THE SPIN HAMILTONIAN PARAMETERS CALCULATION OF 14N AND 15N IN NATURAL TYPE I DIAMOND

2008 ◽  
Vol 22 (25n26) ◽  
pp. 4740-4748 ◽  
Author(s):  
CHITTRA KEDKAEW ◽  
PICHET LIMSUWAN ◽  
KANPHOT THONGCHAM ◽  
SIWAPORN MEEJOO
Keyword(s):  
Natural Diamond ◽  
Microwave Frequency ◽  
Esr Spectra ◽  
Type I ◽  
Spin Hamiltonian ◽  
X Band ◽  
Natural Type ◽  
Hamiltonian Parameters ◽  
Parameters Calculation ◽  
Resonance Magnetic Field

The main purpose of this work is to present the ESR spectra and calculate the spin Hamiltonian parameters of 14 N and 15 N impurities in natural diamond. The ESR spectra of diamond crystal were measured on ESR spectrometer operating at X-band microwave frequency. The results of ESR spectra show that the diamond has a P1 center. This center gives rise to three strong resonance absorption peaks at θ = 90°, φ = 0° due to hyperfine interaction between electron spin and nuclear spin of 14 N . The ESR spectra of 15 N impurity consist of two satellites at the same rotation angle (φ). The effects of isolated substitution nitrogen on carbon atom produced a symmetric distortion from Td to C3V symmetry. According to this symmetry, the resonance magnetic field positions of ESR spectra for the rotation angles of 0°, 90° and 180° are almost overlap. The g-factor values and spin Hamiltonian parameters of 14 N and 15 N are: g = 2.0019, A⊥ = 29.73, A‖ = 40.24 and g = 2.0019, A⊥ = −39.90, A‖ = −57.05, respectively.

scholarly journals Electron Spin Resonance Of Vo2+ In Likso4 Single Crystals

2004 ◽  
Vol 59 (7-8) ◽  
pp. 488-490
Author(s):  
Manu Jain
Keyword(s):  
Electron Spin Resonance ◽  
Single Crystals ◽  
Electron Spin ◽  
Esr Spectra ◽  
Spin Hamiltonian ◽  
X Band ◽  
Spin Resonance ◽  
Hamiltonian Parameters

Electron spin resonance of VO2+ doped in LiKSO4 single crystals has been studied at 295 K, using an X-band spectrometer. Three sites have been observed. VO2+ enters the lattice at Li and K substitutional sites. The ESR spectra have been analysed and spin-Hamiltonian parameters evaluated. PACS: 76.30 F

ESR STUDY OF SPIN-HAMILTONIAN PARAMETERS AND CRYSTAL FIELD ENERGY LEVELS FOR THE LOW C3 SYMMETRY Fe3+ CENTER IN GREEN SAPPHIRE CRYSTALS AND POWDER

2007 ◽  
Vol 21 (04) ◽  
pp. 225-236 ◽  
Author(s):  
P. LIMSUWAN ◽  
N. UDOMKAN ◽  
P. WINOTAI
Keyword(s):  
Rotation Angle ◽  
Energy Levels ◽  
Heat Treating ◽  
Esr Spectra ◽  
Field Energy ◽  
Hamiltonian Matrix ◽  
Magnetic Field Direction ◽  
Spin Hamiltonian ◽  
Corundum Structure ◽  
Hamiltonian Parameters

In this report, Fe 3+ impurity ions present in green sapphire ( Al 2 O 3) were studied experimentally, by heating a light green sapphire in flowing oxygen atmosphere for 12 h from 1200, 1300, 1400, 1500 and 1600°C, respectively. Electron spin resonance (ESR) spectra in X-band (~9.45 GHz ) were recorded by mounting the crystal with the c-axis perpendicular (θ = 90°) to the magnetic field direction. The spectra were recorded and simulated by a numerical diagonalization of spin Hamiltonian matrix in the range from 0 to 180 degrees for every 15 degrees of rotation angle (φ). In our case, only the last two sets of peaks strongly depend on the rotation angle (φ), and each exhibits C 3 symmetry due to two magnetically inequivalent Fe 3+ sites in the corundum structure. For polycrystalline ESR spectra, seven main Fe 3+ ESR absorption peaks occur at the resonance magnetic fields of 100.20, 310.24, 486.80, 525.00, 550.60, 761.00 and 777.00 mT respectively. Specifically, ESR signals show that the number of paramagnetic Fe 3+ ions increase roughly linearly with the heat treating temperature, having the [Formula: see text] ratio ~1.41 at 1600°C.

