A Thermal Chemical Reaction System for Natural Gas Hydrates Exploitation

The methodology of using CO2 to replace CH4 to recover the natural gas hydrates (NGHs) is supposed to avoid geological disasters. However, the reaction path of the CH4–CO2 replacement method is too complex to give satisfactory replacement efficiency. Therefore, this study proposed a thermochemical reaction system that used the heat and the nitrogen released by the thermochemical reactions to recover NGHs. The performance of the thermochemical reaction system (NaNO2 and NH4Cl) regarding heat generation and gas production under low temperature (4°C) conditions was evaluated, and the feasibility of exploiting NGHs with an optimized formula of the thermochemical reaction system was also evaluated in this study. First, the effects of three catalysts (HCl, H₃PO₄, and NH2SO3H) were investigated at the same reactant concentration and catalyst concentration. It was confirmed that HCl as a catalyst can obtain better heat generation and gas production. Second, the effect of HCl concentration on the reaction was investigated under the same reactant concentration. The results showed that the higher the HCl concentration, the faster is the reaction rate. When the concentration of HCl was greater than 14 wt%, side reactions would occur to produce toxic gas; hence, 14 wt% was the optimal catalyst concentration for the reaction of NaNO2 and NH4Cl at low temperatures. Third, the heat generation and gas production of the thermochemical reaction systems were evaluated at different reactant concentrations (1, 2, 3, 4, 5, and 6 mol/L) at 14 wt% HCl concentration. It was found that the best reactant concentration was 5 mol/L. Finally, the feasibility of exploiting NGHs with the optimal system was analyzed from the perspectives of thermal decomposition and nitrogen replacement. The thermochemical reaction system provided by this study is possible to be applied to explore NGHs’ offshore.

Determination of the lower boundaries of the natural gas hydrates stability zone in the subpermafrost horizons of the Yakut arch of the Vilyui syneclise, saturated with bicarbonate-sodium type waters

This paper considers the possibility of the underground gas storage facilities creating in a hydrate state on the north-western slope of the Yakut arch of the Vilyui syneclise. For this, the boundaries of the hydrate stability zone were determined for 6 promising areas of the considered geological structure. Equilibrium conditions of the natural gas hydrates formation in the model porous media containing bicarbonate-sodium type water (mineralization 20 g/l), characteristic for the subpermafrost horizons of the Yakut arch, have been studied by the method of differential thermal analysis. On the basis of the obtained results, the boundaries of the natural gas hydrates stability zone were determined. It was shown that the upper boundaries of the hydrate stability zone are located in the thickness of permafrost rocks. It was found that the lower boundaries of the natural gas hydrates stability zone in moist unsalted porous medium lie in the range from 930 to 1120 m. When the samples are saturated with mineralized water, the boundaries are located 80-360 m higher. The obtained experimental results allow us to conclude that in subpermafrost aquifers of the Yakut arch has favorable conditions for the formation of natural gas hydrates. Keywords: natural gas hydrates; aquifers; underground gas storage; hydrate stability zone; geothermal gradient; equilibrium conditions of the hydrate formation; bicarbonate-sodium type water.

Controlled Production of Natural Gas Hydrates in an Experimental Device with an Internal Circulation Circuit

For countries with limited access to conventional hydrocarbon gases, methane hydrates have emerged as a potential energy source. In view of the European Union’s requirements to reduce the energy intensity of technological processes and increase energy security, it appears promising to accumulate natural gas and biomethane in the form of hydrate structures and release them if necessary. Storing gas in this form in an energy-efficient manner creates interest in developing and innovating technologies in this area. Hydrates that form in gas pipelines are generated by a more or less random process and are an undesirable phenomenon in gas transportation. In our case, the process implemented in the proposed experimental device is a controlled process, which can generate hydrates in orders of magnitude shorter times compared to the classical methods of generating natural gas hydrates in autoclaves by saturating water only. The recirculation of gas-saturated water has been shown to be the most significant factor in reducing the energy consumption of natural gas hydrate generation. Not only is the energy intensity of generation reduced, but also its generation time. In this paper, a circuit diagram for an experimental device for natural gas hydrate generation is shown with complete description, principle of operation, and measurement methodology. The natural gas hydrate formation process is analyzed using a mathematical model that correlates well with the measured hydrate formation times. Hydrates may become a current challenge in the future and, once verified, may find applications in various fields of technology or industry.

