scholarly journals Functionalization of Cellulose Fibres with Oxygen Plasma and ZnO Nanoparticles for Achieving UV Protective Properties

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Katja Jazbec ◽  
Martin Šala ◽  
Miran Mozetič ◽  
Alenka Vesel ◽  
Marija Gorjanc

Low-pressure oxygen plasma created by an electrodeless radiofrequency (RF) discharge was applied to modify the properties of cellulosic fibrous polymer (cotton) in order to improve adsorption properties towards zinc oxide (ZnO) nanoparticles and to achieve excellent ultraviolet (UV) protective properties of cotton fabric. The chemical and physical surface modifications of plasma-treated cotton fabric were examined by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The mechanical properties of plasma-treated samples were evaluated, measuring strength and elongation of the fabrics. The quantity of zinc on the ZnO-functionalized cotton samples was determined using inductively coupled plasma mass spectrometry (ICP-MS) and the effectiveness of plasma treatment for UV protective properties of cotton fabrics was evaluated using UV-VIS spectrometry, measuring the UV protection factor (UPF). The results indicated that longer plasma treatment times cause higher concentration of oxygen functional groups on the surface of fibres and higher surface roughness of fibres. These two conditions are crucial in increasing the content of ZnO nanoparticles on the fibres, providing excellent UV protective properties of treated cotton, with UPF factor up to 65.93.

Cellulose ◽  
2014 ◽  
Vol 21 (4) ◽  
pp. 3007-3021 ◽  
Author(s):  
Marija Gorjanc ◽  
Katja Jazbec ◽  
Martin Šala ◽  
Rok Zaplotnik ◽  
Alenka Vesel ◽  
...  

Author(s):  
Cloé L. Esposito ◽  
Plamen Kirilov

With the increase in occupation-specific risks of lip cancer associated with solar radiation, there is a need for developing photoprotective lipsticks to protect skin against harmful effects of UV radiation. Considering the unique chemical and physical properties of low-molecular-weight organogelators (LMOGs), the present study intended to assess the UV protective properties of LMOGs-based lipstick formulations. In this study, dibenzylidene-D-sorbitol (DBS) and 12-hydroxystearic acid (12-HSA) were used to formulate lipsticks : L1 (1% DBS), L2 (10% 12-HSA), L3 (1.5% DBS) and L4 (control, no LMOGs). The lipstick formulations were tested for in vitro sun protection factors (SPF), UVA protection factor (UVA-PF), thermal, mechanical and texture analyses. Lipsticks with LMOGs exhibited higher UVA-PF and SPF, and more particularly 12-HSA-based lipstick. Results showed also the viscoelastic and heat-resistant properties of LMOGs and their effect of increasing pay-off values. In general, texture analysis indicating that 12-HSA-based lipstick was significantly harder to bend compared to control, while other formulations became softer and easier to bend throughout the stability study. Finally, sensorial and instrumental analyses permitted to classify lipsticks into two groups. This work suggests the potential use of LMOGs as a structuring agent for lipsticks paving the way towards more photoprotective and sustainable-derived alternatives.


2013 ◽  
Vol 796 ◽  
pp. 353-359
Author(s):  
De Suo Zhang ◽  
Yan Fen Liao ◽  
Hong Lin ◽  
Yu Yue Chen

A novel ZnO nanoparticles aqueous solution was prepared through a one-step reaction between a modified hyperbranched polymer-PNP and zinc nitrate. During the reaction process, PNP not only acted as the reagent to produce ZnO nanoparticles, but also controlled the size of the synthesized ZnO nanoparticles and stabilize them after reaction. The size of ZnO nanoparticles were about 6 nm with narrow size distribution. Then the ZnO nanoparticles were utilized for the functional finishing of cotton fabrics by in situ generation and deposition method. Scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD) measurements confirmed the ZnO nanoparticles coated on the cotton fibers. The treated cotton fabrics exhibited excellent UV protective properties and antibacterial activities. When the ZnO content in cotton fabric was 2.23 %, the UPF value of treated cotton fabric reached 114.4 and the bacterial reduction rates againstStaphylococcus aureus(S. aureus) andEscherichia coli(E. coli) both exceeded 98 %.


2014 ◽  
Vol 15 (10) ◽  
pp. 2095-2104 ◽  
Author(s):  
Marija Gorjanc ◽  
Katja Jazbec ◽  
Miran Mozetič ◽  
Mateja Kert

2021 ◽  
pp. 004051752110018
Author(s):  
Mengmeng Li ◽  
Amjad Farooq ◽  
Shuai Jiang ◽  
Meiling Zhang ◽  
Hassan Mussana ◽  
...  

A simple impregnation method was employed to obtain functional cotton fabric based on a zinc oxide (ZnO) and cellulose nanocomposite. The cellulose nanofibril suspension was utilized to reduce the agglomeration of ZnO nanoparticles (ZnO NPs) and bind them to the surface of the fiber. Scanning electron microscopy and inductively coupled plasma mass spectrometry were used to confirm the presence of ZnO NPs on the surface of the fiber. The treated cotton fabrics exhibited high ultraviolet protection factor values, which were still higher than 50 even after 30 standard washing cycles. Furthermore, the treated samples showed a modest antibacterial effect due to the presence of ZnO NPs. Meanwhile, the treated cotton fabrics showed a decrease (less than 30%) in air permeability.


2020 ◽  
Vol 63 (2) ◽  
pp. 525-536
Author(s):  
Hekmat I. Ibrahim ◽  
Reham Farouk ◽  
Elham A. El-karadly ◽  
Ahmed Elwahy ◽  
Abdalla. A. Mousa

Author(s):  
Wei Mao ◽  
shihao Xu ◽  
Haiyong Wang ◽  
Cui Yang ◽  
ShengLei Zhao ◽  
...  

Abstract The treatment effect of the oxygen plasma on the performance of recessed AlGaN/GaN Schottky barrier diodes has been investigated. After the oxygen plasma treatment, the turn-on voltage and reverse leakage current are slightly changed, while the current collapse could be effectively mitigated. The X-ray photoelectron spectroscopy results suggest that a thin surface oxide layer is formed by the oxygen plasma treatment, which is responsible for the reduced current collapse. In addition, the device with oxygen plasma treatment has a relatively more inhomogeneous barrier height.


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