The Experimental Research and Numerical Simulation on Thermal Properties of Molten Salt at Melting Point

2009 ◽  
Author(s):  
Yannan Liang ◽  
Jiemin Zhou ◽  
Ying Yang ◽  
Ye Wu ◽  
Yanyan He
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Thermal Properties ◽  
Phase Change ◽  
Molten Salts ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Phase Interface ◽  
Measuring System ◽  
Solid Liquid

The use of phase-change materials for latent heat storage is a new type of environmentally-friendly energy-saving technologies. Molten salts, one kind of phase-change materials, which have high latent heats, and whose phase transition temperatures match the high temperatures of heat engines, are the most widely used high-temperature phase-change heat storage materials. However, the heat transfer at solid/liquid phase interface belongs to Micro/Nanoscale Heat transfer, lots of the thermal properties of molten salt at melting point is difficult to test. In this investigation, based on the theory that the thermal conductivity can be determined by measuring the speed of the propagation of the solid/liquid phase interface during phase change, a set of system is developed to investigate the thermal conductivity of molten salts at liquid/solid phase transformation point. Meanwhile, mathematical calculation is applied to intuitively simulate the melting and solidifying process in the phase change chamber, by which the error could be analyzed and partly corrected and the result precision could also be increased. And a series of verification experiments have been performed to estimate the precision and the applicability of the measuring system to evaluate the feasibility of the method and measuring system. This research will pave the way to the follow-on research on heat storage at high temperature in industry.

Latent Heat Storage: Container Geometry, Enhancement Techniques, and Applications—A Review

2019 ◽  
Vol 141 (5) ◽  
Author(s):  
S. Arunachalam
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Energy Storage ◽  
Phase Change ◽  
Latent Heat ◽  
Thermal Energy ◽  
Heat Exchangers ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Low Thermal Conductivity

Energy storage helps in waste management, environmental protection, saving of fossil fuels, cost effectiveness, and sustainable growth. Phase change material (PCM) is a substance which undergoes simultaneous melting and solidification at certain temperature and pressure and can thereby absorb and release thermal energy. Phase change materials are also called thermal batteries which have the ability to store large amount of heat at fixed temperature. Effective integration of the latent heat thermal energy storage system with solar thermal collectors depends on heat storage materials and heat exchangers. The practical limitation of the latent heat thermal energy system for successful implementation in various applications is mainly from its low thermal conductivity. Low thermal conductivity leads to low heat transfer coefficient, and thereby, the phase change process is prolonged which signifies the requirement of heat transfer enhancement techniques. Typically, for salt hydrates and organic PCMs, the thermal conductivity range varies between 0.4–0.7 W/m K and 0.15–0.3 W/m K which increases the thermal resistance within phase change materials during operation, seriously affecting efficiency and thermal response. This paper reviews the different geometry of commercial heat exchangers that can be used to address the problem of low thermal conductivity, like use of fins, additives with high thermal conductivity materials like metal strips, microencapsulated PCM, composite PCM, porous metals, porous metal foam matrix, carbon nanofibers and nanotubes, etc. Finally, different solar thermal applications and potential PCMs for low-temperature thermal energy storage were also discussed.

The Investigation of Phase Change Emulsion (PCE): Fabrication, Thermal Conductivity and Utilization of Nanoparticles

2013 ◽  
Vol 860-863 ◽  
pp. 862-866 ◽  
Author(s):  
Yi Fei Zheng ◽  
Zhong Zhu Qiu ◽  
Jie Chen
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Energy Storage ◽  
Phase Change ◽  
Phase Change Material ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Change Material

Phase change materials in the form of emulsion (PCE) is a category of novel phase change fluid used as heat storage and transfer media. It plays an important role in commercially viable applications (energy storage, particularly).The emulsion is made of microparticles of a phase change wax (a kind of paraffin or mixture ) as a phase change material (PCM), mixed paraffin directly with water. This paper presents information on the different PCM emulsions by different researchers. It gives the method of preparation of the PCE, and makes a special effort to investigate the heat transfer phenomena and the method of enhancing the thermal conductivity of the emulsion.

