AC Conductivity and Dielectric Properties of BiScO3–PbTiO3 Piezoelectric Ceramics

2021 ◽  
Vol 13 (9) ◽  
pp. 1807-1811
Author(s):  
Jae-Hoon Ji ◽  
Yoo-Young Oh ◽  
Bo Su Kim ◽  
Wook-Hee Han ◽  
Jung-Hyuk Koh

Bi-based BiMeO3 (where Me is a transition metal) has been extensively studied owing to its outstanding ferroelectric properties. The dielectric and electrical properties of piezoelectric ceramics can be enhanced by the addition of Bi-based materials such as BiAlO3, BiScO3 , and Bi(Mg, Ti)O3. Among them, BiScO3–PbTiO3 ceramics have shown excellent piezoelectric properties and temperature stability near the morphotropic phase boundary (MPB) region. Meanwhile, it is important to study the electrical properties of piezoelectric materials such as dielectric permittivity, conductivity of ferroelectric compounds, since dielectric and conductivities are related to pyroelectricity and piezoelectricity. In this study, the AC conductivity and dielectric properties of BiScO3–PbTiO3 ceramics were investigated with a wide range of frequencies and temperatures. Especially,the effect of PbTiO3 content on dielectric behavior of the BiScO3–PbTiO3 system was intensively studied by impedance spectroscopy.

RSC Advances ◽  
2016 ◽  
Vol 6 (62) ◽  
pp. 57210-57216 ◽  
Author(s):  
Jie Xing ◽  
Zhi Tan ◽  
Jing Yuan ◽  
Laiming Jiang ◽  
Qiang Chen ◽  
...  

(0.965 − x)(K0.48Na0.52)NbO3–xBiGaO3–0.035(Bi0.5Na0.5)ZrO3 [(0.965 − x)KNN–xBG–BNZ] lead-free piezoelectric ceramics were prepared using normal sintering for improving the piezoelectric properties and temperature stability of KNN-based ceramics.


2008 ◽  
Vol 41 (24) ◽  
pp. 245401 ◽  
Author(s):  
Yuanyu Wang ◽  
Jiagang Wu ◽  
Dingquan Xiao ◽  
Bin Zhang ◽  
Wenjuan Wu ◽  
...  

2011 ◽  
Vol 492 ◽  
pp. 194-197 ◽  
Author(s):  
Yue Fang Wang ◽  
Xiu Jie Yi ◽  
Wei Pan ◽  
Guo Zhong Zang ◽  
Juan Du

Lead-free (1-x-y)Na1/2Bi1/2TiO3-xBaTiO3-yBiFeO3 ceramics were synthesized by ordinary sintering technique. The compositional dependence of phase structure and electrical properties of the ceramics was systematically investigated. All samples possessed pure perovskite structure. The dielectric and piezoelectric properties of ceramics were investigated with the amount of different BiFeO3 substitutions. The addition of BiFeO3 can not only decrease Ec and Pr but also lead to a significant degradation of the dielectric loss tanδ.


2014 ◽  
Vol 87 ◽  
pp. 12-17
Author(s):  
Fares Kahoul ◽  
Louanes Hamzioui ◽  
Ahmed Boutarfaia

The phase structure, microstructure and electrical properties of (1-x)Pb (ZryTi1-y)O3-xSm(Fe3+0.5,Nb5+0.5)O3(PZT–SFN) (with x = 2 %, 41%≤ y ≤57 %) piezoelectric ceramics were prepared by the conventional solid state method, and effects of SFN and the Zr/Ti ratio content on the piezoelectric properties of PZT ceramics were mainly investigated. A stable solid solution has been formed between PZT and SFN, and a morphotropic phase boundary of PZT–SFN ceramics is identified in the range of 51% ≤ y ≤55 %. The Curie temperature of PZT–SFN ceramics decreases with increasing at Zr/Ti ratio content. A higher εrvalue and a lower tanδ value are demonstrated for the PZT–SFN ceramics with y = 53 %. The PZT–SFN ceramics with y = 53 % has an enhanced electrical behavior of kp~ 61.2 %, Qm~ 104, εr~ 566, tanδ ~ 2.02 % and TC~ 370OC. As a result, PZT–SFN ceramics are promising candidate materials for the field of lead piezoelectric materials and piezoelectric device.


