Capillary-Dominated Fluid Displacement in Porous Media

2019 ◽  
Vol 51 (1) ◽  
pp. 429-449 ◽  
Author(s):  
Kamaljit Singh ◽  
Michael Jung ◽  
Martin Brinkmann ◽  
Ralf Seemann

Liquid invasion into a porous medium is a phenomenon of great importance in both nature and technology. Despite its enormous importance, there is a surprisingly sparse understanding of the processes occurring on the scale of individual pores and of how these processes determine the global invasion pattern. In particular, the exact influence of the wettability remains unclear besides the limiting cases of very small or very large contact angles of the invading fluid. Most quantitative pore-scale experiments and theoretical considerations have been conducted in effectively two-dimensional (2D) micromodels and Hele–Shaw geometries. Although these pioneering works helped to unravel some of the physical aspects of the displacement processes, the relevance of 2D models has not always been appreciated for natural porous media. With the availability of X-ray microtomography, 3D imaging has become a standard for exploring pore-scale processes in porous media. Applying advanced postprocessing routines and synchrotron microtomography, researchers can image even slow flow processes in real time and extract relevant material parameters like the contact angle from the interfaces in the pore space. These advances are expected to boost both theoretical and experimental understanding of pore-scale processes in natural porous media.

2021 ◽  
Author(s):  
Pietro de Anna ◽  
Amir A. Pahlavan ◽  
Yutaka Yawata ◽  
Roman Stocker ◽  
Ruben Juanes

<div> <div> <div> <p>Natural soils are host to a high density and diversity of microorganisms, and even deep-earth porous rocks provide a habitat for active microbial communities. In these environ- ments, microbial transport by disordered flows is relevant for a broad range of natural and engineered processes, from biochemical cycling to remineralization and bioremediation. Yet, how bacteria are transported and distributed in the sub- surface as a result of the disordered flow and the associ- ated chemical gradients characteristic of porous media has remained poorly understood, in part because studies have so far focused on steady, macroscale chemical gradients. Here, we use a microfluidic model system that captures flow disorder and chemical gradients at the pore scale to quantify the transport and dispersion of the soil-dwelling bacterium Bacillus subtilis in porous media. We observe that chemotaxis strongly modulates the persistence of bacteria in low-flow regions of the pore space, resulting in a 100% increase in their dispersion coefficient. This effect stems directly from the strong pore-scale gradients created by flow disorder and demonstrates that the microscale interplay between bacterial behaviour and pore-scale disorder can impact the macroscale dynamics of biota in the subsurface.</p> </div> </div> </div>


2021 ◽  
Author(s):  
Marco Dentz ◽  
Alexandre Puyguiraud ◽  
Philippe Gouze

<p>Transport of dissolved substances through porous media is determined by the complexity of the pore space and diffusive mass transfer within and between pores. The interplay of diffusive pore-scale mixing and spatial flow variability are key for the understanding of transport and reaction phenomena in porous media. We study the interplay of pore-scale mixing and network-scale advection through heterogeneous porous media, and its role for the evolution and asymptotic behavior of hydrodynamic dispersion. In a Lagrangian framework, we identify three fundamental mechanisms of pore-scale mixing that determine large scale particle motion: (i) The smoothing of intra-pore velocity contrasts, (ii) the increase of the tortuosity of particle paths, and (iii) the setting of a maximum time for particle transitions. Based on these mechanisms, we derive an upscaled approach that predicts anomalous and normal hydrodynamic dispersion based on the characteristic pore length, Eulerian velocity distribution and Péclet number. The theoretical developments are supported and validated by direct numerical flow and transport simulations in a three-dimensional digitized Berea sandstone sample obtained using X-Ray microtomography. Solute breakthrough curves, are characterized by an intermediate power-law behavior and exponential cut-off, which reflect pore-scale velocity variability and intra-pore solute mixing. Similarly, dispersion evolves from molecular diffusion at early times to asymptotic hydrodynamics dispersion via an intermediate superdiffusive regime. The theory captures the full evolution form anomalous to normal transport behavior at different Péclet numbers as well as the Péclet-dependence of asymptotic dispersion. It sheds light on hydrodynamic dispersion behaviors as a consequence of the interaction between pore-scale mixing and Eulerian flow variability. </p>


2016 ◽  
Vol 113 (37) ◽  
pp. 10251-10256 ◽  
Author(s):  
Benzhong Zhao ◽  
Christopher W. MacMinn ◽  
Ruben Juanes

