The Effect of Zinc Oxide on the Physical and Mechanical Properties of Elastic Polymers

2021 ◽  
Vol 57 (3) ◽  
pp. 507-515
Author(s):  
T. R. Aslamazova ◽  
V. A. Kotenev ◽  
N. Yu. Lomovskaya ◽  
V. A. Lomovskoy ◽  
A. Yu. Tsivadze
CERNE ◽  
2016 ◽  
Vol 22 (4) ◽  
pp. 465-474 ◽  
Author(s):  
Siroos Habibzade ◽  
Hamid R. Taghiyari ◽  
Asghar Omidvar ◽  
Hamid R. Roudi

ABSTRACT Nanoparticles have been vastly applied in wood polymer composites (WPCs) in the recent years to improve some of the drawbacks of solid wood species. In the present study, the effects of ZnO nanoparticles on fire retarding, physical, and mechanical properties of polymerized poplar wood were investigated. Poplar specimens were impregnated with styrene monomer, containing four different contents of nano-zinc oxide (ZnO) (0, 0.5, 1 and 1.5%, based on the dry weight of monomer). Results of the scanning electron microscopy (SEM) showed homogeneous dispersion of ZnO nanoparticles in the WPC matrix. Nano-zinc oxide improved physical properties such as dimensional stability and water absorption. Moreover, mechanical properties increased in comparison to the control specimens. The impregnation process also significantly improved some of the fire-retarding properties, including the ignition time; however, the flammability nature of styrene aggravated some others, such as carbonized area. It was concluded that, although most of the properties were improved, the final application of WPC should be taken in to consideration before making decision on whether or not to impregnate populus wood with styrene.


2013 ◽  
Vol 29 (5) ◽  
pp. 495-505 ◽  
Author(s):  
Sara Tavassoli Hojati ◽  
Homayoon Alaghemand ◽  
Faeze Hamze ◽  
Fateme Ahmadian Babaki ◽  
Ramazan Rajab-Nia ◽  
...  

2020 ◽  
pp. 009524432094775
Author(s):  
Shunyu Yang ◽  
Qiwei Pan ◽  
Zhaohui Chen

Sulfur-vulcanized nature rubber (NR) usually accompanies with reversion, which is of great challenge to the application of the NR products. In this work, zinc glycerolate in combination with zinc laurate was incorporated into sulfur-vulcanized NR, for the purpose of effectively substituting the traditional activator zinc oxide. Curing characteristics, physical and mechanical properties and dynamic viscoelastic behavior of the sulfur-vulcanized NR were investigated. Compared with solo addition of zinc glycerolate, zinc glycerolate/zinc laurate significantly improved the anti-reversion property of the sulfur-vulcanized NR. Incorporation of zinc laurate also enhanced the processing fluidity, filler dispersion, and rolling resistance of the sulfur-vulcanized NR. Moreover, the mole fraction of zinc was reduced by 51% with using zinc glycerolate/zinc laurate, compared with the traditional vulcanizates activated by zinc oxide. Our work provides a green approach to fabricate sulfur-vulcanized NR with outstanding anti-reversion performance.


2016 ◽  
Vol 872 ◽  
pp. 162-167 ◽  
Author(s):  
Yandi Andiyana ◽  
Nugraha Edhi Suyatma ◽  
Suliantari

Zinc oxide nanoparticles (ZnO-NPs) were successfully prepared by hydrothermal method at low temperatures (80°C) for 2 hours using zinc nitrate as starting materials. The average size of hydrothermally synthesized ZnO-NPs were comparable with commercial one as confirmed by Particle Size Analyzer (PSA). The incorporation of hydrothermally synthesized ZnO-NPs (0.5% and 1%, w/w) and glycerol as plasticizer (20%, w/w) into tapioca starch film significantly reduce water absorption capacity and water vapor transmission rate while increasing tensile strength and elongation at break of the composite film. These results suggest that hydrothermally synthesized ZnO-NPs have the potential as nanofiller to improve the physical and mechanical properties of biobased film.


2013 ◽  
Vol 465-466 ◽  
pp. 27-31 ◽  
Author(s):  
Sufiah Mohamad Yahya ◽  
A. Azmi ◽  
Maizlinda Izwana Idris ◽  
Muhamad Zaini Yunos ◽  
Shahruddin Mahzan ◽  
...  

Additional of fillers such as silica (SiO2), alumina (Al2O3), zinc oxide (ZnO), Zirconium carbide ( ZrC) and Zirconia (ZrO2) would affect the properties of the polysiloxane sheet, that can be applied in various applications. Polysiloxane sheet composites are largely use today with various materials as fillers. The fabrication techniques of the polysiloxane composite sheets include micro-moulding, casting moulding and injection moulding. Application of different fabricating process, physical and mechanical properties of polysiloxane sheet composites. Thus, this paper complies various studies with regards to the various properties of polysiloxane sheet composites established by incorporation of different fabrication technique and fillers.


Author(s):  
O. V. Karmanova ◽  
A. Y. Fatneva ◽  
S. G. Tikhomirov ◽  
L. V. Popova

The properties of rubber compounds and vulcanizates made using a compositional curing activator with a low content of zinc oxide were studied in this work. Technological modes of obtaining new curing activator activators in the form of an alloy of zinc oxide with a mixture of fatty acids have been developed. To give a convenient outlet shape, finely dispersed fillers of various types were introduced into the experimental products: silicon dioxide, carbon black, microcellulose, bentonite, shungite. The physicochemical properties of compositional curing activator were studied and it was established that, according to the values of acid and iodine numbers, the experimental products satisfy the regulatory requirements for stearic acid. A comparative analysis of the properties of elastomers of experimental products with widely used as curing activator activators of zinc oxide and stearic acid is carried out. It was found that the use of experimental products improves the processability of the compositions due to their better dispersion in an elastomeric medium. The ratios of the compositional curing activator components are determined, which ensure the optimal complex of vulcanization and physical and mechanical properties of elastomers made on their basis. The effectiveness of the action of composite vulcanization activator in the manufacture of elastomeric products is shown - a reduction in the mixing cycle of experimental compositions by an average of 10% is noted compared to the standard rubber compound. The analysis of the research results confirmed the improvement of technological and vulcanization properties of rubber compounds, resistance to scorching. It is shown that the use of compositional curing activators provides the required level of physical and mechanical properties of rubbers even with a decrease in the content of zinc oxide in the experimental product to 20 wt%, and also improves the dispersion of the components of the rubber compound, having a positive effect on the technological and vulcanization properties of rubber compounds.


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