The Synergetic Effect of MoSO2/Graphite Nanosheets as Highly Efficient for Electrochemical Water Splitting in Acidic Media

2021 ◽  
Vol 13 (8) ◽  
pp. 1574-1583
Author(s):  
Abdul Qayoom Mugheri ◽  
Muhammad Soomar Samtio ◽  
Shahzad Ahmed Memon ◽  
Hassan Fouad ◽  
Sukumaran Anil ◽  
...  

Metal oxide nanoarchitectures have a wide range of qualities that can be used to produce novel technologies in the field of renewable energy, such as energy conversion solar fuels and storage via the photovoltaic effect, and electrochemical water splitting. The approach for the synthesis of earth abundant metal oxide nanostructures is facile and cost effective and involves scalable methodologies for the development of functional devices. The composite material exhibits enhanced active edge sites for the potential HER. The electrochemical experiments revealed satisfactory results of electrocatalytic gas production HER. The composite sample produces a current density at 10 mAcm−2 an over potential of 345 mV and Tafel value of 60 mVdec−1 it exhibits at which predominantly ensures the swift charge transfer kinetics during HER. The sample 3 remains durable and stable for 30 hours. EIS shown value of 21.88 Ohms as charge transfer resistance which further strengthened HER and Tafel results. The sample 3 exhibits a 4.69 µFcm−2 capacitance double layer and surface area of 177.25 cm2 it further supports the unique productivity for HER activity. The small Tafel slope which relatively close to Pt shows a clear and high potential of as prepared MoS2/Graphite nanosheets composite material for the replacement of noble metals in the field of renewable energy. The tiny Tafel slope value suggests that the efficient hydrogen evolution reaction has a lot of promise. This developed method provides the alternative method for the development of other materials for the energy harvesting applications.

2021 ◽  
Author(s):  
Duanduan Liu ◽  
Wei Wei ◽  
Maidina Mahemu ◽  
Hao Qin ◽  
Kai Zhu ◽  
...  

The solid-state redox couple is a vital charge transfer medium for electrochemical water splitting.


2021 ◽  
Author(s):  
Yun-Wu Li ◽  
Shi-Kun Su ◽  
Cai-Zhen Yue ◽  
Jun Shu ◽  
Pengfang Zhang ◽  
...  

Electrochemical water splitting is convinced as one of the most promising solutions to combat energy crisis. The exploitation of efficient hydrogen and oxygen evolution reactions (HER/OER) bifunctional electrocatalysts is undoubtedly...


2021 ◽  
Vol MA2021-01 (39) ◽  
pp. 1251-1251
Author(s):  
Gerko Oskam ◽  
Ingrid Rodriguez Gutierrez ◽  
Manuel Rodríguez Pérez ◽  
Alberto Vega Poot ◽  
Geonel Rodriguez Gattorno ◽  
...  

2017 ◽  
Vol 46 (38) ◽  
pp. 12811-12823 ◽  
Author(s):  
Christoph Haisch ◽  
Jenny Schneider ◽  
Manuel Fleisch ◽  
Henning Gutzmann ◽  
Thomas Klassen ◽  
...  

Films prepared by cold spray have potential applications as photoanodes in electrochemical water splitting and waste water purification.


2021 ◽  
Author(s):  
Balaji Ramachandran ◽  
Narendhar Chandrasekar ◽  
Pinky Steffi Alexander ◽  
Prakash Natarajan

Nanoscale ◽  
2021 ◽  
Author(s):  
Yiming Xu ◽  
Kaicai Fan ◽  
Huai Qin Fu ◽  
Yu Zou ◽  
Mengyang Dong ◽  
...  

Electrocatalytic energy conversion between electricity and chemical bonding energy is realized through redox reactions with multiple charge transfer steps at the electrode-electrolyte interface. The surface atomic structure of the electrode...


2020 ◽  
Vol 2020 ◽  
pp. 1-14
Author(s):  
Buzuayehu Abebe ◽  
H. C. Ananda Murthy ◽  
Enyew Amare Zereffa ◽  
You Qiang

The poly(vinyl alcohol)-assisted sol-gel-self-propagation route has been used for the synthesis of porous binary metal oxide nanocomposites (BMONCs) and ternary metal oxide nanocomposites (TMONCs). The effects of synthesis techniques, precursor’s type, amount of PVA loading, and precursor’s percentage were studied. The optical, chemical bonding, crystallinity, morphological, textural, and electrochemical properties of the synthesized materials were characterized by UV-vis-DRS/UV-vis, FT-IR, XRD, SEM/EDX and TEM/HRTEM/SAED, BET, and CV/EIS techniques, respectively. The porous nature of the materials was confirmed by SEM, BET, and SAED analytical techniques. Using XRD and TEM analysis, the approximate particle size of the materials was confirmed to be in the nanometer range (~7-70 nm). The EDX and HRTEM analysis was confirming the presence of predictable composition and actuality of the composites, respectively. Moving from bare ZnO to ternary nanocomposites, the great morphological, surface area, and electrochemical property enhancement was confirmed. The charge transfer capability order was obtained to be ZnO/Fe2O3/Mn2O3 > ZnO/Fe2O3 > ZnO/Mn2O3 > ZnO. The respective approximate electron transfer resistance value is 7, 25, 61, and 65 Ω. Therefore, this work can improve the toxicity towards solvent used, surface area to volume ratio, and aggregation/agglomeration problem and also enhance the charge transfer capability due to the heterojunction.


2013 ◽  
Vol 15 (33) ◽  
pp. 13737 ◽  
Author(s):  
Richard L. Doyle ◽  
Ian J. Godwin ◽  
Michael P. Brandon ◽  
Michael E. G. Lyons

Sign in / Sign up

Export Citation Format

Share Document