Effect of Rigidity of a Polymer Matrix on the Photochemical Transformations of Photochromic Compounds

2020 ◽  
Vol 62 (4) ◽  
pp. 350-361
Author(s):  
V. P. Grachev ◽  
A. S. Dzhalmukhanova ◽  
M. L. Bubnova ◽  
S. A. Kurochkin ◽  
S. M. Aldoshin
1985 ◽  
Vol 63 (6) ◽  
pp. 1333-1336 ◽  
Author(s):  
J. E. Guillet ◽  
W. K. MacInnis ◽  
A. E. Redpath

Studies of the photocyclization of α-(o-tolyl)acetophenone dissolved in crosslinked ethylene–vinyl acetate beads show that quantum yields close to unity can be achieved, even in the solid polymer matrix. In preliminary experiments using solar radiation it was demonstrated that the rates of photochemical transformations are close to those calculated from the photon energy distribution of the solar spectrum.


Author(s):  
Ru-Min Wang ◽  
Shui-Rong Zheng ◽  
Ya-Ping Zheng

2020 ◽  
pp. 59-64
Author(s):  
N. I. Kurbanova ◽  
◽  
T. M. Gulieva ◽  
N. Ya. Ischenko ◽  
◽  
...  

The effect of additives of nanofillers (NF) containing nanoparticles (NP) of copper oxide, stabilized by a polymer matrix of maleized polyethylene (MPE), obtained by the mechanochemical method, on the properties of composites based on isotactic polypropylene (PP) and high-pressure polyethylene (PE) was studied by X-ray phase (XRD) and thermogravimetric (TGA) analyzes. The enhancement of strength, deformation, and rheological parameters, as well as the thermo-oxidative stability of the obtained nanocomposites was revealed, which, apparently, is due to the synergistic effect of the interaction of copper-containing nanoparticles with anhydride groups of MPE. It is shown that nanocomposites based on PP/PE/NF can be processed both by pressing and injection molding and extrusion, which expands the scope of its application.


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