Brachiopod biostratigraphy of the middle Ordovician Cow Head and Table Head groups, western Newfoundland

1987 ◽  
Vol 24 (1) ◽  
pp. 70-95 ◽  
Author(s):  
Reuben J. Ross Jr ◽  
Noel P. James

Brachiopods from shallow-water limestone boulders in beds 12, 13, and 14 of the allochthonous Cow Head Group belong in the earliest Whiterockian Orthidiella Zone. Brachiopods of the autochthonous intertidal to deep-water Table Head Group are equivalent to those of the younger Whiterockian Anomalorthis Zone. The Cow Head is older than the Table Head.Integration of the brachiopod data from western Newfoundland with those from the type Whiterockian in Nevada, combined with the evidence of graptolites from both areas, indicates that the Orthidiella Zone spans the Australian Castlemainian, Yapeenian, and lower Darriwilian Dal zones.


1987 ◽  
Vol 24 (3) ◽  
pp. 456-470 ◽  
Author(s):  
S. Henry Williams ◽  
W. Douglas Boyce ◽  
Noel P. James

Faunal assemblages of the autochthonous, shelf carbonate sequences belonging to the St. George and Table Head groups are dominated by shelly macrofossils and conodonts. Rare, usually monotypic graptolitic horizons enable correlation with the allochthonous Cow Head Group, which was deposited on the middle to lower slope, and the shelly, conodont, and graptolitic zonal schemes elsewhere in North America.The Catoche Formation of the St. George Group is of Ibexian (Canadian) age and yields graptolites indicative of the Tetragraptus approximatus and Tetragraptus akzharensis zones (early Arenig). The basal Aguathuna Formation belongs to the Pendeograptus fruticosus Zone, whereas higher parts span the Ibexian–Whiterock boundary. Graptolites suggest that the Table Head Group entirely postdates the Cow Head Group. This is supported by a Whiterock (early Llanvirn) trilobite, conodont, and brachiopod fauna.



1988 ◽  
Vol 125 (4) ◽  
pp. 381-414 ◽  
Author(s):  
C. R. Barnes

AbstractSections exposing the Cambrian–Ordovician Boundary interval at Broom Point in western Newfoundland have been proposed earlier for a global systemic boundary stratotype. These lie within the Cow Head Group, a late Middle Cambrian to early Middle Ordovician allochthonous unit of limestone, shale, and conglomerate deposited at the toe of the ancient continental slope and on the adjacent continental rise. Several recent studies have further investigated the stratigraphy, sedimentology, and palaeontology of the Cow Head Group and others are under way on magnetostratigraphy and chemostratigraphy. These aspects are reviewed for six key boundary sections representing proximal to distal facies: Cow Head Ledge, Broom Point South, Broom Point North, St Pauls Inlet Quarry, Martin Point, and Green Point. In particular, new data are presented from 260 conodont samples that yielded 15500 conodonts. This intense sampling has allowed the discrimination of minor hiatuses in the proximal to intermediate facies where conglomerates have eroded and cannibalized underlying strata. New conodont data from Broom Point North have lowered the base of the C. lindstromi Zone into unit 74 conglomerates, thereby making this section unsuitable as a boundary stratotype. New collections from Green Point have yielded abundant conodonts and over 9400 conodonts have been recovered from 77 samples.The conodont, graptolite, and trilobite biostratigraphy through the boundary interval is documented allowing accurate correlation between sections and more precisely revealing small hiatuses in the proximal and intermediate facies. The sequence of conodont zones is: Eoconodontus notchpeakensis, Cordylodus proavus, C. caboti, C. intermedius, C. lindstromi and C. angulatus. These can be correlated with trilobite zones established from both in situ and clast faunas from the proximal to intermediate facies and with graptolite assemblages (of Cooper 1979) especially in the intermediate to distal facies. Three new species of Cordylodus are described (C. andresi, C. hastatus and C. tortus) and the full apparatus of Iapetognathus preaengensis is illustrated.The criteria for selecting a global boundary stratotype and point (GSSP) are reviewed in terms of the Cow Head sections. The Green Point section is shown to meet, and largely surpass, the prerequisites required of a stratotype. The Green Point section is proposed to be the global boundary stratotype with the base of the Ordovician System defined at the base of unit 23, which is the base of the Broom Point Member, Green Point Formation, at a level coincident with the base of the Cordylodus lindstromi Zone. In addition to an abundant and superbly preserved conodont fauna, this section preserves the best sequence of earliest planktic graptolites through a 40 m interval; the first nematophorous graptolites (of Assemblage 1) occur in unit 25, 6.9 m above the base of the C. lindstromi Zone. This level can be readily correlated into the proximal facies where both deep and shallow water trilobites (in situ and in clasts, respectively) show the base of the C. lindstromi Zone to lie within the Symphysurina brevispicata trilobite Subzone.



