Factors Affecting the Self-Healing Efficiency of Cracked Concrete Structures

In the study, a novel microcapsule technology based self-healing system for concrete structures has been developed. Through situ-polymerization reaction, the microcapsule is formed by urea formaldehyde resin to pack the epoxy material, which is applied to cementitious composite to achieve self-healing effect. The experimental results revealed that the self-healing efficiency of the composite can be accessed from the recovery of the permeability and strength for the cracked cementitious specimens as the healing agent in the microcapsule acting on the cracks directly. Scanning electronic microscope (SEM/EDX) results show that the epoxy resin is released along with the cracking of the cementitious composite and prevent from cracks continued growth. Further studies show that the self-healing efficiency is affected by the pre-loading of composite, particle size of microcapsule, aging duration of healing agent and so on.

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Effect of Using Magnesium Acetate on the Self-Healing Efficiency of Hydrogel-Encapsulated Bacteria in Concrete

10.1061/9780784483787.018 ◽

2021 ◽

Author(s):

Ricardo Hungria ◽

Momen Mousa ◽

Marwa Hassan ◽

Omar Omar ◽

Andrea Gavilanes ◽

...

Keyword(s):

The Self ◽

Magnesium Acetate ◽

Self Healing ◽

Healing Efficiency ◽

Encapsulated Bacteria

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Design of self-healing catalysts for aircraft application

International Journal of Structural Integrity ◽

10.1108/ijsi-12-2017-0077 ◽

2018 ◽

Vol 9 (6) ◽

pp. 723-736 ◽

Cited By ~ 1

Author(s):

Elisa Calabrese ◽

Pasquale Longo ◽

Carlo Naddeo ◽

Annaluisa Mariconda ◽

Luigi Vertuccio ◽

...

Keyword(s):

Ruthenium Catalysts ◽

The Self ◽

Self Healing ◽

Catalytic Systems ◽

Content Type ◽

Aerospace Applications ◽

Healing Efficiency ◽

Relevant Role ◽

Aircraft Application

PurposeThe purpose of this paper is to highlight the relevant role of the stereochemistry of two Ruthenium catalysts on the self-healing efficiency of aeronautical resins.Design/methodology/approachHere, a very detailed evaluation on the stereochemistry of two new ruthenium catalysts evidences the crucial role of the spatial orientation of phenyl groups in the N-heterocyclic carbene ligands in determining the temperature range within the curing cycles is feasible without deactivating the self-healing mechanisms (ring-opening metathesis polymerization reactions) inside the thermosetting resin. The exceptional activity and thermal stability of the HG2MesPhSyncatalyst, with the syn orientation of phenyl groups, highlight the relevant potentiality and the future perspectives of this complex for the activation of the self-healing function in aeronautical resins.FindingsThe HG2MesPhSyncomplex, with the syn orientation of the phenyl groups, is able to activate metathesis reactions within the highly reactive environment of the epoxy thermosetting resins, cured up to 180°C, while the other stereoisomer, with the anti-orientation of the phenyl groups, does not preserve its catalytic activity in these conditions.Originality/valueIn this paper, a comparison between the self-healing functionality of two catalytic systems has been performed, using metathesis tests and FTIR spectroscopy. In the field of the design of catalytic systems for self-healing structural materials, a very relevant result has been found: a slight difference in the molecular stereochemistry plays a key role in the development of self-healing materials for aeronautical and aerospace applications.

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Experimental Investigation on the Self-Healing Efficiency of Araldite 2011 Adhesive Reinforced with Thermoplastic Microparticles

Adhesives - Applications and Properties ◽

10.5772/65167 ◽

2016 ◽

Cited By ~ 1

Author(s):

Halil Özer ◽

Engin Erbayrak

Keyword(s):

Experimental Investigation ◽

The Self ◽

Self Healing ◽

Healing Efficiency

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Contribution to study of the self-healing effect activated by crystalline catalysts in concrete structures when subjected to continuous exposure to water

Concrete Repair, Rehabilitation and Retrofitting III ◽

10.1201/b12750-237 ◽

2012 ◽

pp. 530-531

Keyword(s):

Concrete Structures ◽

The Self ◽

Continuous Exposure ◽

Self Healing ◽

Healing Effect

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Healing Performance of a Self-Healing Protective Coating According to Damage Width

Coatings ◽

10.3390/coatings10060543 ◽

2020 ◽

Vol 10 (6) ◽

pp. 543

Author(s):

Dong-Min Kim ◽

Junseo Lee ◽

Ju-Young Choi ◽

Seung-Won Jin ◽

Kyeong-Nam Nam ◽

...

