MAGNETIC PROPERTIES OF (GdxZr1-x)2CoAl3 SYSTEM

2009 ◽  
Vol 23 (10) ◽  
pp. 1345-1350
Author(s):  
ILEANA LUPŞA ◽  
T. PETRIŞOR

The magnetic properties of the ( Gd x Zr 1-x)2 CoAl 3 system were investigated in the 4–700 K temperature range and fields up to 70 kOe. The systems seem to be ferrimagnetically ordered. In the ordered state, the Co moments opposite to the gadolinium ones have very low values. The paramagnetic properties evidence over a characteristic temperature T*, a Curie–Weiss type behavior and the presence of the effective magnetic moments on Co atoms. The paramagnetic behavior of cobalt is analyzed in the spin fluctuations model.

2006 ◽  
Vol 20 (21) ◽  
pp. 1343-1349
Author(s):  
ILEANA LUPSA

The magnetic properties of the Dy x U 1-x AlCo 3 system, investigated in the 4–800 K temperature range and fields up to 80 kOe indicated ferrimagnetic order for x≥0.2. The cobalt magnetic moments opposite to dysprosium and the Curie temperatures decrease with decreasing Dy content. The internal magnetic field dependence of the Co moment shows that cobalt moment becomes saturated above 1000 kOe. The high temperature paramagnetic behavior follows a Curie–Weiss type law evidencing effective magnetic moments on Co positions. The paramagnetic properties are analyzed in the spin fluctuations model.


2003 ◽  
Vol 17 (27n28) ◽  
pp. 1453-1460
Author(s):  
ILEANA LUPSA

The magnetic properties of U 1-x Dy x Al y Ni 5-y (y=0,1) systems were investigated in the 2(5)–600 K temperature range and for fields up to 80 kOe. The systems having x≥0.2 are magnetically ordered with low transition temperatures and magnetization mainly due to the Dy contribution. The nickel exhibits magnetic moments, very weak in the low temperature range and well-defined effective moments over transition temperatures. The nickel behavior is discussed in terms of the spin fluctuation model.


1992 ◽  
Vol 06 (23n24) ◽  
pp. 3953-3958 ◽  
Author(s):  
Kazuyoshi Tanaka ◽  
Anvar A. Zakhidov ◽  
Kazunari Yoshizawa ◽  
Kenji Okahara ◽  
Tokio Yamabe ◽  
...  

Magnetic properties of C 60 and C 70 complexes with tetrakis(dimethylamino)ethylene (TDAE) have been studied based on the measurements of the Faraday-balance magnetization and the electron spin resonance (ESR). It has been found that both TDAE- C 60 and TDAE- C 70 possess about one radical spin per fullerene molecule. TDAE- C 60 has been confirmed to show ferromagnetic-type transition at Tc=16.7–17.5 K . Appearance of a new broad and intense ESR signal below Tc of TDAE- C 60 suggests that the radical spins in the magnetically ordered state rather localize on each C 60 molecule and are ferromagnetically correlated. On the other hand, TDAE- C 70 does not show ferromagnetism in all the temperature range down to 4.5K.


Author(s):  
O.K. Kuvandikov ◽  
◽  
N.I. Leonyuk ◽  
V.V. Malsev ◽  
M.M. Kuzmin ◽  
...  

Temperature dependence of the magnetic susceptibility has been studied for rare-earth borates NdCr3(BO3)4, SmCr3(BO3)4 and LuCr3(BO3)4 by the Faradey method in the wide temperature range (300-1200 K). The dependence for each phase follows the Curi - Weis law. The Curie temperatures, Neel temperatures and magnetic moments corresponding to the chemical formula of the crystals, have been found.


1968 ◽  
Vol 21 (1) ◽  
pp. 83 ◽  
Author(s):  
HA Goodwin ◽  
RN Sylva

The magnetism of the salts [Fe mephen3]X2 (X = I-, ClO4-, BF4-, PF6-; mephen = 2-methyl- 1,l0-phenanthroline) has been investigated over the temperature range c. 100-300�K. The compounds exhibit anomalous behaviour, and this has been qualitatively interpreted as being the result of the presence of nearly equi-energetic ground terms 1A1 and 5T2 of the complexed iron(11) ion, a thermal equilibrium between these terms causing the magnetic moments to be markedly temperature dependent. This behaviour is apparently the result of the sterie hindrance to the coordination of an iron(11) ion induced by the presence of the methyl group in the ligand and the consequent lowering of the effective strength of the ligand field. The colour of the salts varies with temperature, and this has been discussed in terms of π-bonding between the iron(11) ion and the ligand.


2003 ◽  
Vol 17 (22) ◽  
pp. 1181-1185 ◽  
Author(s):  
P. Lucaci ◽  
Ileana Lupsa

The magnetic properties of the U 1-x Y x NiAl system were studied in the 4–600 K temperature range fields up to 7 T. The systems with x≤0.8 were analyzed in terms of the spin fluctuations theory. The system presents a Curie–Weiss type behavior over a certain temperature T*. The paramagnetic Curie temperatures are negative and decrease in absolute magnitude as yttrium content increases. The effective magnetic moment per uranium atom is composition independent (≈3.1 μB) proving the presence of temperature induced spin fluctuations.


Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 378
Author(s):  
Li Zhao ◽  
Zhiwei Hu ◽  
Hanjie Guo ◽  
Christoph Geibel ◽  
Hong-Ji Lin ◽  
...  

We report on the synthesis and physical properties of cm-sized CoGeO3 single crystals grown in a high pressure mirror furnace at pressures of 80 bar. Direction dependent magnetic susceptibility measurements on our single crystals reveal highly anisotropic magnetic properties that we attribute to the impact of strong single ion anisotropy appearing in this system with TN∼33.5 K. Furthermore, we observe effective magnetic moments that are exceeding the spin only values of the Co ions, which reveals the presence of sizable orbital moments in CoGeO3.


2021 ◽  
Vol 859 ◽  
pp. 158290
Author(s):  
S. Udhayakumar ◽  
G. Jagadish Kumar ◽  
E. Senthil Kumar ◽  
M. Navaneethan ◽  
K. Kamala Bharathi

1995 ◽  
Vol 384 ◽  
Author(s):  
Zhi-Qiang Li ◽  
Yuichi Hashi ◽  
Jing-Zhi Yu ◽  
Kaoru Ohno ◽  
Yoshiyuki Kawazoe

ABSTRACTThe electronic structure and magnetic properties of rhodium clusters with sizes of 1 - 43 atoms embedded in the nickel host are studied by the first-principles spin-polarized calculations within the local density functional formalism. Single Rh atom in Ni matrix is found to have magnetic moment of 0.45μB. Rh13 and Rhl 9 clusters in Ni matrix have lower magnetic moments compared with the free ones. The most interesting finding is tha.t Rh43 cluster, which is bulk-like nonmagnetic in vacuum, becomes ferromagnetic when embedded in the nickel host.


Sign in / Sign up

Export Citation Format

Share Document