2001 ◽  
Vol 38 (3) ◽  
pp. 387-409 ◽  
Author(s):  
Roberto Albani ◽  
Gabriella Bagnoli ◽  
Jörg Maletz ◽  
Svend Stouge

The Cape Cormorant Formation of the Table Head Group exposed on the Port au Port Peninsula, western Newfoundland, is composed of dark-brown to black shales with interbeds of thin calcareous silty and sandy distal turbidites. Distinctive carbonate conglomerates and breccias derived from the foundering shelf are occasionally found in the formation. The sediments accumulated in the foreland basin formed during the early stage of the Taconic orogeny. The faunas from the upper part of the Cape Cormorant Formation include graptolites, conodonts, and chitinozoans. The graptolites are well preserved, but are of low diversity and are referred to the Darriwil Pterograptus elegans Zone. Conodonts recorded from the distal turbidites are rare and fragmented. The faunas include taxa that are known from the St. George and Table Head groups. The conodont fauna is tentatively assigned to the Histiodella kristinae Phylozone and to the younger, unzoned interval. The chitinozoans are well preserved and the yield is high. The fauna is assigned to the Cyathochitina jenkinsi Zone and to an undefined interval. The abundance and diversity of the chitinozoan assemblages display a cyclic pattern, which is related to changes of the oceanic watermass in the foreland basin. The new chitinozoan species Belonechitina nevillensis n. sp., Belonechitina uniformipunctata n. sp., and Cyathochitina cormorani n. sp. are described.



1987 ◽  
Vol 24 (6) ◽  
pp. 1199-1211 ◽  
Author(s):  
Noel P. James ◽  
Jack W. Botsford ◽  
S. Henry Williams

The upper part of an intact sequence of Lower to Middle Ordovician deep-water sediments, which now form a large, disrupted raft within the Rocky Harbour Mélange at Lobster Cove Head, is interpreted as having been deposited downslope from a drowned carbonate platform margin. The entire 50 m thick section is Arenig (late Canadian or Ibexian to early Whiterock) in age; graptolite biostratigraphy demonstrates a correlation with upper parts of the Cow Head Group to the north. The basal part of the section is a proximal facies of the Cow Head Group (Shallow Bay Formation, Factory Cove Member, Beds 9, 10, and part of Bed 11). The upper part of the section consists of interbedded dolostone and shale and is unlike any other sequence in the Cow Head Group. This upper sedimentary sequence is defined as the Lobster Cove Head Member of the Shallow Bay Formation, Cow Head Group. Contact between the two sedimentary packages is also marked by a faunal break and coincides with emplacement of megaconglomerate Bed 12 at Cow Head.This break marks the change from a uniform to complex carbonate platform margin configuration and is here interpreted as the result of synsedimentary faulting. The margin upslope from Cow Head remained in shallow water during the final stages of Cow Head Group deposition, whereas that upslope from Lobster Cove Head was drowned and shed little sediment into deep water. The synsedimentary faulting, which led to rapid subsidence and platform-margin drowning upslope from Lobster Cove Head and possibly the deposition of megaconglomerate Bed 12 at Cow Head, coincides with the onset of the Taconic Orogeny in western Newfoundland.



1984 ◽  
Vol 21 (2) ◽  
pp. 194-199 ◽  
Author(s):  
R. K. Pickerill ◽  
T. L. Harland ◽  
D. Fillion

Specimens of in situ lingulids have been discovered in carbonates of the Middle Ordovician Table Head Group of northwestern Newfoundland and Trenton Group of the St. Lawrence Lowland of Quebec. The discoveries have two important implications regarding Palaeozoic lingulid ecology. First, they represent one of the few recordings of in situ lingulids in carbonate substrates of Palaeozoic age and, second, they occur mainly in outer shelf and upper slope sediments (Grondines Member of Neuville Formation, Trenton Group, and Table Cove Formation, Table Head Group), deposited in presumed considerable water depths. Caution must be observed with the use in the fossil record of lingulids as palaeo-environmental indicators.



