaba and Fahud Salt Basins and the Mabrouk-Makarem High. In the Fahud Salt Basin, biodegradation of an early oil charge during Late Paleozoic uplift resulted in reservoir-quality degradation by bitumen clogging of the pore space. On the Eastern Flank and the Mabrouk-Makarem High, however, the early oil bypassed the area. In contrast, post-Carboniferous liquid hydrocarbons were trapped in the Mabrouk-Makarem High, whereas on the Eastern Flank surface water infiltration and loss of hydrocarbons or biodegradation to pore occluding bitumen occurred. In the Ghaba Salt Basin, post-Carboniferous hydrocarbon charge induced a redox reaction to form porosity/permeability preserving chlorite in the reservoirs. The liquid hydrocarbons were replaced since the obduction of the Oman Mountains by gas/condensate which prevented the deep parts (>5,000 m) of the Ghaba Salt Basin from pore occluding pyrobitumen and thus deterioration of the reservoir quality.


2006 ◽  
Vol 6 (2) ◽  
pp. 58 ◽  
Author(s):  
Didi Dwi Anggoro ◽  
Nor Aishah Saidina Amin

The direct conversion of natural gas-in particular, its principal component, methane into useful products has been the subject of intense study over the past decades. However, commercialization of this process is still not viable because its conversion and selectivity potentials remain low. Thus, the search continues to come up with a suitable catalyst that allows methane to be oxidized in a controlled environment to yield a high percentage of higher hydrocarbons. ZSM-5 zeolite has been known to be a suitable catalyst for olefin oligomerization. Previous studies, however, have indicated that ZSM-5 zeolites are not resistant to high temperatures. In this work, ZSM-5 was modified with copper and tungsten to develop a highly active and heat-resistant bifunctional oxidative acid catalyst. The oxidation of methane was performed over W/Cu/HZSM-5 catalyst and the results compared with the catalytic performance of W/ HZSM-5 and HZSM-5 catalysts. The metal oxide on the catalyst surface led to enhanced conversion of Hz and CO to CZ-3 ydrocarbons and, hence, reduced HzO selectivity. Inh the liquid hydrocarbons, Cs+ selectivity increased with increasing amount of surface Bn1Jnstedacid sites. The experimental results indicated higher methane conversion and liquid hydrocarbon selectivity than that of W/3.0Cu/HZSM-5 catalyst.


2014 ◽  
Vol 52 (3) ◽  
pp. 319-327 ◽  
Author(s):  
Yu. A. Lebedev ◽  
I. L. Epstein ◽  
V. A. Shakhatov ◽  
E. V. Yusupova ◽  
V. S. Konstantinov

1975 ◽  
Vol 15 (1) ◽  
pp. 159
Author(s):  
G. N. Keith

Australia's currently known reserves of fossil fuel indicate that we have 250 years supply of black coal at current production rates, 400 years of brown coal, 170 years of natural gas, but only 16 years of crude oil (20 years if natural gas liquids figures are included). While we are presently supplying about 65% of our liquid hydrocarbon requirements, this will drop to about 10% by 1990 unless significant new discoveries are made. While it may be technically possible to replace the petroleum based industrial fuels with either coal or natural gas, there is no currently developed alternative for transport fuels. If Australia wishes to pursue the objective of energy self-sufficiency, then these transport fuels produced from indigenous crude, even with the maximum of secondary processing, will have to be supplemented with synthetic fuels made from coal, natural gas or L.P.G.There is considerable activity world wide in perfecting the technology of coal liquefaction, but it seems certain that the process will be highly capital intensive and there will need to be some guaranteed minimum price for the products to protect the venture from fluctuations in the world price of natural crude oil.Converting LPG to gasoline is technically feasible but whether it is sound from an economic standpoint or whether it is justified when considering conservation of energy is a matter for debate.Natural gas can be converted to gasoline but again with a relatively low efficiency of energy conservation. However, it could be attractive where gas is available far in excess of conventional demands and can be supplied to the process at a reasonable price.


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