Investigation on the Synthesis and Photocatalytic Property of Uranyl Complexes of the β-Diketonates Biscatecholamide Ligand

A series of uranyl complexes have been synthesized by reacting hexadentate ligands CH2[COO (CH2)nCAM; n=2, 3, 4]2 [CAM = 2,3-Ph(OH)2CONH] containing the catecholamide (CAM) group and β-diketonates framework with uranyl nitrate. They were characterized by FTIR, UV-vis, 1H NMR, XPS, TGA, and elemental analysis. The analysis revealed that oxygen atom of β-diketonate did not bind to uranyl ion in complexes 1–3. The photocatalytic degradation properties of the target complexes for degradation of rhodamine B (RhB) were investigated. The result indicated that approximately 74%, 71%, and 67% RhB were degraded in the presence of complexes 1–3 after about 210 min, respectively. Consequently, complexes 1–3 have excellent photocatalytic degradation property.

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Synthesis, Structure Characterization and Photocatalytic Property of a New 3-D Polyoxovanadate-Based Organic-Inorganic Hybrid Compound

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.997.260 ◽

2014 ◽

Vol 997 ◽

pp. 260-263 ◽

Cited By ~ 1

Author(s):

Ya Bing Liu ◽

Peng Yu

Keyword(s):

Transition Metal ◽

Elemental Analysis ◽

Rhodamine B ◽

Photocatalytic Property ◽

Building Blocks ◽

Structure Characterization ◽

X Ray Diffraction ◽

Hybrid Compound ◽

Inorganic Hybrid ◽

X Ray

A new polyoxovanadates-based organic-inorganic hybrid compound, [Cu(en)2]2[VV6VIV4O25] (1) has been hydrothermally synthesized and structurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 consists of [Cu(en)2]2+transition metal coordination fragment and the [VV6VIV4O25]4-building blocks, which are linked together via covalently-bonding interactions to form a new 3-D networks. The degradation of rhodamine B (RhB) under UV-vis irradiation with 1 as the heterogeneous photocatalyst has been investigated, showing a good photocatalytic property of 1 for RhB degradation.

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Preparation of TiO2-based photocatalysts and their photocatalytic degradation properties for methylene blue, rhodamine B and methyl orange

10.5004/dwt.2017.21109 ◽

2017 ◽

Vol 81 ◽

pp. 282-290 ◽

Cited By ~ 7

Author(s):

Jin-Gang Yu ◽

Jiao Zou ◽

Liang-Liang Liu ◽

Xin-Yu Jiang ◽

Fei-Peng Jiao ◽

...

Keyword(s):

Methylene Blue ◽

Methyl Orange ◽

Photocatalytic Degradation ◽

Rhodamine B ◽

Degradation Properties

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Synthesis and Antituberculotic Activity of Some Substituted 3-Arylamino-5-cyano-2-pyrazinecarboxamides

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19951236 ◽

1995 ◽

Vol 60 (7) ◽

pp. 1236-1241 ◽

Cited By ~ 7

Author(s):

Martin Doležal ◽

Jiří Hartl ◽

Antonín Lyčka ◽

Vladimír Buchta ◽

Želmíra Odlerová

Keyword(s):

Nucleophilic Substitution ◽

Elemental Analysis ◽

Nmr Spectra ◽

Substituted Anilines ◽

H Nmr

Nucleophilic substitution of 3-chloro-5-cyano-2-pyrazinecarboxamide by substituted anilines afforded substituted 3-arylamino-5-cyano-2-pyrazinecarboxamides I-X. The structures of compounds were confirmed by elemental analysis, UV, IR and 1H NMR spectra. The assessment of in vitro antimycotic and antimycobacterial activities of the compounds was carried out. The highest antituberculotic activity against M. tuberculosis in this series was shown by 3-anilino- 5-cyano-2-pyrazinecarboxamide (I), whose efficacy was the same as that of pyrazinecarboxamide.

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