Author(s):  
Jon R. Ineson ◽  
John S. Peel

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Ineson, J. R., & Peel, J. S. (1997). Cambrian shelf stratigraphy of North Greenland. Geology of Greenland Survey Bulletin, 173, 1-120. https://doi.org/10.34194/ggub.v173.5024 _______________ The Lower Palaeozoic Franklinian Basin is extensively exposed in northern Greenland and the Canadian Arctic Islands. For much of the early Palaeozoic, the basin consisted of a southern shelf, bordering the craton, and a northern deep-water trough; the boundary between the shelf and the trough shifted southwards with time. In North Greenland, the evolution of the shelf during the Cambrian is recorded by the Skagen Group, the Portfjeld and Buen Formations and the Brønlund Fjord, Tavsens Iskappe and Ryder Gletscher Groups; the lithostratigraphy of these last three groups forms the main focus of this paper. The Skagen Group, a mixed carbonate-siliciclastic shelf succession of earliest Cambrian age was deposited prior to the development of a deep-water trough. The succeeding Portfjeld Formation represents an extensive shallow-water carbonate platform that covered much of the shelf; marked differentiation of the shelf and trough occurred at this time. Following exposure and karstification of this platform, the shelf was progressively transgressed and the siliciclastics of the Buen Formation were deposited. From the late Early Cambrian to the Early Ordovician, the shelf showed a terraced profile, with a flat-topped shallow-water carbonate platform in the south passing northwards via a carbonate slope apron into a deeper-water outer shelf region. The evolution of this platform and outer shelf system is recorded by the Brønlund Fjord, Tavsens Iskappe and Ryder Gletscher Groups. The dolomites, limestones and subordinate siliciclastics of the Brønlund Fjord and Tavsens Iskappe Groups represent platform margin to deep outer shelf environments. These groups are recognised in three discrete outcrop belts - the southern, northern and eastern outcrop belts. In the southern outcrop belt, from Warming Land to south-east Peary Land, the Brønlund Fjord Group (Lower-Middle Cambrian) is subdivided into eight formations while the Tavsens Iskappe Group (Middle Cambrian - lowermost Ordovician) comprises six formations. In the northern outcrop belt, from northern Nyeboe Land to north-west Peary Land, the Brønlund Fjord Group consists of two formations both defined in the southern outcrop belt, whereas a single formation makes up the Tavsens Iskappe Group. In the eastern outcrop area, a highly faulted terrane in north-east Peary Land, a dolomite-sandstone succession is referred to two formations of the Brønlund Fjord Group. The Ryder Gletscher Group is a thick succession of shallow-water, platform interior carbonates and siliciclastics that extends throughout North Greenland and ranges in age from latest Early Cambrian to Middle Ordovician. The Cambrian portion of this group between Warming Land and south-west Peary Land is formally subdivided into four formations.The Lower Palaeozoic Franklinian Basin is extensively exposed in northern Greenland and the Canadian Arctic Islands. For much of the early Palaeozoic, the basin consisted of a southern shelf, bordering the craton, and a northern deep-water trough; the boundary between the shelf and the trough shifted southwards with time. In North Greenland, the evolution of the shelf during the Cambrian is recorded by the Skagen Group, the Portfjeld and Buen Formations and the Brønlund Fjord, Tavsens Iskappe and Ryder Gletscher Groups; the lithostratigraphy of these last three groups forms the main focus of this paper. The Skagen Group, a mixed carbonate-siliciclastic shelf succession of earliest Cambrian age was deposited prior to the development of a deep-water trough. The succeeding Portfjeld Formation represents an extensive shallow-water carbonate platform that covered much of the shelf; marked differentiation of the shelf and trough occurred at this time. Following exposure and karstification of this platform, the shelf was progressively transgressed and the siliciclastics of the Buen Formation were deposited. From the late Early Cambrian to the Early Ordovician, the shelf showed a terraced profile, with a flat-topped shallow-water carbonate platform in the south passing northwards via a carbonate slope apron into a deeper-water outer shelf region. The evolution of this platform and outer shelf system is recorded by the Brønlund Fjord, Tavsens Iskappe and Ryder Gletscher Groups. The dolomites, limestones and subordinate siliciclastics of the Brønlund Fjord and Tavsens Iskappe Groups represent platform margin to deep outer shelf environments. These groups are recognised in three discrete outcrop belts - the southern, northern and eastern outcrop belts. In the southern outcrop belt, from Warming Land to south-east Peary Land, the Brønlund Fjord Group (Lower-Middle Cambrian) is subdivided into eight formations while the Tavsens Iskappe Group (Middle Cambrian - lowermost Ordovician) comprises six formations. In the northern outcrop belt, from northern Nyeboe Land to north-west Peary Land, the Brønlund Fjord Group consists of two formations both defined in the southern outcrop belt, whereas a single formation makes up the Tavsens Iskappe Group. In the eastern outcrop area, a highly faulted terrane in north-east Peary Land, a dolomite-sandstone succession is referred to two formations of the Brønlund Fjord Group. The Ryder Gletscher Group is a thick succession of shallow-water, platform interior carbonates and siliciclastics that extends throughout North Greenland and ranges in age from latest Early Cambrian to Middle Ordovician. The Cambrian portion of this group between Warming Land and south-west Peary Land is formally subdivided into four formations.



Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 116-125
Author(s):  
Yi-Fan Li ◽  
Amit Ghosh ◽  
Pronay Kumar Biswas ◽  
Suchismita Saha ◽  
Michael Schmittel

Three distinct four-component supramolecular nanorotors were prepared, using, for the first time, bipyridine instead of phenanthroline stations in the stator. Following our established self-sorting protocol to multicomponent nanodevices, the nanorotors were self-assembled by mixing the stator, rotators with various pyridine head groups, copper(I) ions and 1,4-diazabicyclo[2.2.2]octane (DABCO). Whereas the exchange of a phenanthroline vs. a bipyridine station did not entail significant changes in the rotational exchange frequency, the para-substituents at the pyridine head group of the rotator had drastic consequences on the speed: 4-OMe (k298 = 35 kHz), 4-H (k298 = 77 kHz) and 4-NO2 (k298 = 843 kHz). The exchange frequency (log k) showed an excellent linear correlation with both the Hammett substituent constants and log K of the copper(I)–ligand interaction, proving that rotator–copper(I) bond cleavage is the key determining factor in the rate-determining step.



Author(s):  
Elton J. B. Ribeiro ◽  
Zhimin Tan ◽  
Yucheng Hou ◽  
Yanqiu Zhang ◽  
Andre Iwane

Currently the oil and gas industry is focusing on challenging deep water projects, particularly in Campos Basin located coast off Brazil. However, there are a lot of prolific reservoirs located in shallow water, which need to be developed and they are located in area very far from the coast, where there aren’t pipelines facilities to export oil production, in this case is necessary to use a floating production unit able to storage produced oil, such as a FPSO. So, the riser system configuration should be able to absorb FPSO’s dynamic response due to wave load and avoid damage at touch down zone, in this case is recommended to use compliant riser configuration, such as Lazy Wave, Tethered Wave or Lazy S. In addition to, the proposed FPSO for Tubarão Martelo development is a type VLCC (Very Large Crude Carrier) using external turret moored system, which cause large vertical motion at riser connection and it presents large static offset. Also are expected to install 26 risers and umbilicals hanging off on the turret, this large number of risers and umbilicals has driven the main concerns to clashing and clearance requirement since Lazy-S configuration was adopted. In this paper, some numerical model details and recommendations will be presented, which became a feasible challenging risers system in shallow water. For instance, to solve clashing problem it is strictly recommended for modeling MWA (Mid Water Arch) gutter and bend stiffener at top I-tube interface, this recommendation doesn’t matter in deep water, but for shallow water problem is very important. Also is important to use ballast modules in order to solve clashing problems.



Ground Water ◽  
2003 ◽  
Vol 41 (7) ◽  
pp. 964-972 ◽  
Author(s):  
James B. Shanley ◽  
K. Niclas Hjerdt ◽  
Jeffrey J. McDonnell ◽  
Carol Kendall


1980 ◽  
Vol 17 (8) ◽  
pp. 1007-1019 ◽  
Author(s):  
Colin F. Klappa ◽  
Paul R. Opalinski ◽  
Noel P. James

Lithostratigraphic nomenclature of early Middle Ordovician strata from western Newfound land is formally revised. The present Table Head Formation is raised to group status and extended to include overlying interbedded terrigenoclastic-rich calcarenites and shales with lime megabreccias. Four new formation names are proposed: Table Point Formation (previously lower Table Head); Table Cove Formation (previously middle Table Head); Black Cove Formation (previously upper Table Head); and Cape Cormorant Formation (previously Caribou Brook formation). The Table Point Formation comprises bioturbated, fossiliferous grey, hackly limestones and minor dolostones; the Table Cove Formation comprises interbedded lime mudstones and grey–black calcareous shales; the Black Cove Formation comprises black graptolitic shales; and the Cape Cormorant Formation comprises interbedded terrigenoclastic and calcareous sandstones, siltstones, and shales, punctuated by massive or thick-bedded lime megabreccias. The newly defined Table Head Group rests conformably or disconformably on dolostones of the Lower Ordovician St. George Group (an upward-migrating diagenetic dolomitization front commonly obscures the contact) and is overlain concordantly by easterly-derived flysch deposits. Upward-varying lithologic characteristics within the Table Head Group result from fragmentation and subsidence of the Cambro-Ordovician carbonate platform and margin during closure of a proto-Atlantic (Iapetus) Ocean.



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