scholarly journals Thermochemical Equilibrium Model of Synthetic Natural Gas Production from Coal Gasification Using Aspen Plus

2014 ◽  
Vol 2014 ◽  
pp. 1-18 ◽  
Author(s):  
Rolando Barrera ◽  
Carlos Salazar ◽  
Juan F. Pérez

The production of synthetic or substitute natural gas (SNG) from coal is a process of interest in Colombia where the reserves-to-production ratio (R/P) for natural gas is expected to be between 7 and 10 years, while the R/P for coal is forecasted to be around 90 years. In this work, the process to produce SNG by means of coal-entrained flow gasifiers is modeled under thermochemical equilibrium with the Gibbs free energy approach. The model was developed using a complete and comprehensive Aspen Plus model. Two typical technologies used in entrained flow gasifiers such as coal dry and coal slurry are modeled and simulated. Emphasis is put on interactions between the fuel feeding technology and selected energy output parameters of coal-SNG process, that is, energy efficiencies, power, and SNG quality. It was found that coal rank does not significantly affect energy indicators such as cold gas, process, and global efficiencies. However, feeding technology clearly has an effect on the process due to the gasifying agent. Simulations results are compared against available technical data with good accuracy. Thus, the proposed model is considered as a versatile and useful computational tool to study and optimize the coal to SNG process.

SPE Journal ◽  
2016 ◽  
Vol 21 (05) ◽  
pp. 1782-1792
Author(s):  
Maxian B. Seales ◽  
Jill Marcelle-De Silva ◽  
Turgay Ertekin ◽  
John Yilin Wang

Summary It is anticipated that increasing pressure for cleaner burning fuels and lower carbon dioxide (CO2) emissions will cause a shift in global energy demand from oil to natural gas. In the near future, natural gas is expected to replace crude oil as the fuel of choice for energy production and transportation. In Trinidad and Tobago, natural-gas production has already surpassed crude-oil production. Natural gas accounts for 80% of the country's energy export, but the reserves-to-production ratio is only 7 years (year 2022). Consequently, the Ministry of Energy has taken steps to supplement the natural-gas resource base by supporting initiatives that can potentially bolster the nation's proven gas reserves. Such initiatives include invitations to tender on deepwater blocks offshore Trinidad and Tobago's gas-rich east coast. Even though initiatives are under way to boost conventional natural-gas reserves, effort was not placed on identifying and/or characterizing unconventional gas resources such as natural-gas hydrates. Furthermore, the potential hazards of submarine gas hydrates on deepwater exploration and production (E&P) activities on Trinidad and Tobago's east coast were not assessed. The results presented in this manuscript provide oil-and-gas operators with a means of proactively managing the risk associated with natural-gas hydrates. More importantly, this study acts as a necessary precursor to future studies in characterizing and, later, harnessing the energy potential of Trinidad-and-Tobago's natural-gas-hydrate deposits.


2016 ◽  
Vol 25 (41) ◽  
pp. 41
Author(s):  
Juan Fernando Pérez-Bayer ◽  
Rolando Barrera-Zapata ◽  
Carlos Alberto Salazar-Jiménez

<p>The effect of coal rank (from sub-bituminous to semi-anthracite) and type of fuel feeding technology (slurry and dry) on the production of substitute natural gas (SNG) in entrained flow gasifiers is studied. Ten coals from important Colombian mines were selected. The process is modeled under thermochemical equilibrium using Aspen Plus, and its performance is evaluated in function of output parameters that include SNG heating value, Wobbe index, coal conversion efficiency, cold gas efficiency, process efficiency, global efficiency, and SNG production rate, among others. In descending order, the coal-to-SNG process improves energetically with the use of coals with: higher volatile-matter to fixed-carbon ratio, lower ash content, higher C+H/O ratio, and higher coal heating value. The overall energy efficiency of the slurry-feed technology (S-FT) to produce SNG by gasification is 17% higher than the dry-feed technology (D-FT), possibly as a consequence of the higher CH4 concentration in the syngas (around 7 vol. %) when the coal is fed as aqueous slurry. As the simulated SNG meets the natural gas (NG) quality standards in Colombia, the substitute gaseous fuel could be directly transported through pipelines. Therefore, the coal-to-SNG process is a technically feasible and unconventional alternative for NG production.</p>


During the last decagon, there has been expanding international worry over the rise of anthropogenic CO2 discharge into the Earth’s atmosphere. The application of CO2 into a valuable asset is a major concern. The generation of syn gas and then usage of the syn gas into liquid fuel, seems to be one of the promising options in terms of industrial employment, as it offers several advantages: (a) reduction of CO2 , (b) conversion of gases, specially bio-gas, natural gas, LPG, and etc. and CO2 into syngas (c) producing syngas with H2 /CO2 ratio 1:1.9 to 1:2.1 which may further be used for the generation of valuable petrochemicals. The present research focusses on the gas to liquid conversion using the simulating software, Aspen Plus ®. The outcomes are then subjected to Design Expert ® for calculation of the optimal generation rate. The feedstocks used for the proposed present examination are bio-gas or pyro-gas, natural gas and LPG. The research scheme, gas to liquid conversion is carried out using three steps: (a) gas (feedstock) to syngas from the combination of dry reforming and steam reforming of methane, (b) Fischer Tropsch process to produce long chains of hydrocarbons and (c) usage of unconverted CO and H2 and other alcohol derivates in the CHP unit for the production of electricity. Amongst all the feedstocks natural gas production or generation is maximum followed by bio-gas or pyro-gas and then LPG. Due to non-available resources of natural gas and generation of GHG emission, for countries like India, bio-gas or pyro-gas can be used as a promising sustainable feedstock for reducing GHG emission and global warming. The outcomes of Aspen Plus ® of biogas or pyro-gas are then subjected to Design Expert ® for the prediction of the maximal production. It can be confirmed that with 6997.54 kg/h of biogas flowrate and 99.39% recycling of CO2 , the production of green gasoline, green diesel and green waxes are 565.24 (kg/h), 545.45(kg/h) and 642.68 (kg/h) respectively. The outcomes are in good agreement with the theories, thus proving the process to be a realistic one in nature. Therefore, bringing its viability for India in terms of reduction in CO2 emission and development of gas to liquid conversion process.


Sign in / Sign up

Export Citation Format

Share Document