Interface Defects in n-Type 3C-SiC/SiO2: An EPR Study of Oxidized Porous Silicon Carbide Single Crystals

2005 ◽  
Vol 483-485 ◽  
pp. 273-276 ◽  
Author(s):  
Hans Jürgen von Bardeleben ◽  
J.L. Cantin ◽  
L. Ke ◽  
Y. Shishkin ◽  
Robert P. Devaty ◽  
...  
Keyword(s):  
Silicon Carbide ◽  
Carbon Atom ◽  
Spin Hamiltonian ◽  
Dangling Bond ◽  
Interface Defects ◽  
X Band ◽  
Interface Defect ◽  
Bond Center ◽  
Oxidized Porous Silicon ◽  
Hamiltonian Parameters

The defects at the 3C-SiC/SiO2 interface have been studied by X-band EPR spectroscopy in oxidized porous 3C-SiC. One interface defect is detected; its spin Hamiltonian parameters, spin S=1/2, C3V symmetry, g//=2.00238 and g⊥=2.00317, central hyperfine interaction (CHF) with one carbon atom and AB//[001]=48G and superhyperfine (SHF) interaction with three equivalent Si neighbour atoms and TB//[001]=12.4G, allow us to attribute the center to a sp3 coordinated carbon dangling bond center, PbC.

EPR Studies of Mn2+-Doped Diammonium Hexaaqua Magnesium(II) Sulfate

2006 ◽  
Vol 61 (12) ◽  
pp. 683-687 ◽  
Author(s):  
Ram Kripal ◽  
Ashutosh Kumar Shukla
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Fine Structure ◽  
Single Crystals ◽  
Room Temperature ◽  
Spin Hamiltonian ◽  
Epr Spectrum ◽  
Paramagnetic Resonance ◽  
X Band ◽  
Hamiltonian Parameters ◽  
Electron Paramagnetic

Electron paramagnetic resonance (EPR) studies of Mn2+ impurity in single crystals of diammonium hexaaqua magnesium(II) sulfate have been carried out at 9.3 GHz (X-band) at room temperature. The EPR spectra exhibit a group of five fine structure transitions. The spin-Hamiltonian parameters were determined. Mn2+ enters the lattice interstitially. The EPR spectrum of a powder sample supports the data obtained by single crystal studies. - PACS number: 76.30

REDUCTION BY HYDROGEN OF VANADIUM IN PHOSPHATE AND VANADATE LEAD APATITES: AN ESR STUDY

2007 ◽  
Vol 21 (22) ◽  
pp. 1489-1500 ◽  
Author(s):  
M. IKRAM ◽  
H. AHMED ◽  
PIETRO MENDES ◽  
F. A. MIR ◽  
A. BASHIR ◽  
...  
Keyword(s):  
Solid Solution ◽  
Computer Simulations ◽  
Esr Spectroscopy ◽  
Esr Spectra ◽  
Hydrogen Gas ◽  
Charge Carriers ◽  
Spin Hamiltonian ◽  
Powder Spectrum ◽  
Hamiltonian Parameters ◽  
Vanadium Ions

A solid solution of phosphate and vanadate lead apatites Pb 10( PO 4)6-x( VO 4)x( OH )2 (x = 0.5, 1.0, 2.0, 3.0, and 6.0) were reduced with hydrogen gas at temperature 300°C for one hour. All these compounds were investigated by XRD and ESR spectroscopy. Only one reduced oxidation state, V 4+, was detected. Two types of species-like isolated vanadium (+ 4) and clusters of V 4+ were observed. The EPR powder spectrum computer simulations were performed using the program Simfonia from Bruker. Spin Hamiltonian parameters were also calculated. As the concentrations of vanadium ions increase to 2.0, the intensity of the ESR lines increases, and x = 3.0 the intensity of the ESR line decreases sharply. After this concentration, i.e. x > 3.0, there is again an increase in the intensity. The variation of the line shape and intensity of the ESR spectra can be attributed to increases in the hopping rate of the charge carriers (polarons) in different apatite compositions.