Reverse Time Migration of Vertical Cable Seismic Data to Image Hydrate-Bearing Sediments With High Resolution

Marine vertical cable seismic (VCS) is a promising survey technique for submarine complex structure imaging and reservoir monitoring, which uses vertical arrays of hydrophones deployed near the seafloor to record seismic wavefields in a quiet environment. Recently, we developed a new type of distributed VCS system for exploration and development of natural gas hydrates preserved in shallow sediments under the seafloor. Using this system and air-gun sources, we accomplished a 3D VCS yield data acquisition for gas hydrates exploration in the Shenhu area, South China Sea. In view of the characteristics of VCS geometry, we implement reverse time migration (RTM) on a common receiver gather to obtain high-resolution images of marine sediments. Due to the unique acquisition method, it is asymmetrical for the reflection path between the sources and the receivers in the VCS survey. Therefore, we apply accurate velocity analysis to common scatter point (CSP) gathers generated from common receiver gathers instead of the conventional velocity analysis based on common depth point gathers. RTM with this reliable velocity model results in high-resolution images of submarine hydrate-bearing sediments in deep water conditions. The RTM imaging section clearly shows the bottom simulating reflector (BSR) and also the reflection characteristics of the hydrate-bearing sediments filled with consolidated hydrates. Moreover, its resolution is relative to that of acoustic logging curves from the nearby borehole, and this imaging section is well consistent with the synthetic seismogram trace generated by the logging data. All these results reveal that VCS is a great potential technology for exploration and production of marine natural gas hydrates.

Experimental Investigation On Hydrate Dissociation in Near-Wellbore Region Caused By Invasion of Drilling Fluid: Ultrasonic Measurement and Analysis

As we all know, development and utilization of clean energy is the only way for society to achieve sustainable development. Although natural gas hydrates is a new type of clean energy, uncontrollable hydrate dissociation and accompanying methane leakage in drilling operation threaten drilling safety and marine environment. However, dissociation range of natural gas hydrates around wellbore can't be reasonably and clearly determined in previous investigations, which may lead to the inaccurate estimation of borehole collapse and methane leakage. Then, the marine environment will be greatly damaged or affected. The purpose of the present work is to experimentally explore the dissociation characteristics of natural gas hydrates around wellbore in drilling operation, and analyze the influence law and mechanism of various factors on hydrate dissociation. It is expected to provide reference for exploring effective engineering measures to avoid the uncontrolled hydrate dissociation, borehole collapse and accompanying methane leakage. The experimental results demonstrate that acoustic velocity of hydrate-bearing sediment can be accurately expressed as quadratic polynomial of hydrate saturation, which is the theoretical basis for determination of hydrate saturation in subsequent experiments. Owing to the fact that hydrate dissociation is an endothermic reaction, hydrate dissociation gradually slows down in experiment. Throughout the experiment, the maximum dissociation rate at the beginning of the experiment is 8.69 times that at the end of the experiment. In addition, sensitivity analysis found that the increase of stabilizer concentration in drilling fluid can inhibit hydrate dissociation more than the increase in hydrate saturation. Hydrate dissociation was completely inhibited when the concentration of soybean lecithin exceeds 0.60wt%, but hydrate dissociation definitely occurs in the near-wellbore region no matter what hydrate saturation is. In this way, based on the requirements of drilling safety and environment protection, hydrate dissociation and accompanying methane leakage can be controlled by designing and adjusting the stabilizer concentration in drilling fluid.