THE SEPARATION OF SMALL AMOUNTS OF THE PLATINUM METALS: 1. THE COLORIMETRIC DETERMINATION OF RHODIUM AND ITS SEPARATION FROM IRIDIUM
Keyword(s):
A method for separating small amounts of rhodium from iridium is described. In 3 to 9 M hydrochloric acid solutions, the amber-to-red complex of bivalent rhodium with 4,5-dimethyl-2-mercaptothiazole is formed after reduction of tervalent rhodium with chromous or stannous chloride. Rhodium is quantitatively separated from iridium by chloroform extraction of this product; separation can be made in solutions that have been fumed with sulphuric acid if chromous chloride is used for the prior reduction of the rhodium. The complex, after removal of the chloroform, is dissolved in dilute hydrochloric acid, and the optical density of the resulting colored solution is measured.
1960 ◽
Vol 38
(12)
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pp. 2488-2492
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Determination of the Distribution of Cupric Chloro-Complexes in Hydrochloric Acid Solutions at 298 K
2017 ◽
Vol 46
(3)
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pp. 704-719
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Keyword(s):
1976 ◽
Vol 82
(1)
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pp. 217-221
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1960 ◽
Vol 64
(9)
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pp. 1277-1279
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Keyword(s):
1987 ◽
Vol 119
(2)
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pp. 143-147