THE ELECTRON SPIN RESONANCE OF VO2+ IONS IN TWO TYPES OF ALUMINIUM ALUMS

1967 ◽  
Vol 45 (8) ◽  
pp. 2769-2777 ◽  
Author(s):  
A. Manoogian ◽  
J. A. MacKinnon
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Room Temperature ◽  
Resonance Spectrum ◽  
Microwave Frequency ◽  
Spin Hamiltonian ◽  
Vanadyl Ion ◽  
Spin Resonance ◽  
Hamiltonian Parameters ◽  
Crystallographic Axes

The electron spin resonance spectrum of the vanadyl ion VO2+ is studied in single crystals of RbAl(SO4)2.12 H2O and CsAl(SO4)2.12 H2O, at room temperature and in the 9.2 kMc/s microwave frequency range. In RbAl(SO4)2.12 H2O the V–O axes are found to have three orientations directed along the cubic crystallographic axes, giving rise to three magnetic complexes. The spin Hamiltonian parameters are S = 1/2, [Formula: see text], [Formula: see text], [Formula: see text] cm−1, and [Formula: see text] cm−1. In CsAl(SO4)2.12 H2O the V–O axes are displaced from the crystallographic axes, giving rise to 12 magnetic complexes. The spin Hamiltonian parameters are S = 1/2, [Formula: see text], [Formula: see text], [Formula: see text] cm−1, and [Formula: see text] cm−1. The observed spectra are attributed to a vanadyl pentahydrate complex (VO2+.5 H2O) associated with a water-molecule vacancy.

EPR of VO2+ in ZnCs2(SO4)2 · 6 H2O Single Crystals

1977 ◽  
Vol 32 (9) ◽  
pp. 1068-1069 ◽  
Author(s):  
V. K. Jain ◽  
T. M. Srinivasan
Keyword(s):  
Single Crystals ◽  
Spin Hamiltonian ◽  
X Band ◽  
Hamiltonian Parameters

Abstract The EPR of VO2+ is studied in single crystals of ZnCs2(SO)4)2 · 6 H2O at X-band. The V-0 axis is found to have two orientations. The spin-Hamiltonian parameters at 298 K are determined.

EPR Studies of Tb 4+ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates

1996 ◽  
Vol 51 (8) ◽  
pp. 885-894 ◽  
Author(s):  
S. Hansen ◽  
B. D. Mosel ◽  
W. Müller-Warmuth ◽  
P. E. Fielding
Keyword(s):  
Magnetic Field ◽  
Zero Field ◽  
Scheelite Structure ◽  
Spin Hamiltonian ◽  
Field Limit ◽  
Paramagnetic Resonance ◽  
Zircon Structure ◽  
X Band ◽  
Hamiltonian Parameters ◽  
Electron Paramagnetic

Abstract Electron paramagnetic resonance spectra of tetravalent terbium ions have been observed in host crystals of ZrSiO4 , HfSiO4 , ThSiO4 , ThGeO4 (zircon structure) and ZrGeO4 , HfGeO4 (scheelite structure) at X band and Q band and various temperatures. The spin Hamiltonian parameters have been determined from the rotational diagrams; the zero field splittings turned out to be extremely large, so that complex spectra far from the strong magnetic field limit had to be analyzed. In all the compounds Tb4+ substitutes for the tetragonal metal lattice sites. The incorporation of terbium, the origin of the large second-order parameters and comparisons with the spectra of trivalent gadolinium in similar systems are discussed.

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