Thermal properties of nano-graphite-embedded magnesium chloride hexahydrate phase change composites

2017 ◽  
Vol 28 (7) ◽  
pp. 651-660 ◽  
Author(s):  
Apurv Yadav ◽  
Bidyut Barman ◽  
Abhishek Kardam ◽  
S Shankara Narayanan ◽  
Abhishek Verma ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Phase Change ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Melting Time ◽  
Chloride Hexahydrate ◽  
Large Heat ◽  
Phase Change Composites ◽  
Change Material

Phase change materials can provide large heat storage density with low volume. But their low thermal conductivity limits their heat transfer capabilities. Since carbonaceous nanoparticles have a good thermal conductivity they can be applied as an additive to phase change materials to increase their heat transfer rate. In this study, nano-graphite is used as an additive and the influences of its various concentrations on the thermal conductivity and melting and freezing rate for the nanoparticle-enhanced phase change materials is experimentally investigated. Experimental results indicates a reduction of 22% in melting time and a reduction of 75% in solidification time of 0.5% nano-graphite-embedded phase change material.

Thermal Conductivity Enhancement in a Latent Heat Storage Device

2013 ◽  
Vol 860-863 ◽  
pp. 590-593
Author(s):  
Cha Xiu Guo ◽  
Ding Bao Wang ◽  
Gao Lin Hu
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Solid State ◽  
Liquid Phase ◽  
Phase Change ◽  
Latent Heat ◽  
Heat Storage ◽  
Storage Device ◽  
Latent Heat Storage ◽  
Conductivity Enhancement

High conductivity porosity materials are proposed to enhance the phase change materials (PCM) in order to solve the problem of low conductivity of PCM in the latent heat storage device (LHSD), and two-dimensional numerical simulation is conducted to predict the performance of the PCM by CFD software. During the phase change process, the PCM is heated from the solid state to the liquid phase in the process of melting and from the liquid phase to the solid state in the solidification process. The results show that porosity materials can improve heat transfer rate effectively, but the effect of heat transfer of Al foam is superior to that of graphite foam although the heat storage capacity is almost the same for both. The heat transfer is enhanced and the solidification time of PCM is decreased since the effective thermal conductivity of composite PCM is increased.

Solid/Liquid Phase Change Heat Transfer in Latent Heat Thermal Energy Storage

2009 ◽  
Author(s):  
D. Zhou ◽  
C. Y. Zhao
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Energy Storage ◽  
Phase Change ◽  
Calcium Chloride ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Phase Change Materials ◽  
Metal Foams ◽  
Chloride Hexahydrate

Phase change materials (PCMs) have been widely used for thermal energy storage systems due to their capability of storing and releasing large amounts of energy with a small volume and a moderate temperature variation. Most PCMs suffer the common problem of low thermal conductivity, being around 0.2 and 0.5 for paraffin and inorganic salts, respectively, which prolongs the charging and discharging period. In an attempt to improve the thermal conductivity of phase change materials, the graphite or metallic matrix is often embedded within PCMs to enhance the heat transfer. This paper presents an experimental study on heat transfer characteristics of PCMs embedded with open-celled metal foams. In this study both paraffin wax and calcium chloride hexahydrate are employed as the heat storage media. The transient heat transfer behavior is measured. Compared to the results of pure PCMs samples, the investigation shows that the additions of metal foams can double the overall heat transfer rate during the melting process. The results of calcium chloride hexahydrate are also compared with those of paraffin wax.

Effectiveness of heat protection of fabrics loaded with phase change materials

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Elham Fallahi ◽  
Mohammad Barmar ◽  
Mohammad Haghighat Kish
Keyword(s):  
Heat Transfer ◽  
Fourier Transform ◽  
Thermal Properties ◽  
Phase Change ◽  
Phase Change Materials ◽  
Chemical Nature ◽  
Woven Fabrics ◽  
Temperature Changes ◽  
Heat Protection ◽  
Exponential Relation

AbstractAmong different natural and non-corrosive products paraffin wax and camel fat are selected as phase change materials (PCM). These PCMs are applied to glass, polyester/viscose and wool/polyester woven fabrics. To examine their efficacy, their thermal behavior in a condition similar to the actual end uses is measured. Chemical nature and thermal properties of the PCMs are measured by Fourier transform infrared spectroscope and differential scanning calorimeter. A relation based on the principle of heat transfer is used to determine the temperature of a thermometer covered by fabrics loaded with PCMs. A simple exponential relation explains the experimental results. For glass and polyester/viscose fabrics use of these PCMs leads to substantial delays in the temperature changes. The important parameters for the evaluation of the products are discussed.

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