Reduction of conjugate double bonds with trichlorosilane
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A variety of α,β-unsaturated esters and cyclic ketones underwent smooth reduction of the carboncarbon double bond with a combination of inexpensive and readily available trichlorosilane and CoCl2. The reactions are performed under very mild conditions and products are obtained in high yields.Key words: reduction, carbonyl compounds, trichlorosilane, ketones, chemoselectivity.
1978 ◽
Vol 152
(3)
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pp. 359-365
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1995 ◽
pp. 2969-2988
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2002 ◽
Vol 67
(2)
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pp. 235-244
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1991 ◽
Vol 56
(23)
◽
pp. 6720-6722
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