Physical and mechanical properties of hybrid montmorillonite/zinc oxide reinforced carboxymethyl cellulose nanocomposites

2018 ◽  
Vol 108 ◽  
pp. 863-873 ◽  
Author(s):  
Younes Zahedi ◽  
Bahram Fathi-Achachlouei ◽  
Ali Reza Yousefi
CERNE ◽  
2016 ◽  
Vol 22 (4) ◽  
pp. 465-474 ◽  
Author(s):  
Siroos Habibzade ◽  
Hamid R. Taghiyari ◽  
Asghar Omidvar ◽  
Hamid R. Roudi

ABSTRACT Nanoparticles have been vastly applied in wood polymer composites (WPCs) in the recent years to improve some of the drawbacks of solid wood species. In the present study, the effects of ZnO nanoparticles on fire retarding, physical, and mechanical properties of polymerized poplar wood were investigated. Poplar specimens were impregnated with styrene monomer, containing four different contents of nano-zinc oxide (ZnO) (0, 0.5, 1 and 1.5%, based on the dry weight of monomer). Results of the scanning electron microscopy (SEM) showed homogeneous dispersion of ZnO nanoparticles in the WPC matrix. Nano-zinc oxide improved physical properties such as dimensional stability and water absorption. Moreover, mechanical properties increased in comparison to the control specimens. The impregnation process also significantly improved some of the fire-retarding properties, including the ignition time; however, the flammability nature of styrene aggravated some others, such as carbonized area. It was concluded that, although most of the properties were improved, the final application of WPC should be taken in to consideration before making decision on whether or not to impregnate populus wood with styrene.


2006 ◽  
Vol 6 (3) ◽  
pp. 633-639 ◽  
Author(s):  
YongJae Choi ◽  
John Simonsen

Polymer nanocomposites are one of the important application areas for nanotechnology. Naturally derived organic nanophase materials are of special interest in the case of polymer nanocomposites. Carboxymethyl cellulose is a polyelectrolyte derived from natural materials. It has been extensively studied as a hydrogel polymer. Methods to modify the mechanical properties of gels and films made from CMC are of interest in our lab and in the commercial marketplace. The effect of nano-sized fillers on the properties of CMC-based composites is of interest in the development of novel or improved applications for hydrogel polymers in general and CMC in particular. This project investigated cellulose nanocrystals (CNXLs) as a filler in CMC and compared the effects to microcrystalline cellulose (MCC). The composite material was composed of CMC, MCC or CNXL, with glycerin as a plasticizer. CNXL and MCC concentrations ranged from 5% to 30%. Glycerin concentrations were kept constant at 10%. CNXLs improved the strength and stiffness of the resulting composite compared to MCC. In addition, a simple heat treatment was found to render the nanocomposite water resistant.


2013 ◽  
Vol 29 (5) ◽  
pp. 495-505 ◽  
Author(s):  
Sara Tavassoli Hojati ◽  
Homayoon Alaghemand ◽  
Faeze Hamze ◽  
Fateme Ahmadian Babaki ◽  
Ramazan Rajab-Nia ◽  
...  

2020 ◽  
pp. 009524432094775
Author(s):  
Shunyu Yang ◽  
Qiwei Pan ◽  
Zhaohui Chen

Sulfur-vulcanized nature rubber (NR) usually accompanies with reversion, which is of great challenge to the application of the NR products. In this work, zinc glycerolate in combination with zinc laurate was incorporated into sulfur-vulcanized NR, for the purpose of effectively substituting the traditional activator zinc oxide. Curing characteristics, physical and mechanical properties and dynamic viscoelastic behavior of the sulfur-vulcanized NR were investigated. Compared with solo addition of zinc glycerolate, zinc glycerolate/zinc laurate significantly improved the anti-reversion property of the sulfur-vulcanized NR. Incorporation of zinc laurate also enhanced the processing fluidity, filler dispersion, and rolling resistance of the sulfur-vulcanized NR. Moreover, the mole fraction of zinc was reduced by 51% with using zinc glycerolate/zinc laurate, compared with the traditional vulcanizates activated by zinc oxide. Our work provides a green approach to fabricate sulfur-vulcanized NR with outstanding anti-reversion performance.


2017 ◽  
Vol 70 ◽  
pp. 36-45 ◽  
Author(s):  
Nooshin Noshirvani ◽  
Babak Ghanbarzadeh ◽  
Christian Gardrat ◽  
Mokarram Reza Rezaei ◽  
Mahdi Hashemi ◽  
...  

2021 ◽  
Vol 57 (3) ◽  
pp. 507-515
Author(s):  
T. R. Aslamazova ◽  
V. A. Kotenev ◽  
N. Yu. Lomovskaya ◽  
V. A. Lomovskoy ◽  
A. Yu. Tsivadze

2016 ◽  
Vol 872 ◽  
pp. 162-167 ◽  
Author(s):  
Yandi Andiyana ◽  
Nugraha Edhi Suyatma ◽  
Suliantari

Zinc oxide nanoparticles (ZnO-NPs) were successfully prepared by hydrothermal method at low temperatures (80°C) for 2 hours using zinc nitrate as starting materials. The average size of hydrothermally synthesized ZnO-NPs were comparable with commercial one as confirmed by Particle Size Analyzer (PSA). The incorporation of hydrothermally synthesized ZnO-NPs (0.5% and 1%, w/w) and glycerol as plasticizer (20%, w/w) into tapioca starch film significantly reduce water absorption capacity and water vapor transmission rate while increasing tensile strength and elongation at break of the composite film. These results suggest that hydrothermally synthesized ZnO-NPs have the potential as nanofiller to improve the physical and mechanical properties of biobased film.


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