An In-Situ Transmission Fourier Transform Infrared Study on the Interaction Mechanism of Plasma with Nano-Catalyst for CO2 Methanation

2021 ◽  
Vol 21 (7) ◽  
pp. 3858-3862
Author(s):  
Kilsu Park ◽  
Gisung Bae ◽  
Taegyu Kim
Keyword(s):  
Fourier Transform ◽  
Sol Gel ◽  
Interaction Mechanism ◽  
Ftir Analysis ◽  
Co2 Methanation ◽  
Infrared Study ◽  
Gel Method ◽  
Peak Intensity ◽  
Nano Catalyst

The effects of discharge conditions and catalysts on CO2 methanation under the plasma were investigated via In-Situ transmission FTIR and OES analysis. The bare Al2O3, Ni/Al2O3 and Ru/Al2O3 catalysts were coated on the ZnSe window using the modified sol–gel method for In-Situ transmission FTIR analysis. It was confirmed from the OES analysis that the intensity of excited hydrogen increased in all catalysts as the discharge frequency and voltage increased, and the increment of H+ peak intensity was the largest in the Ru/Al2O3 catalyst. In addition, it was found from the In-Situ transmission FTIR analysis that the O-H band was all disappeared as the frequency and voltage increased. In conclusion, the increased H+ with the decomposition of O–H led to the increase in the CH4 conversion, resulting in the highest CH4 conversion in the Ru/Al2O3 catalyst.

scholarly journals Preparation and stress-strain behavior of in-situ epoxidized natural rubber/SiO2 hybrid through a sol-gel method

2018 ◽  
Vol 12 (2) ◽  
pp. 180-185 ◽  
Author(s):  
S. M. Li ◽  
T. W. Xu ◽  
Z. X. Jia ◽  
B. C. Zhong ◽  
Y. F. Luo ◽  
...  
Keyword(s):  
Natural Rubber ◽  
Sol Gel ◽  
Epoxidized Natural Rubber ◽  
Stress Strain ◽  
Gel Method ◽  
Sol Gel Method ◽  
Strain Behavior

Preparation of amphiphilic nano-sized NaA/glass films and powders using layer-by-layer in-situ sol–gel method

2015 ◽  
Vol 213 ◽  
pp. 1-7 ◽  
Author(s):  
Fei Tong ◽  
Jie Gong ◽  
Ming Li ◽  
Changfeng Zeng ◽  
Lixiong Zhang
Keyword(s):  
Sol Gel ◽  
Layer By Layer ◽  
Gel Method ◽  
Sol Gel Method ◽  
Glass Films

In Situ Synthesis of SiO2 Nanoparticles by Sol-Gel Method on Cotton Fabrics and Investigation of their Physical and Chemical Properties

2021 ◽  
Vol 891 ◽  
pp. 37-42
Author(s):  
Sheila Shahidi ◽  
Hakimeh Mohammadbagherloo ◽  
Seyedmohammad Elahi ◽  
Sanaz Dalalsharifi ◽  
Rattanaphol Mongkholrattanasit
Keyword(s):  
Flame Retardant ◽  
Water Drop ◽  
Sol Gel ◽  
Cotton Fabrics ◽  
In Situ Synthesis ◽  
Order Structure ◽  
Gel Method ◽  
Sol Gel Method ◽  
Flame Retardant Properties

In this paper, the sol-gel method was used for in-situ synthesis of SiO2 nanoparticles (NPs) on cotton fabrics with tetraethyl orthosilicate (TEOS) in the presence of acid and alkaline indicators. The samples were characterized using by (X-ray diffraction) XRD, (scanning electron Microscopy) SEM, (Inductively coupled plasma) ICP, water drop test and also the flame retardant properties were studied by char yield. The SEM images showed that the nanoparticles are spherical in shape and the acidity or alkalinity of the medium has an effect on the formation of particles. The XRD patterns showed the typical diffraction of amorphous SiO2 (Si-O short-order structure), also ICP analysis showed that by washing the fabrics, the nanoparticles are still present on the fabric, and this indicated the stability of the washing of the fabrics impregnated with the nanoparticles. By in-situ synthesis of SiO2 nanoparticles, the flame retardant properties have been improved significantly and the amount of residual char was increased and samples were observed to be hydrophilic.

UV-curable fluorine-containing hybrid coatings via thiol-ene “click” reaction and an in situ sol–gel method

2012 ◽  
Vol 70 (3) ◽  
pp. 1037-1048 ◽  
Author(s):  
Emrah Çakmakçı ◽  
Yusuf Mülazim ◽  
Memet Vezir Kahraman
Keyword(s):  
Click Reaction ◽  
Sol Gel ◽  
Hybrid Coatings ◽  
Uv Curable ◽  
Gel Method ◽  
Sol Gel Method

Preparation and the PL Properties of Er3+ - Ce3+ Co-Doped TiO2 Powders

2014 ◽  
Vol 528 ◽  
pp. 30-33
Author(s):  
Ling Yun Bai ◽  
Long Fa Jiang ◽  
Jun Huai Xiang
Keyword(s):  
Hybrid Materials ◽  
Sol Gel ◽  
Gel Method ◽  
Sol Gel Method ◽  
Hybrid Matrix ◽  
Peak Intensity ◽  
Dispersion Effects ◽  
Co Doped

The 0.5-3.0 mol% Er3+-Ce3+ co-doped TiO2 powders have been prepared by sintering the hybrid materials Er0.5Ce0.5(AA)3phen-doped TiO2/PMMA, which were prepared by sol-gel method, using the modified titanium (IV) n-butoxide [Ti(O-Bu)4-x(AAPhen)x] as precursors which were given by the chelate reaction between Ti(O-Bu)4, AA and Phen at 70°C. The hybrid matrix TiO2/PMMA improved the dispersion of Er3+, which caused an enhancement in the photoluminescence (PL) peak intensity at 1.53 mm of the 1 mol% Er (AA)3phen-doped TiO2/PMMA powders sintered at 700 °C of about 23 times higher than that only had TiO2 as its matrix. When co-doped with Ce3+, the above ratio of the PL peak intensity was raised to 75 times, which illustrated the obvious sensitization and dispersion effects of Ce3+ on Er3+.

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