Polyol–Water interactions. Apparent molal heat capacities and volumes of aqueous polyol solutions
1977 ◽
Vol 55
(22)
◽
pp. 3825-3830
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Keyword(s):
Volumetric specific heats (25 °C) and densities (24 °C) were measured with a flow microcalorimeter and flow densimeter for 12 polyols in water (0.05 to 2 m), and for NaCl and n-Bu4NBr in 1 m aqueous alditol solutions. The infinite dilution properties [Formula: see text] of the polyols show specificities in polyol−water interactions which are discussed in terms of the compatibility of the polyol stereochemistry and the existing water environment. The derived heat; capacities and volumes of transfer of hydrophobic and hydrophilic probes to aqueous solutions of homologous polyols suggest that structural interactions are reduced in these systems as compared to pure water.
1978 ◽
Vol 56
(13)
◽
pp. 1827-1831
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1976 ◽
Vol 54
(21)
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pp. 3315-3318
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1973 ◽
Vol 69
(0)
◽
pp. 2112
◽