Multiphase flow in porous media is important in many natural and industrial processes, including geologic CO2 sequestration, enhanced oil recovery, and water infiltration into soil. Although it is well known that the wetting properties of porous media can vary drastically depending on the type of media and pore fluids, the effect of wettability on multiphase flow continues to challenge our microscopic and macroscopic descriptions. Here, we study the impact of wettability on viscously unfavorable fluid–fluid displacement in disordered media by means of high-resolution imaging in microfluidic flow cells patterned with vertical posts. By systematically varying the wettability of the flow cell over a wide range of contact angles, we find that increasing the substrate’s affinity to the invading fluid results in more efficient displacement of the defending fluid up to a critical wetting transition, beyond which the trend is reversed. We identify the pore-scale mechanisms—cooperative pore filling (increasing displacement efficiency) and corner flow (decreasing displacement efficiency)—responsible for this macroscale behavior, and show that they rely on the inherent 3D nature of interfacial flows, even in quasi-2D media. Our results demonstrate the powerful control of wettability on multiphase flow in porous media, and show that the markedly different invasion protocols that emerge—from pore filling to postbridging—are determined by physical mechanisms that are missing from current pore-scale and continuum-scale descriptions.


Georesursy ◽  
2020 ◽  
Vol 22 (1) ◽  
pp. 4-12
Author(s):  
Timur R. Zakirov ◽  
Maxim G. Khramchenkov

This paper presents the results of numerical simulations of two-phase flows in porous media under capillary forces dominance. For modeling of immiscible two-phase flow, the lattice Boltzmann equations with multi relaxation time operator were applied, and the interface phenomena was described with the color-gradient method. The objective of study is to establish direct links between quantitative characteristics of the flow and invasion events, using high temporal resolution when detecting simulation results. This is one of the few works where Haines jumps (rapid invasion event which occurs at meniscus displacing from narrow pore throat to its wide body) are considered in three-dimensional natural pore space, but the focus is also on the displacement mechanics after jumps. It was revealed the sequence of pore scale events which can be considered as a period of drainage process: rapid invasion event during Haines jump; finish of jump and continuation of uniform invasion in current pore; switching of mobile interfaces and displacement in new region. The detected interface change, along with Haines jump, is another distinctive feature of the capillary forces action. The change of the mobile interfaces is manifested in step-like behavior of the front movement. It was obtained that statistical distributions of pressure drops during Haines jumps obey lognormal law. When investigating the flow rate and surface tension effect on the pressure drop statistics it was revealed that these parameters practically don’t affect on the statistical distribution and influence only on the magnitude of pressure drops and the number of individual Haines jumps.


Author(s):  
J. S. Ellis ◽  
A. Ebrahimi ◽  
A. Bazylak

Sequestration of carbon dioxide in deep underground reservoirs has been discussed for the reduction of atmospheric greenhouse gas emissions in the short- to medium-term until more sustainable technologies are available. Cost and long-term stability are major factors in adoption, so techniques to improve the storage efficiency and trapping security are essential. Such improvements require modeling of the porous geological formations involved in the sequestration process, and comparison to both lab- and field-based experimental studies. To this end, we are developing a comprehensive, large-scale pore-network model to describe multi-phase flow in porous media, including the structural, dissolution, and mineral trapping regimes. To explore the optimal operating parameters for mineralization trapping, we describe a two-phase pore-network model of brine-saturated aquifers and model the invasion of supercritical carbon dioxide (CO2) into the pore structure. Regularly-aligned 2D and 3D pore networks are constructed, and rules-based transport models are used to characterize the saturation behavior over a range of viscosity and capillary parameters, and coordination numbers. Finally, saturation patterns are presented for model caprock and sandstone reservoir conditions, taking into account different contact angles for CO2 on mica and quartz at supercritical conditions. These saturation patterns demonstrate the importance of surface heterogeneities in pore-scale modeling of deep saline aquifers.


