scholarly journals Synthesis of Nickel-Encapsulated Carbon Nanocapsules and Cup-Stacked-Type Carbon Nanotubes via Nickel-Doped Fullerene Nanowhiskers

2012 ◽  
Vol 2012 ◽  
pp. 1-5
Author(s):  
Tokushi Kizuka ◽  
Kun'ichi Miyazawa ◽  
Akira Akagawa

Nickel- (Ni) doped C60nanowhiskers (NWs) were synthesized by a liquid-liquid interfacial precipitation method using a C60-saturated toluene solution and isopropanol with Ni nitrate hexahydrate Ni(NO3)2·6H2O. By varying the heating temperature of Ni-doped C60NWs, two types of one-dimensional carbon nanostructures were produced. By heating the NWs at 973 and 1173 K, carbon nanocapsules (CNCs) that encapsulated Ni nanoparticles were produced. The Ni-encapsulated CNCs joined one dimensionally to form chain structures. Upon heating the NWs to 1373 K, cup-stacked-type carbon nanotubes were synthesized.

2012 ◽  
Vol 2012 ◽  
pp. 1-4 ◽  
Author(s):  
Daisuke Matsuura ◽  
Kun'ichi Miyazawa ◽  
Tokushi Kizuka

We synthesized cobalt- (Co-) doped C60 nanowhiskers (NWs) by applying a liquid-liquid interfacial precipitation method using a C60-saturated toluene solution and 2-propanol with Co nitrate hexahydrate (Co(NO3)3⋅6H2O). Heating the NWs at 873–1173 K produced carbon nanocapsules (CNCs) that encapsulated Co clusters with a hexagonal-closed-packed structure. After heating at 1273 K, the encapsulated Co clusters in CNCs were transformed into orthorhombic Co2C clusters. It was found that Co- and Co2C-encapsulated CNCs can be produced by varying heating temperature.


2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Tokushi Kizuka ◽  
Kun'ichi Miyazawa ◽  
Daisuke Matsuura

We synthesized iron-(Fe-)doped C60nanowhiskers (NWs) by applying the liquid-liquid interfacial precipitation method that employs a C60-saturated toluene solution and a solution of 2-propanol containing ferric nitrate nonahydrate (Fe(NO3)3⋅9H2O). Fe particles of 3–7 nm in diameter were precipitated in the NWs. By heating at 1173 K, the NWs were transformed into hollow and Fe3C-encapsulated carbon nanocapsules and carbon nanotubes.


Nano Letters ◽  
2011 ◽  
Vol 11 (6) ◽  
pp. 2464-2471 ◽  
Author(s):  
Renu Sharma ◽  
See-Wee Chee ◽  
Andrew Herzing ◽  
Ryan Miranda ◽  
Peter Rez

2015 ◽  
Vol 2015 ◽  
pp. 1-5
Author(s):  
Chao-Gang Wang ◽  
Xiao-Hong Shao ◽  
Rui-Sheng Xue

The formation of carbon nanotubes (CNTs), spherical carbon nanocapsules (CNCs), and carbon spheres (CSs) is accomplished by using the method of reactions under autogenic pressure at elevated temperatures (RAPET). A powder mixture of naphthalene and nickel acetate tetrahydrate is dissociated under its autogenic pressure. The resultant CNTs and CNCs exhibit good graphitic quality, and the diameters range from 50~200 nm. Smooth and monodisperse CSs with the diameter ranging from 5~10 μm can be obtained by pyrolysis of pure naphthalene. Our results show that the reaction temperature and catalyst proportion play a key role in the formation of carbon nanostructures with RAPET method.


2021 ◽  
Author(s):  
Mingjie Li ◽  
Xuan Zheng ◽  
Xiang Li ◽  
Youjun Yu ◽  
Jinlong Jiang

Recently, transition metal selenides have been investigated extensively as promising electrode materials for high-performance supercapacitors. Herein, the multi-component CoSe2/CNTs@g-C3N4 composites are prepared using a two-step hydrothermal method by incorporating one-dimensional...


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Sheng Wang ◽  
SeokJae Yoo ◽  
Sihan Zhao ◽  
Wenyu Zhao ◽  
Salman Kahn ◽  
...  

AbstractSurface plasmons, collective electromagnetic excitations coupled to conduction electron oscillations, enable the manipulation of light–matter interactions at the nanoscale. Plasmon dispersion of metallic structures depends sensitively on their dimensionality and has been intensively studied for fundamental physics as well as applied technologies. Here, we report possible evidence for gate-tunable hybrid plasmons from the dimensionally mixed coupling between one-dimensional (1D) carbon nanotubes and two-dimensional (2D) graphene. In contrast to the carrier density-independent 1D Luttinger liquid plasmons in bare metallic carbon nanotubes, plasmon wavelengths in the 1D-2D heterostructure are modulated by 75% via electrostatic gating while retaining the high figures of merit of 1D plasmons. We propose a theoretical model to describe the electromagnetic interaction between plasmons in nanotubes and graphene, suggesting plasmon hybridization as a possible origin for the observed large plasmon modulation. The mixed-dimensional plasmonic heterostructures may enable diverse designs of tunable plasmonic nanodevices.


2003 ◽  
Vol 34 (3-6) ◽  
pp. 371-375
Author(s):  
T Sasaki ◽  
K Miyamoto ◽  
N Oguri ◽  
K Ishibashi ◽  
N Aoki ◽  
...  

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