scholarly journals Effect of the Third Element Ni on the Solidification Microstructure of Undercooled Cu-40 wt.% Pb Monotectic Alloy Melt

2019 ◽  
Vol 2019 ◽  
pp. 1-7
Author(s):  
Xi Hao ◽  
Yugui Li ◽  
Ying Hu ◽  
Guihong Geng

In this paper, the evolution of solidification microstructure of Cu-40 wt.% Pb monotectic alloy of the third element Ni pair under deep undercooling conditions was studied. By comparing the phenomena of liquid phase separation during deep undercooling and rapid solidification of Cu-40 wt.% Pb monotectic alloy, the melt of the alloy increases with the undercooling, and the solidification structure appears uneven or even stratified. With the addition of the third element Ni, the liquid phase separation can be effectively inhibited by the change of interfacial energy. The solidified structure undergoes the transformation from coarse dendrite to the first kind of granular and refined dendrite in a wide undercooling range. When the undercooling reaches 143 K, the structure begins to show an inhomogeneous trend.

Author(s):  
Dandan Zhao ◽  
Jianrong Gao

Undercooling of Cu-based alloys often induces metastable liquid phase separation followed by rapid solidification of separated liquids. The rapid solidification can help freeze in the morphology of a higher-melting liquid and eases difficulties in studies of liquid phase separation kinetics. In the present work, the influence of static magnetic fields on liquid phase separation in bulk Cu 84 Co 16 composition was investigated. Inductively melted samples were glass-fluxed, undercooled and solidified under uniform and non-uniform magnetic fields generated by a superconducting magnet. Solidification microstructure of the phase-separated samples was examined using an optical microscope. The imposition of the magnetic fields, both uniform and non-uniform, altered the morphology, segregation pattern and size distribution of Co-rich droplets due to liquid phase separation. The imposition of the non-uniform magnetic fields with positive and negative gradients brought about segregation of the Co-rich droplets at the top and the bottom side of the samples, respectively. Such influence of the static magnetic fields is interpreted by assuming intensification of convective flow and Kelvin force-controlled migration of the Co-rich droplets. This article is part of the theme issue ‘Heterogeneous materials: metastable and non-ergodic internal structures’.


2012 ◽  
Vol 28 (7) ◽  
pp. 622-625 ◽  
Author(s):  
Ning Liu ◽  
Feng Liu ◽  
Zheng Chen ◽  
Gencang Yang ◽  
Changlin Yang ◽  
...  

2016 ◽  
Vol 72 ◽  
pp. 44-52 ◽  
Author(s):  
N. Liu ◽  
P.H. Wu ◽  
P.J. Zhou ◽  
Z. Peng ◽  
X.J. Wang ◽  
...  

2018 ◽  
Vol 2018 ◽  
pp. 1-6 ◽  
Author(s):  
Xiaosi Sun ◽  
Weixin Hao ◽  
Guihong Geng ◽  
Teng Ma ◽  
Yongtang Li

The solidification microstructure evolution of undercooled Cu-15 wt.% Fe alloy melt was studied in this study by the combined method of glass fluxing and overheating. The liquidus and peritectic reaction temperatures of Cu-15 wt.% Fe were experimentally obtained, and the obtained results were consistent with the previous studies. Based on the experimental results and related theories, the solidification process and microstructure evolution of undercooled Cu-15 wt.% Fe alloy melt were illustrated. The conclusions provide the basis to the further study on the liquid-phase separation and application of copper-iron alloy.


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