An in Situ Graphite-Grafted Alkaline Iron Electrode for Iron-Based Accumulators

Keyword(s):  
2014 ◽  
Vol 7 (3) ◽  
pp. 1110 ◽  
Author(s):  
Aravamuthan Sundar Rajan ◽  
Srinivasan Sampath ◽  
Ashok Kumar Shukla
Keyword(s):  

2021 ◽  
Vol 63 (7) ◽  
pp. 630-638
Author(s):  
Mustafa Kaptanoglu ◽  
Mehmet Eroglu

Abstract In the study for this contribution, production of in situ synthesized TiB2 particles in iron-based composite coatings using four different submerged arc welding powders (fluxes) containing increasing amounts of ferrotitanium and ferroboron with S1 welding wire, were targeted. For this purpose, coating deposition was carried out to improve the hardness and wear properties of the AISI 1020 steel surfaces using hybrid submerged arc welding. In hybrid submerged arc welding, the welding pool is protected by both welding powders and an argon gas atmosphere. To examine the composite coatings, visual, chemical, microstructural analyses and hardness and wear tests were carried out. With the use of increasing amounts of ferrotitanium and ferroboron in the welding powders, it was observed that the microstructure of the coatings changed in terms of TiB2 particle geometries such as rectangular and hexagonal; volume fractions of TiB2 particles in the coating microstructures increased; hardness values of coatings were enhanced from 34 HRC to 41 HRC; the wear resistance of the coatings improved, and worn surface images of the coatings caused by the counter body changed from continuous with deep scratches to discontinuous with fine scratches and crater cavities.


2020 ◽  
Author(s):  
Barbara Souza ◽  
Jin-Chong Tan

We report two solvent-free mechanochemical methods to achieve one‑pot encapsulation of anti-cancer drug 5‑Fluorouracil (5‑FU) in the iron-based MIL‑100 metal-organic framework (MOF). We compare the structural and physicochemical properties of drug@MIL‑100 systems derived from <i>in situ </i>manual and vortex grinding, where the former exhibits a slower drug release due to stronger guest-host interactions.


2021 ◽  
pp. 73-122
Author(s):  
Jose Daniel Biasoli de Mello ◽  
Cristiano Binder ◽  
Sonia Maria Hickel Probst ◽  
Aloisio Nelmo Klein
Keyword(s):  

Metals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 554
Author(s):  
Fehmi Nair ◽  
Mustafa Hamamcı

The objective of this study is to investigate the impact behavior of iron-based composites reinforced with boron carbide (B4C) particles and in-situ synthesized iron borides (Fe2B/FeB). The composite specimens (Fe/B4C) were fabricated by hot-pressing under a pressure of 250 MPa at 500 °C, and sintered at a temperature of 1000 °C. The effects of the reinforcement ratio on the formation of in-situ borides and impact behavior were investigated by means of different volume fractions of B4C inside the iron matrix: 0% (un-reinforced), 5%, 10%, 20%, and 30%. Drop-weight impact tests were performed by an instrumented Charpy impactor on reinforced and un-reinforced test specimens. The results of the impact tests were supported with microstructural and fractographical analysis. As a result of in-situ reactions between the Fe matrix and B4C particles, Fe2B phases were formed in the iron matrix. The iron borides, formed in the iron matrix during sintering, heavily affected the hardness and the morphology of the fractured surface. Due to the high amount of B4C (over 10%), porosity played a major role in decreasing the contact forces and fracture energy. The results showed that the in-situ synthesized iron boride phases affect the impact properties of the Fe/B4C composites.


RSC Advances ◽  
2019 ◽  
Vol 9 (36) ◽  
pp. 20687-20697
Author(s):  
Dajun Zhai ◽  
Yue Shui ◽  
Keqin Feng ◽  
Yanyan Zhang

In this work, we prepared an iron-based frictional material from vanadium-bearing titanomagnetite concentrates by in situ carbothermic reaction with improved tribological properties.


2018 ◽  
Vol 1 (1) ◽  
Author(s):  
Chuande Huang ◽  
Jian Wu ◽  
You-Tao Chen ◽  
Ming Tian ◽  
Alexandre I. Rykov ◽  
...  

2020 ◽  
Vol 8 (35) ◽  
pp. 18367-18375
Author(s):  
Taotao Gao ◽  
Caixia Zhou ◽  
Xiaojuan Chen ◽  
Zhihan Huang ◽  
Hongyan Yuan ◽  
...  

The FeCO3@IF electrode based on Fe2(SO4)3 as iron resource shows efficient catalytic performance for both OER and HER due to the unique in situ self-reconstructing hierarchical structures induced by the surface corrosion of FeCO3 compounds.


1999 ◽  
Vol 64 (12) ◽  
pp. 2044-2060 ◽  
Author(s):  
Karel Bouzek ◽  
Martin Nejezchleba

In situ Mössbauer spectra of the iron electrode at anodic potential were measured in sodium hydroxide solution over a wide range of concentrations (0.1 - 14 mol l-1). It was found that the in situ Mössbauer spectra exhibit generally one sextet and one doublet corresponding to the oxide layer on the anode surface. Parameters of these spectra show only minor variations within the electrolyte concentration range of 0.1 - 7 M NaOH. A pronounced change in the spectra was observed in 14 M NaOH. The major processes taking place in the anode surface layer are based on the break-down of protective properties of the passive layer, incipient intense metal dissolution and subsequent oxidation. Important differences were also found between in situ and ex situ spectra measurements.


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