2011 ◽  
Vol 687 ◽  
pp. 228-232
Author(s):  
Yong Jie Zhao ◽  
Yu Zhen Zhao ◽  
Rong Xia Huang ◽  
Rong Zheng Liu ◽  
He Ping Zhou

(1-x) (K0.475Na0.475Li0.05)(Nb0.975Sb0.025)O3-xmolBiFeO3 (x=0, 0.002, 0.004, 0.006, 0.008) doped with 0.8mol%CuO lead-free piezoelectric ceramics were prepared by the solid state reaction technique. X-ray diffraction patterns suggested that all the ceramics presented perovskite structure. The compositional dependence of the phase structure and the electrical properties of the ceramics were studied. The ceramic (x=0.002) near room temperature exhibited excellent electrical properties (piezoelectric constant d33=172pC/N, planar electromechanical coupling factor kp=0.43, and dielectric constant =418). A relatively high mechanical quality factor (Qm=200) was also obtained in this particular composition. All these results revealed that this system might become a promising candidate for lead-free piezoelectric materials.


2012 ◽  
Vol 512-515 ◽  
pp. 1308-1312 ◽  
Author(s):  
Beata Wodecka-Duś ◽  
Agata Lisińska-Czekaj ◽  
Dionizy Czekaj

Results of fabrication and study of Ba1-xLaxTi1-x/4O3(BLT) ceramics for x within the range 0.001≤x≤0.004 is reported in the present paper. BLT ceramics has a structure based on ABO3–type perovskite, and its properties strongly depend on the chemical comSubscript textposition. The interrelated semiconductor and ferroelectric properties of La-doped BaTiO3ceramics were considered for describing its electrical properties. Dielectric properties were studied in frequency domain by impedance spectroscopy with a Quadtech 1920-type precision LCR meter at room temperature T=RT.


2014 ◽  
Vol 887-888 ◽  
pp. 289-293
Author(s):  
Jing Chang Zhao ◽  
Zhen Lai Zhou

(Na,Bi)TiO3-BaTiO3lead free piezoelectric ceramics were fabricated with modification of CaCu3Ti4O12additives. The phase structure, morphology, dielectric and piezoelectric properties of prepared samples were investigated, respectively. It was found that CaCu3Ti4O12additives evidently improve the polarization properties of (Na,Bi)TiO3-BaTiO3lead free ceramics and the obtained samples exhibit an excellent piezoelectric properties (electromechanical coupling factorKp=31%, mechanical quality factorQm=151 and piezoelectric constantd33=160pC/N). According to results, the effect of CaCu3Ti4O12additives on electrical properties of (Na,Bi)TiO3-BaTiO3lead free piezoelectric ceramics is discussed.


2010 ◽  
Vol 105-106 ◽  
pp. 248-251 ◽  
Author(s):  
Ji Gong Hao ◽  
Zhi Jun Xu ◽  
Rui Qing Chu ◽  
Yan Jie Zhang ◽  
Qian Chen ◽  
...  

Zr-doped Sr2Bi4Ti5O18 (SBTi) bismuth layer-structured ferroelectric ceramics were prepared and studied. XRD patterns revealed that all the ceramic samples were single phase compounds. SEM images showed that dense microstructures with uniform gain size were obtained in all samples. The effects of Zr4+ doping on the dielectric, ferroelectric and piezoelectric properties of SBTi ceramics were also investigated. It was found that Zr4+ dopant gradually decreased the Curie temperature (Tc), enhanced the remnant polarization (2Pr) and decreased the coercive field (Ec) of SBTi ceramics. Furthermore, the piezoelectric properties of the SBTi ceramics were improved by enlarging the content of Zr. The SBTi ceramics with 4 mol% of Zr4+ dopant exhibited good electrical properties: d33 = 21 pC/N, 2Pr = 14.3 μC/cm2, Tc = 251°C, εr = 376, tanδ = 1.8%.


2014 ◽  
Vol 602-603 ◽  
pp. 826-829
Author(s):  
Hong Yun Ma ◽  
Yan Gai Liu ◽  
Jin Qiu Zhao ◽  
Zhao Hui Huang ◽  
Ming Hao Fang

In this paper, the KNN powders with Li+ substituted (K0.5Na0.5)+ were prepared by the sol-gel method in order to make powders pure, (Na0.50+xK0.50-2xLix) -NbO3 (x=0, 0.04, 0.06, 0.08) ceramics were prepared by pressureless sintering. The phase composition of powders was determined by XRD. The effects of the Li+ substitution on piezoelectric and ferroelectric properties of ceramics were systematically studied for determining optimal Li+ content. Li+ can significantly increase the piezoelectric constant of ceramic. When Li+ content was 0.04, piezoelectric properties of ceramics were the best, d33=115 pC/N, Pr=6.35 μC/cm2, Ec=14.24 kV/cm.


Sign in / Sign up

Export Citation Format

Share Document