INFRARED EVIDENCE FOR THE COEXISTENCE OF FREE AND BOUND CHARGES IN Nd2-xCexCuO4 AND Bi2Sr2CuO6
Electron-doped Nd 2-x Ce x CuO 4 and hole-doped Bi 2 Sr 2 CuO 6 have been studied in the infrared to discriminate between the existing models of the optical conductivity σ(ω) in metallic cuprates. In Nd 2-x Ce x CuO 4 an absorption peak clearly visible in the insulating phase softens for increasing x and for decreasing temperature, until it reaches the far infrared (FIR peak) at the insulator-to-metal transition. In the superconducting phase it persists beside the free-carrier Drude absorption, as shown by fitting procedures, and disappears only in the overdoped normal metal. Direct evidence for the presence of the FIR peak in a metallic cuprate comes from the reflectivity of a Bi 2 Sr 2 CuO 6 film, measured down to 10 cm -1, where we could resolve the FIR peak from a normal Drude term as narrow as 35 cm -1 at low T. This observation provides direct evidence for the coexistence of free and "bound" charges in a superconducting cuprate.