Keyword(s):

Protective Coating ◽

Coating Thickness ◽

Chloride Ion ◽

The Self ◽

Self Healing ◽

Chloride Ion Penetration ◽

Healing Efficiency ◽

Sem Study ◽

Capsule Size ◽

Ion Penetration

Although self-healing protective coatings have been widely studied, systematic research on healing performance of the coating according to damage width has been rare. In addition, there has been rare reports of self-healing of the protective coating having damage width wider than 100 µm. In this study, self-healing performance of a microcapsule type self-healing protective coating on cement mortar was studied for the coating with damage width of 100–300 µm. The effect of capsule-loading (20 wt%, 30 wt% and 40 wt%), capsule size (65-, 102- and 135-µm-mean diameter) and coating thickness (50-, 80- and 100-µm-thick undercoating) on healing efficiency was investigated by water sorptivity test. Accelerated carbonation test, chloride ion penetration test and scanning electron microscope (SEM) study were conducted for the self-healing coating with a 300-µm-wide damage. Healing efficiency of the self-healing coating decreased with increasing damage width. As capsule-loading, capsule size or coating thickness increased, healing efficiency of the self-healing coating increased. Healing efficiency of 76% or higher was achieved using the self-healing coating with a 300-µm-wide scratch. The self-healing coating with a 200-µm-wide crack showed healing efficiency of 70% or higher. The self-healing coating having a 300-µm-wide scratch showed effective protection of the substrate mortar from carbonation and chloride ion penetration, which was supported by SEM study.

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Self-Healable Supramolecular Vanadium Pentoxide Reinforced Polydimethylsiloxane-Graft-Polyurethane Composites

Polymers ◽

10.3390/polym11010041 ◽

2018 ◽

Vol 11 (1) ◽

pp. 41 ◽

Cited By ~ 4

Author(s):

Ali Berkem ◽

Ahmet Capoglu ◽

Turgut Nugay ◽

Erol Sancaktar ◽

Ilke Anac

Keyword(s):

Tensile Strength ◽

Vanadium Pentoxide ◽

Coupling Reaction ◽

Optical Microscope ◽

Mechanical Tests ◽

Healing Time ◽

The Self ◽

Supramolecular Polymer ◽

Self Healing ◽

Healing Efficiency

The self-healing ability can be imparted to the polymers by different mechanisms. In this study, self-healing polydimethylsiloxane-graft-polyurethane (PDMS-g-PUR)/Vanadium pentoxide (V2O5) nanofiber supramolecular polymer composites based on a reversible hydrogen bonding mechanism are prepared. V2O5 nanofibers are synthesized via colloidal route and characterized by XRD, SEM, EDX, and TEM techniques. In order to prepare PDMS-g-PUR, linear aliphatic PUR having one –COOH functional group (PUR-COOH) is synthesized and grafted onto aminopropyl functionalized PDMS by EDC/HCl coupling reaction. PUR-COOH and PDMS-g-PUR are characterized by 1H NMR, FTIR. PDMS-g-PUR/V2O5 nanofiber composites are prepared and characterized by DSC/TGA, FTIR, and tensile tests. The self-healing ability of PDMS-graft-PUR and composites are determined by mechanical tests and optical microscope. Tensile strength data obtained from mechanical tests show that healing efficiencies of PDMS-g-PUR increase with healing time and reach 85.4 ± 1.2 % after waiting 120 min at 50 °C. The addition of V2O5 nanofibers enhances the mechanical properties and healing efficiency of the PDMS-g-PUR. An increase of healing efficiency and max tensile strength from 85.4 ± 1.2% to 95.3 ± 0.4% and 113.08 ± 5.24 kPa to 1443.40 ± 8.96 kPa is observed after the addition of 10 wt % V2O5 nanofiber into the polymer.