1985 ◽  
Vol 25 (01) ◽  
pp. 89-100 ◽  
Author(s):  
J. Koplik ◽  
T.J. Lasseter

Abstract To explore how the microscopic geometry of a pore space affects the macroscopic characteristics of fluid flow in porous media, we have used approximate solutions of the porous media, we have used approximate solutions of the Navier-Stokes equations to calculate the flow of two fluids in random networks. The model pore space consists of an array of pores of variable radius connected to a random number of nearest neighbors by throats of variable length and radius. The various size and connectedness distributions may be arbitrarily assigned, as are the wetting characteristics of the two fluids in the pore space. The fluids are assumed to be incompressible, immiscible. Newtonian, and of equal viscosity. In the calculation, we use Stokes flow results for the motion of the individual fluids and incorporate microscopic capillary force by using the Washburn approximation. At any time, the problem is mathematically identical to a random electrical network of resistors, batteries, and diodes. From the numerical solution of the latter, we compute the fluid velocities and saturation rates of change and use a discrete timestepping procedure to follow the subsequent motion. The scale of the computation has restricted us so far to networks of hundreds of pores in two dimensions (2D). Within these limitations, we discuss the dependence of residual oil saturations and interface shapes on network geometry and flow conditions. Introduction A significant limitation to our understanding of the dynamics of multiphase fluids in porous media is the inability to connect the physics at the microscopic scale to the macroscopic phenomena observed in the laboratory and in the field. Within individual pores, the motion of fluids and menisci can be discussed, at least approximately, in terms of the microgeometry and the physical characteristics of the liquids. gases, and solids present. On the macroscopic scale, the multiphase Darcy equations involving several empirical parameters-relative permeabilities and average capillary pressures permeabilities and average capillary pressures conventionally are used. The connection between these two levels of description, if there is one, has never been elucidated despite years of effort (as reviewed by Scheidegger ). In consequence, it is difficult to predict the behavior of oil reservoirs in advance, and considerable waste of money, effort, and resources can ensue. Economic issues aside, this situation provides another example of a pervasive problem in physics: macroscopic averaging of a random problem in physics: macroscopic averaging of a random microscopically disordered medium to predict large-scale behavior from a knowledge of small-scale dynamics. In optimal circumstances, existing methods in the physics literature (i.e., Ziman ) can be used to carry out physics literature (i.e., Ziman ) can be used to carry out the averaging. For fluid problems, for example, percolation theory has been applied to the spatial distribution of percolation theory has been applied to the spatial distribution of fluids in a pore space, both in static situations and in quasistatic displacement. Another set of ideas, effective medium theories, has been applied to electrical conductivity and its fluid analog, absolute permeability. The general fluid displacement problem, when both permeability. The general fluid displacement problem, when both capillary and viscous forces are present, is related to a class of physics problems that are as yet unresolved, such as crystal growth, surface evolution, and dynamic percolation. In this situation, we are forced to resort to percolation. In this situation, we are forced to resort to brute-force numerical modeling, both as a means of obtaining statistical information and as a guide to approximations that may permit future analytical work. In this paper, we describe our initial efforts to calculate the motion of two fluids in porous media from the microscopic scale up, starting from the Stokes equations and boundary conditions in this pore space. As usual, we model the porous medium as a network of similarly shaped, but randomly sized, elements. The key to the calculation is the mathematical analogy between the fluid problem and an appropriate electrical network of random problem and an appropriate electrical network of random resistors, batteries, and diodes. The calculation is a very difficult one, numerically speaking, and to date we have been restricted to fairly small 2D networks of hundreds of pores. We expect, however, that with more sophisticated programming methods our approach can be applied to three-dimensional (3D) networks of thousands of pores. pores. After this work was in progress, we came across a paper of Singhal and Somerton where a similar calculational framework was used but with a different emphasis. Those authors considered a single realization of a small network of triangular channels of random sizes with flow regimes randomly assigned in each channel and compute the relative permeabilities and capillary pressure curves of the network. Our emphasis in this paper is on time-dependent phenomena and statistical averaging of flow quantities. We also note the somewhat related work by Payatakes et al., who considered a square lattice of Payatakes et al., who considered a square lattice of converging/diverging tubes meeting at point nodes and simulate the dislodgement of blobs of trapped oil. Subsequently, Dias and Payatakes used the same geometry and calculational rules similar to those employed here to study fluid displacement. SPEJ P. 89


Author(s):  
Zhenyu Liu ◽  
Huiying Wu

The utilization of porous media can enhance the heat transfer process due to its large heat transfer area within limited space. The natural convection in porous media widely exists in various heat transfer equipment and the related flow and heat transfer in porous spaces is one complicated transport phenomenon, for which the accurate prediction is challenging. Pore-scale models can predict transport phenomena in porous media in pore space, which can be used in the modeling of flow and heat transfer in porous media under local thermal non-equilibrium condition. The pore-scale study includes the reconstruction of porous structure and the direct numerical simulation of transport phenomena in the pore spaces. In this paper, the geometrical reconstruction approach was developed to generate the porous region using the tomographic reconstruction, which is one nondestructive imaging technique. The porous sample was scanned on a micro-CT scanner with micrometer resolution. 2D sliced scan images were obtained and then stacked to reconstruct the 3D porous geometry. A double-population thermal lattice Boltzmann model was established to predict the natural convection in reconstructed porous media at pore scale.


2020 ◽  
Vol 561 ◽  
pp. 173-180 ◽  
Author(s):  
Chenhao Sun ◽  
James E. McClure ◽  
Peyman Mostaghimi ◽  
Anna L. Herring ◽  
Mehdi Shabaninejad ◽  
...  

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