The Influence of Ion Irradiation on the Morphology and Elemental and Chemical Composition of Surface Layers of Tungsten-Free Hard Alloys

Author(s):  
A. M. Badamshin ◽  
S. N. Nesov ◽  
V. S. Kovivchak ◽  
S. N. Povoroznyuk ◽  
V. V. Akimov
Author(s):  
William J. Baxter

In this form of electron microscopy, photoelectrons emitted from a metal by ultraviolet radiation are accelerated and imaged onto a fluorescent screen by conventional electron optics. image contrast is determined by spatial variations in the intensity of the photoemission. The dominant source of contrast is due to changes in the photoelectric work function, between surfaces of different crystalline orientation, or different chemical composition. Topographical variations produce a relatively weak contrast due to shadowing and edge effects.Since the photoelectrons originate from the surface layers (e.g. ∼5-10 nm for metals), photoelectron microscopy is surface sensitive. Thus to see the microstructure of a metal the thin layer (∼3 nm) of surface oxide must be removed, either by ion bombardment or by thermal decomposition in the vacuum of the microscope.


2003 ◽  
Vol 35 (1) ◽  
pp. 13-22
Author(s):  
V.Yu. Dorofeyev ◽  
YU.G. Dorofeyev

In the present paper the problems, connected with the formation of a powder material and its surface layers in conditions of chemical thermal treatment and impregnation with melt, combined with the use of mechanical loads at different process stages are examined. The new results of liquid phase influence on compaction of powder preforms, subjected to impregnation, are obtained. The presence of a liquid phase in preform surface layers can also be connected with the change of the materials chemical composition as the result of boronizing, siliconizing or other kinds of chemical thermal treatment.


2021 ◽  
pp. 5-9
Author(s):  
V. V. Akimov ◽  
◽  
A. M. Badamshin ◽  
S. N. Nesov ◽  
S. N. Povoroznyuk ◽  
...  

Using experimental methods of analysis, the morphology, elemental composition and chemical state of hard alloys of the «TiC-TiNi» system in the initial state and after various types of ion-beam treatment have been investigated. It is found that the effect of a continuous ion beam leads to an increase in the microhardness of the investigated alloys by 10–12 %. When samples are irradiated with a pulsed ion beam, as a result of destruction of surface layers, the microhardness value decreases by 20 %, as a result of which this type of modification is not preferable for alloys of the TiC-TiNi system


1994 ◽  
Vol 339 ◽  
Author(s):  
V. Heera ◽  
R. Kögler ◽  
W. Skorupa ◽  
J. Stoemenos

ABSTRACTThe evolution of the damage in the near surface region of single crystalline 6H-SiC generated by 200 keV Ge+ ion implantation at room temperature (RT) was investigated by Rutherford backscattering spectroscopy/chanelling (RBS/C). The threshold dose for amorphization was found to be about 3 · 1014 cm-2, Amorphous surface layers produced with Ge+ ion doses above the threshold were partly annealed by 300 keV Si+ ion beam induced epitaxial crystallization (IBIEC) at a relatively low temperature of 480°C For comparison, temperatures of at least 1450°C are necessary to recrystallize amorphous SiC layers without assisting ion irradiation. The structure and quality of both the amorphous and recrystallized layers were characterized by cross-section transmission electron microscopy (XTEM). Density changes of SiC due to amorphization were measured by step height measurements.


2018 ◽  
Vol 781 ◽  
pp. 70-75
Author(s):  
Sergei Ghyngazov ◽  
Valeria Kostenko ◽  
Sergey Shevelev ◽  
Anatoliy I. Kupchishin ◽  
Aleksey Kondratyuk

The effect of ion irradiation on the strength characteristics of magnesium oxide and ceramics based on zirconia is studied. The MgO samples were a single crystal grown in an artificial manner. Samples of zirconium ceramics were prepared by ceramic technology. Irradiation of MgO crystals was carried out by Si+ ions (E = 150 keV), Fe+ (E = 70 keV), C+ (E = 50 keV) at room temperature. The fluence varied within the range (1016–1017) сm–2. The modification of the investigated types of ceramics was carried out by ions Al+ (Е = 60 keV), Ar+ (Е= 60 keV), N+ (E = 50 keV). We used ion beams of microsecond duration and moderate power (the current density in the pulse was 3 10-3 A/cm2). Fluence was 1017 cm-2. The irradiation of the ceramics with an ion beam C+ (E = 50 keV) was also performed with nanosecond duration (τ = 50 ns). It is established that ionic irradiation of magnesium oxide leads to an increase in crack resistance and a critical stress intensity factor. Irradiation of ceramics leads to hardening of its near-surface layers.


2020 ◽  
Vol 299 ◽  
pp. 938-942
Author(s):  
Leonid Moiseevich Gurevich ◽  
Dmitri Pronichev ◽  
Aleksey Serov

The structure and chemical composition of the surface layers of aluminum 6000-series alloys after crystallization and homogenization annealing at 580 °C were investigated. It is shown that the state of the surface significantly depends on the presence of impurities in the coolant of the crystallizer, which deteriorate the continuity of the oxide film, which leads to the formation of light color of individual parts of the ingot surface.


Author(s):  
V E Ovcharenko ◽  
Yu F Ivanov ◽  
K V Ivanov ◽  
A A Mokhovikov ◽  
Yu Baohai ◽  
...  

2004 ◽  
Vol 40 (4) ◽  
pp. 337-344 ◽  
Author(s):  
V. I. Lad'yanov ◽  
M. A. Eremina ◽  
L. I. Zhdanova ◽  
S. F. Lomaeva ◽  
T. G. Krutkina ◽  
...  

1989 ◽  
Vol 157 ◽  
Author(s):  
M.C. Ridgway ◽  
R.G. Elliman ◽  
J.S. Williams

ABSTRACTIon—beam induced epitaxial crystallization (IBIEC) of amorphous N1Si2 and CoSi2 layers is demonstrated. Epitaxial metal suicide layers on (111) Si substrates were implanted with 40 keV Si ions to form amorphous surface layers. IBIEC of amorphous NiSi2 and CoSi2 layers was induced at 13—74°C with 1.5 MeV Ne ion irradiation and proceeded in a layer—by—layer manner from the original amorphous/crystalline interface with activation energies of 0.26 ± 0.07 and 0.21 ± 0.06 eV for N1Si2 and CoSi2, respectively.


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