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Self-Healing of Concrete Cracks by Ceramsite-Loaded Microorganisms

Advances in Materials Science and Engineering ◽

10.1155/2018/5153041 ◽

2018 ◽

Vol 2018 ◽

pp. 1-8 ◽

Cited By ~ 11

Author(s):

Jing Xu ◽

Xianzhi Wang ◽

Junqing Zuo ◽

Xiaoyan Liu

Keyword(s):

Heat Treatment ◽

Compressive Strength ◽

Heating Temperature ◽

Concrete Strength ◽

The Self ◽

Self Healing ◽

Healing Efficiency ◽

Maximum Crack ◽

Harsh Conditions ◽

Urea Decomposition

Protective carrier is essential for the self-healing of concrete cracks by microbially induced CaCO3 precipitation, owing to the harsh conditions in concrete. In this paper, porous ceramsite particles are used as microbial carrier. Heat treatment and NaOH soaking are first employed to improve the loading content of the ceramsite. The viability of bacterial spores is assessed by urea decomposition measurements. Then, the self-healing efficiency of concrete cracks by spores is evaluated by a series of tests including compressive strength regain, water uptake, and visual inspection of cracks. Results indicate that heat treatment can improve the loading content of ceramsite while not leading to a reduction of concrete strength by the ceramsite addition. The optimal heating temperature is 750°C. Ceramsite particles act as a shelter and protect spores from high-pH environment in concrete. When nutrients and spores are incorporated in ceramsite particles at the same time, nutrients are well accessible to the cells. The regain ratio of the compressive strength increases over 20%, and the water absorption ratio decreases about 30% compared with the control. The healing ratio of cracks reaches 86%, and the maximum crack width healed is near 0.3 mm.

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Influence of the Active Particles on the Self-Healing Efficiency in Glassy Matrix

Advanced Engineering Materials ◽

10.1002/adem.201100002 ◽

2011 ◽

Vol 13 (5) ◽

pp. 426-435 ◽

Cited By ~ 11

Author(s):

Daniel Coillot ◽

François O. Méar ◽

Renaud Podor ◽

Lionel Montagne

Keyword(s):

The Self ◽

Glassy Matrix ◽

Self Healing ◽

Active Particles ◽

Healing Efficiency

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The Self-Healing Performance of Carbon-Based Nanomaterials Modified Asphalt Binders Based on Molecular Dynamics Simulations

Frontiers in Materials ◽

10.3389/fmats.2020.599551 ◽

2021 ◽

Vol 7 ◽

Author(s):

Yan Gong ◽

Jian Xu ◽

Er-hu Yan ◽

Jun-hua Cai

Keyword(s):

Healing Process ◽

Asphalt Binder ◽

Mean Square Displacement ◽

The Self ◽

Asphalt Binders ◽

Self Healing ◽

Modified Asphalt ◽

Healing Efficiency ◽

Carbon Based Nanomaterials ◽

Carbon Based

In this study, the molecular dynamics simulation was used to explore the effects of carbon-based nanomaterials as binder modifiers on self-healing capability of asphalt binder and to investigate the microscopic self-healing process of modified asphalt binders under different temperature. An asphalt average molecular structure model of PEN70 asphalt binder was constructed firstly. Further, three kinds of carbon-based nanomaterials were added at three different percentages ranging from 0.5 to 1.5% to the base binder to study their effects on the self-healing capability, including two carbon nanotubes (CNT1 and CNT2) and graphene nanoflakes. Combining with the three-dimensional (3D) microcrack model to simulate the asphalt self-healing process, the density analysis, relative concentration analysis along OZ direction, and mean square displacement analysis were performed to investigate the temperature sensitive self-healing characters. Results showed that the additions of CNTs were effective in enhancing the self-healing efficiency of the plain asphalt binder. By adding 0.5% CNT1 and 0.5% CNT2, about 652% and 230% of the mean square displacement of plain asphalt binder were enhanced at the optimal temperatures. However, the use of graphene nanoflakes as an asphalt modifier did not provide any noticeable changes on the self-healing efficiency. It can be found that the self-healing capability of the asphalt was closely related to the temperature. For base asphalt, the self-healing effect became especially high at the phase transition temperature range, while, for the modified asphalt, the enhancement of the self-healing capability at the low phase transition temperature (15°C) became negligible. In general, the optimal healing temperature range of the CNTs modified asphalt binders is determined as 45–55°C and the optimal dosage of the CNTs is about 0.5% over the total weight of the asphalt binder. Considering the effect of carbon-based nanomaterials on the self-healing properties, the recommended carbon-based nanomaterials modifier is CNT1 with the aspect ratio of 1.81.

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