A CFD Study with Analytical and Experimental Validation of Laminar and Turbulent Mass-Transfer in Electrochemical Reactors

2018 ◽  
Vol 165 (2) ◽  
pp. E81-E88 ◽  
Author(s):  
A. N. Colli ◽  
J. M. Bisang
2011 ◽  
Vol 133 (8) ◽  
Author(s):  
Dong-Hyeog Yoon ◽  
Kyung-Soo Yang ◽  
Klaus Bremhorst

Characteristics of turbulent mass transfer around a rotating circular cylinder have been investigated by Direct Numerical Simulation. The concentration field was computed for three different cases of Schmidt number, Sc = 1, 10 and 100 at ReR* = 336. Our results confirm that the thickness of the Nernst diffusion layer decreases as Sc increases. Wall-limiting behavior within the diffusion layer was examined and compared with that of channel flow. Concentration fluctuation time scale was found to scale with r+2, while the time scale ratio nearly equals the Schmidt number throughout the diffusion layer. Scalar modeling closure constants based on gradient diffusion models were found to vary considerably within the diffusion layer. Results of an octant analysis show the significant role played by the ejection and sweep events just as is found for flat plate, channel, and pipe flow boundary layers. Turbulence budgets revealed a strong Sc dependence of turbulent scalar transport.


2012 ◽  
Vol 550-553 ◽  
pp. 2014-2018
Author(s):  
Xiao Lan Zhou ◽  
Cai Xi Liu ◽  
Yu Hong Dong

Electrochemical mass transfer in turbulent flows and binary electrolytes is investigated. The primary objective is to provide information about mass transfer in the near-wall region between a solid boundary and a turbulent fluid flow at different Schmidt numbers. Based on the computational fluid dynamics and electrochemistry theories, a model for turbulent electrodes channel flow is established. The turbulent mass transfer in electrolytic processes has been predicted by the direct numerical simulation method under limiting current and galvanostatic conditions, we investigate mean concentration and the structure of the concentration fluctuating filed for different Schmidt numbers from 0.1 to 100 .The effect of different concentration boundary conditions at the electrodes on the near-wall turbulence statistics is also discussed.


1972 ◽  
Vol 8 (7) ◽  
pp. 630-631
Author(s):  
V. A. Garin ◽  
V. V. Mazaev ◽  
A. F. Semenov ◽  
Yu. V. Poplavskii

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