Hydration of Some Acids in Sulfolane

1975 ◽  
Vol 53 (18) ◽  
pp. 2683-2688 ◽  
Author(s):  
R. L. Benoit ◽  
S. Y. Lam
Keyword(s):  
Acetic Acid ◽  
Sulfonic Acid ◽  
Picric Acid ◽  
Methanesulfonic Acid ◽  
Pressure Measurements ◽  
Methane Sulfonic Acid ◽  
Enthalpy Changes ◽  
Low Concentrations ◽  
Vapor Pressure Measurements ◽  
And Calorimetry

Interaction between water at low concentrations and some carboxylic acids, methane-sulfonic acid and picric acid, HA, have been studied in Sulfolane at 30 °C. Vapor pressure measurements and calorimetry were used. Results are interpreted in terms of hydration constants K1 and enthalpy changes ΔH1, for the 1:1 complexes [Formula: see text] The values of K1 are low and generally increase slightly with the strength of the acid HA from ∼0.4 for acetic acid to 5.7 for methanesulfonic acid.

THE REACTION OF METHANESULFONIC ACID WITH SULFUR TRIOXIDE

1966 ◽  
Vol 44 (12) ◽  
pp. 1437-1444 ◽  
Author(s):  
E. A. Robinson ◽  
V. Silberberg
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Raman Spectra ◽  
Sulfonic Acid ◽  
Sulfur Trioxide ◽  
Methanesulfonic Acid ◽  
Resonance Peak ◽  
Methane Sulfonic Acid ◽  
Low Concentrations ◽  
Rapid Equilibrium

The reaction of sulfur trioxide with methanesulfonic acid has been studied by examination of the nuclear magnetic resonance (n.m.r.) and Raman spectra of solutions containing up to 0.8 stoichiometric mole fraction of SO3.At relatively low SO3 concentrations the polysulfonic acid CH3S2O6H is formed initially and reacts with excess methane sulfonic acid to give methanesulfonic anhydride.[Formula: see text]CH3S2O6H and CH3SO3H exchange protons and SO3 rapidly and a single methyl resonance peak only is observed for these species in the n.m.r. spectrum. A separate methyl resonance is observed for (CH3)2S2O5 at relatively low concentrations of SO3, but at higher concentrations the peak merges with that due to CH3SO3H and CH3S2O6H because of the rapid equilibration of (CH3)2S2O5 with H2S2O7.[Formula: see text]At higher concentrations of SO3 it is likely that the system contains polymers of the three series CH3Sn+1O3n+3H, (CH3)2Sn+2O3n+5, and H2Sn+1O3n+4 in rapid equilibrium. Free SO3 is not found in the system at concentrations less than 60 mole %.

scholarly journals Effects of the degradation of methane sulfonic acid electrolyte on the collapse failure of Sn–Ag alloy solders for flip-chip interconnections

RSC Advances ◽  
2017 ◽  
Vol 7 (37) ◽  
pp. 23136-23142 ◽  
Author(s):  
Mi-Seok Park ◽  
Do-Hwan Nam ◽  
Ki-Min Jung ◽  
Kyung-Sik Hong ◽  
Hyuk-Sang Kwon
Keyword(s):  
Sulfonic Acid ◽  
Flip Chip ◽  
Degradation Mechanism ◽  
Methanesulfonic Acid ◽  
Acid Electrolyte ◽  
Methane Sulfonic Acid ◽  
Solder Bumps ◽  
Alloy Solder ◽  
Collapse Failure

The degradation mechanism of the methanesulfonic acid based electroplating bath used for the electrodeposition of Sn–Ag alloy solder bumps and its effects on the collapse failure of flip-chip solder bumps.

scholarly journals Pretreatment of Switchgrass for Production of Glucose via Sulfonic Acid-Impregnated Activated Carbon

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 504
Author(s):  
Yane Ansanay ◽  
Praveen Kolar ◽  
Ratna Sharma-Shivappa ◽  
Jay Cheng ◽  
Consuelo Arellano
Keyword(s):  
Activated Carbon ◽  
Sulfonic Acid ◽  
Solid Acid ◽  
Methanesulfonic Acid ◽  
Biofuel Production ◽  
Acid Catalysts ◽  
Effects Of Temperature ◽  
Carbon Catalysts ◽  
Hydrolysis Of

In the present research, activated carbon-supported sulfonic acid catalysts were synthesized and tested as pretreatment agents for the conversion of switchgrass into glucose. The catalysts were synthesized by reacting sulfuric acid, methanesulfonic acid, and p-toluenesulfonic acid with activated carbon. The characterization of catalysts suggested an increase in surface acidities, while surface area and pore volumes decreased because of sulfonation. Batch experiments were performed in 125 mL serum bottles to investigate the effects of temperature (30, 60, and 90 °C), reaction time (90 and 120 min) on the yields of glucose. Enzymatic hydrolysis of pretreated switchgrass using Ctec2 yielded up to 57.13% glucose. Durability tests indicated that sulfonic solid-impregnated carbon catalysts were able to maintain activity even after three cycles. From the results obtained, the solid acid catalysts appear to serve as effective pretreatment agents and can potentially reduce the use of conventional liquid acids and bases in biomass-into-biofuel production.

Rapid Vapor-Collection Method for Vapor Pressure Measurements of Low-Volatility Compounds

2020 ◽  
Vol 92 (24) ◽  
pp. 16253-16259
Author(s):  
Megan E. Harries ◽  
Cheryle N. Beuning ◽  
Bridger L. Johnston ◽  
Tara M. Lovestead ◽  
Jason A. Widegren
Keyword(s):  
Vapor Pressure ◽  
Pressure Measurements ◽  
Collection Method ◽  
Vapor Collection ◽  
Vapor Pressure Measurements

Zur Thermodynamik der hydrophoben Wechselwirkung; die Systeme Wasser + Glycin+ Harnstoff und Wasser + Alanin+ Harnstoff bei 25 °C / Thermodynamics of Hydrophobie Interaction in the Systems Water + Glycin + Urea and Water + Alanin + Urea at 25 °C

1973 ◽  
Vol 28 (9-10) ◽  
pp. 533-554 ◽  
Author(s):  
Lothar Rafflenbeul ◽  
Wa-Ming Pang ◽  
Hansjürgen Schönert ◽  
Klaus Haberle
Keyword(s):  
Amino Acid ◽  
Magnetic Resonance ◽  
Proton Magnetic Resonance ◽  
Pressure Measurements ◽  
Free Enthalpy ◽  
Heat Of Dilution ◽  
Ternary Solutions ◽  
Vapor Pressure Measurements ◽  
Calorimetric Determination

Abstract Isopiestic vapor pressure measurements and calorimetric determination of the heat of dilution have been performed and evaluated with respect to enthalpy, entropy and free enthalpy in the ternary solutions water+ glycin+ urea and water+ alanin + urea. The free enthalpy of transfer for the process: Amino acid from water to water+ urea, which can be derived from these measurements, does not agree with the value calculated from solubility measurements. The reason for this discrepancy and the values of entropy and enthalpy in terms of hydrophobic interaction are discussed. Supplementary measurements of the proton magnetic resonance in these solutions are included.

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