Abstract
The increasing population growth, depletion of natural resources, and rising energy demand have sparked enormous research endeavors in electrochemical energy storage and conversion. For example, rechargeable lithium-ion batteries are ubiquitous in everyday life. Mechanics plays a critical role in designing a wide range of energy technologies. The emerging field of electro-chemo-mechanics, the interplay of mechanics and electrochemistry, is crucial for understanding the coupled physiochemical processes. The electrochemical phenomena can govern the mechanical response such as stress generation, deformation, fracture initiation/propagation, elasticity, plasticity, etc. Similarly, mechanical phenomena also influence the electrochemical properties such as device reliability, durability, etc. Therefore, the in-depth mechanical study of electrochemical systems is urgently necessary for fundamental science and technological applications. Over the past few years, there has been significant progress in modeling, theories, and experimental characterizations of mechanical aspects of energy storage and conversion. This timely special issue addressed some recent advances in electro-chemo-mechanics. We have selected eight papers covering a wide range of issues in batteries and fuel cells such as (i) deformation, microstructural changes, creep, overcharge detection and prevention, optimization of structural parameters in batteries, (ii) temperature and load variations, metal-free cathode catalyst in fuel cells. The selected papers cover a gamut of electrochemical-mechanics centric research in energy storage and conversion.
Ionic Liquid Electrolytes for Electrochemical Energy Storage Devices