Thermal properties of nano-graphite-embedded magnesium chloride hexahydrate phase change composites

2017 ◽  
Vol 28 (7) ◽  
pp. 651-660 ◽  
Author(s):  
Apurv Yadav ◽  
Bidyut Barman ◽  
Abhishek Kardam ◽  
S Shankara Narayanan ◽  
Abhishek Verma ◽  
...  

Phase change materials can provide large heat storage density with low volume. But their low thermal conductivity limits their heat transfer capabilities. Since carbonaceous nanoparticles have a good thermal conductivity they can be applied as an additive to phase change materials to increase their heat transfer rate. In this study, nano-graphite is used as an additive and the influences of its various concentrations on the thermal conductivity and melting and freezing rate for the nanoparticle-enhanced phase change materials is experimentally investigated. Experimental results indicates a reduction of 22% in melting time and a reduction of 75% in solidification time of 0.5% nano-graphite-embedded phase change material.

2013 ◽  
Vol 860-863 ◽  
pp. 862-866 ◽  
Author(s):  
Yi Fei Zheng ◽  
Zhong Zhu Qiu ◽  
Jie Chen

Phase change materials in the form of emulsion (PCE) is a category of novel phase change fluid used as heat storage and transfer media. It plays an important role in commercially viable applications (energy storage, particularly).The emulsion is made of microparticles of a phase change wax (a kind of paraffin or mixture ) as a phase change material (PCM), mixed paraffin directly with water. This paper presents information on the different PCM emulsions by different researchers. It gives the method of preparation of the PCE, and makes a special effort to investigate the heat transfer phenomena and the method of enhancing the thermal conductivity of the emulsion.


Author(s):  
D. Zhou ◽  
C. Y. Zhao

Phase change materials (PCMs) have been widely used for thermal energy storage systems due to their capability of storing and releasing large amounts of energy with a small volume and a moderate temperature variation. Most PCMs suffer the common problem of low thermal conductivity, being around 0.2 and 0.5 for paraffin and inorganic salts, respectively, which prolongs the charging and discharging period. In an attempt to improve the thermal conductivity of phase change materials, the graphite or metallic matrix is often embedded within PCMs to enhance the heat transfer. This paper presents an experimental study on heat transfer characteristics of PCMs embedded with open-celled metal foams. In this study both paraffin wax and calcium chloride hexahydrate are employed as the heat storage media. The transient heat transfer behavior is measured. Compared to the results of pure PCMs samples, the investigation shows that the additions of metal foams can double the overall heat transfer rate during the melting process. The results of calcium chloride hexahydrate are also compared with those of paraffin wax.


1984 ◽  
Vol 106 (1) ◽  
pp. 106-111 ◽  
Author(s):  
D. Dietz

The thermal performance of an air-heated/cooled, phase-change, heat stoage module was tested and evaluated. The module (rated at 38.7 kWh) consist of 130 vertically oriented tubes filled with 729 kg (1607 lb) of calcium chloride hexahydrate and enclosed in a rectangular box. Heat transfer rates measured during charging and discharging decreased with time as a result of decreasing effective heat transfer area and increasing thermal resistance of the phase-change material. These two dominant effects are included in a proposed mathematical model that predicted the experimental data.


2019 ◽  
Vol 141 (5) ◽  
Author(s):  
S. Arunachalam

Energy storage helps in waste management, environmental protection, saving of fossil fuels, cost effectiveness, and sustainable growth. Phase change material (PCM) is a substance which undergoes simultaneous melting and solidification at certain temperature and pressure and can thereby absorb and release thermal energy. Phase change materials are also called thermal batteries which have the ability to store large amount of heat at fixed temperature. Effective integration of the latent heat thermal energy storage system with solar thermal collectors depends on heat storage materials and heat exchangers. The practical limitation of the latent heat thermal energy system for successful implementation in various applications is mainly from its low thermal conductivity. Low thermal conductivity leads to low heat transfer coefficient, and thereby, the phase change process is prolonged which signifies the requirement of heat transfer enhancement techniques. Typically, for salt hydrates and organic PCMs, the thermal conductivity range varies between 0.4–0.7 W/m K and 0.15–0.3 W/m K which increases the thermal resistance within phase change materials during operation, seriously affecting efficiency and thermal response. This paper reviews the different geometry of commercial heat exchangers that can be used to address the problem of low thermal conductivity, like use of fins, additives with high thermal conductivity materials like metal strips, microencapsulated PCM, composite PCM, porous metals, porous metal foam matrix, carbon nanofibers and nanotubes, etc. Finally, different solar thermal applications and potential PCMs for low-temperature thermal energy storage were also discussed.


Author(s):  
Yannan Liang ◽  
Jiemin Zhou ◽  
Ying Yang ◽  
Ye Wu ◽  
Yanyan He

The use of phase-change materials for latent heat storage is a new type of environmentally-friendly energy-saving technologies. Molten salts, one kind of phase-change materials, which have high latent heats, and whose phase transition temperatures match the high temperatures of heat engines, are the most widely used high-temperature phase-change heat storage materials. However, the heat transfer at solid/liquid phase interface belongs to Micro/Nanoscale Heat transfer, lots of the thermal properties of molten salt at melting point is difficult to test. In this investigation, based on the theory that the thermal conductivity can be determined by measuring the speed of the propagation of the solid/liquid phase interface during phase change, a set of system is developed to investigate the thermal conductivity of molten salts at liquid/solid phase transformation point. Meanwhile, mathematical calculation is applied to intuitively simulate the melting and solidifying process in the phase change chamber, by which the error could be analyzed and partly corrected and the result precision could also be increased. And a series of verification experiments have been performed to estimate the precision and the applicability of the measuring system to evaluate the feasibility of the method and measuring system. This research will pave the way to the follow-on research on heat storage at high temperature in industry.


2016 ◽  
Vol 20 (5) ◽  
pp. 1533-1541 ◽  
Author(s):  
Jamalabadi Abdollahzadeh ◽  
Jae Park

Enhancement of thermal and heat transfer capabilities of phase change materials with addition of nanoparticles is reported. The mixed nanofluid of phase change material and nanoparticles presents a high thermal conductivity and low heat capacity and latent heat, in comparison with the base fluid. In order to present the thermophysical effects of nanoparticles, a solidification of nanofluid in a rectangular enclosure with natural convection induced by different wall temperatures is considered. The results show that the balance between the solidification acceleration by nanoparticles and slowing-down by phase change material gives rise to control the medium temperature. It indicates that this kind of mixture has great potential in various applications which requires temperature regulation. Also, the Brownian motion of nanoparticles enhances the convective heat transfer much more than the conductive transfer.


2012 ◽  
Vol 614-615 ◽  
pp. 286-290
Author(s):  
Xu Liang Gao ◽  
Li Yang

The article presents a new kind of shell and tube phase change heat storage exchanger using vertical fins. And select paraffin as phase change materials, Fluent6.3 software was used to study the melting process. Some conditions of different fin height, different fin width and different fin numbers of axial direction were investigated. The results show that the higher and the wider of the fins, and the more the fin number of axial direction, the shorter is the melting time, the better is the effect of heat transfer


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