Effect of used motor oil as a rejuvenator on crumb rubber modifier’s released components to asphalt binder

Author(s):  
Eslam Deef-Allah ◽  
Magdy Abdelrahman

Asphalt binder modification by crumb rubber modifier (CRM) could enhance its rheological properties at high and intermediate temperatures by increasing its stiffness and elasticity. To obtain a modified binder blend with more enhanced intermediate- and low-temperature rheological properties, used motor oil (UMO) was introduced to the crumb rubber-modified asphalt (CRMA) binder. The enhanced high- and intermediate-temperature rheological properties of the modified binders were investigated using a temperature sweep test. UMO, used as a rejuvenator, can regulate the CRM role in the modified binder blend by creating a balance between the binder’s enhanced stiffness and fluidity. This was achieved by increasing |G*|/sin δ at high temperatures and decreasing |G*|.sin δ at intermediate temperatures. The mutual components between the CRM and the asphalt binder were explored by thermogravimetric analysis and Fourier transform infrared (FTIR) spectroscopy. UMO was found to have similar FTIR bands of the asphalt binder that helped the CRM particles to absorb more low-molecular-weight fractions at the beginning of the interaction time, which caused them to swell more and then dissolve, releasing their polymeric components in the asphalt binder’s liquid phase. Adding UMO with two and half percentage by the weight of the neat asphalt binder to the CRMA binder, interacted at 190°C–50 Hz–60 min, could increase the CRM dissolution and cause a greater release of CRM polymeric components into the asphalt binder matrix. This was assured by the presence of FTIR peaks at 911 and 966 cm−1 that are related to the polybutadiene, synthetic rubber in CRM.

2019 ◽  
Vol 8 (4) ◽  
pp. 5501-5508

The crumb rubber modifier (CRM) particles release polymeric fractions in the matrix of the asphalt binder, which increase the asphalt binder’s fatigue and rutting resistance. The used motor oil (UMO) compensates the asphalt binder for the low-molecular-weight components lost during the aging processes. Moreover, UMO could increase the asphalt binder’s fluidity and softness. Therefore, modification of the asphalt binder by CRM in combination with UMO could enhance the asphalt binder’s performance. In this paper, the asphalt binder was modified by CRM. Then, the UMO was added to the crumb rubber modified asphalt (CRMA). The neat asphalt, CRMA, and UMO–CRMA binders’ resistance to rutting and fatigue cracking was evaluated. Temperature sweep test was used to evaluate the neat and modified asphalt binders’ resistance to rutting and fatigue cracking by measuring |G*|/sinδ and |G*|.sinδ parameters, respectively. Linear amplitude sweep (LAS) test was used to analyze the neat and modified asphalt binders’ resistance to fatigue cracking by measuring the number of load repetitions to failure (Nf ). It was found that using CRM and UMO enhanced the asphalt binder’s resistance to rutting and fatigue cracking. Therefore, UMO succeeded as a rejuvenator to balance the CRMA binder’s performance. This had occurred by creating a balance between the enhanced properties at high, intermediate, and low temperatures. Interaction temperature plays a dominant role in enhancing the asphalt binder’s performance: the enhancement in rutting and fatigue cracking parameters reached the highest values for CRMA or UMO–CRMA samples interacted at 190°C interaction temperature. At 220°C interaction temperature, these enhancements had decreased due to the devulcanization and depolymerization processes of the polymeric components released in the asphalt binder’s matrix.


Recycling ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 11 ◽  
Author(s):  
Eslam Deef-Allah ◽  
Magdy Abdelrahman ◽  
Mark Fitch ◽  
Mohyeldin Ragab ◽  
Mousumi Bose ◽  
...  

Road deterioration inspires researchers to enhance the properties of asphalt binder for better performing mixes. Recycled tire rubber, or crumb rubber modifier (CRM), and used motor oil (UMO) are two modifiers that enhance asphalt binder performance through two different mechanisms. CRM affects high-temperature properties while UMO modifies low-temperature properties. Potential environmental concerns arising from the use of UMO have been raised in the literature. In this paper, the two recycled materials were investigated for their ability to complement each other. Both performance benefits of using both materials and the environmental concerns of using UMO were studied. Four CRM asphalt binders were investigated: two with UMO and two without UMO. Environmental impacts were evaluated using gas chromatography to check air emissions for benzene, toluene, ethyl-benzene, and xylenes (BTEX). The potential for toxic leaching of elements from modified hot mix asphalt (HMA) were checked using the US Environmental Protection Agency (EPA) Toxicity Characteristic Leaching Protocol (TCLP). For asphalt binders modified by CRM-UMO combinations, CRM decreased the amounts of released BTEX components, presumably by absorbing UMO and slowing the release of BTEX. Leaching results concluded that UMO mixtures showed a notable percentage of sulfur (S) as compared to non-UMO mixes. All these leachate components were under EPA limits.


2016 ◽  
Vol 78 (7-3) ◽  
Author(s):  
Rosnawati Buhari ◽  
Nur Fareesya Zabidi ◽  
Mohd Ezree Abdullah ◽  
Siti Khatijah Abu Bakar ◽  
Nurul Hidayah Mohd Kamarudin

The objectives of this study were to determine the blending parameters of coconut shell powder (CSP) modified asphalt binder and to evaluate the rheological properties of CSP modified asphalt binder. CSP of 2%, 4%, 6%, 8% and 10% by weight of asphalt have been incorporated into an unaged 80/100 asphalt mix in order to improve its performance. The influence of the additives on the physical and rheological properties was evaluated with penetration test, softening point, storage stability, dynamic shear rheometer test (DSR), and Field Emission Scanning Electron Microscope (FESEM). The aging of asphalt binders was simulated in a laboratory by using Rotational Thin Film Oven (RTFO). The results showed that the addition of CSP into virgin binder was decreasing the penetration value and increasing the softening point temperature compared to the original binder. On the rheological effect, for unaged modified binder, higher CSP resulted higher G*/sin δ especially at lower temperature compared to the unaged control binder. Besides, for the aged modified binder, stiffness was lower than the control aged binder for all temperature.


2015 ◽  
Vol 76 (9) ◽  
Author(s):  
E. Shaffie ◽  
J. Ahmad ◽  
A. K. Arshad ◽  
D. Kamarun

In this paper, the effects of nanopolyacrylate (NP) in binder modification on the empirical and rheological characteristics of the conventional binder were explored. The empirical and rheological binder properties were characterized using penetration, softening point, viscosity and dynamic shear rheometer (DSR) respectively.  These testings have become useful methods in characterizing of the binder performance on the pavement. The results indicated that NP polymer modification improved the physical properties of the conventional binder such as; penetration, softening point and temperature susceptibility. The results of viscosity test show that the NP polymer modified binder is more viscous than unmodified binder where viscosity increases with the increment of polymer content. The DSR results indicate that the NP polymer improves rheological properties of conventional binder, i.e. increasing the complex shear modulus (G∗) values and rutting parameters (G∗/sin δ), as well as decreasing the phase angle (δ) values. Therefore, it can be concluded that NP polymers considerably improves elastic properties and rutting resistance of binder and thus could be used for enhancing the asphalt pavement performance.


Environments ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 47
Author(s):  
Lim Min Khiong ◽  
Md. Safiuddin ◽  
Mohammad Abdul Mannan ◽  
Resdiansyah

This paper presents the results of a laboratory-based experimental investigation on the properties of asphalt binder and hot-mix asphalt (HMA) mixes modified by locally available crumb rubber, which was used as a partial replacement of asphalt by weight. In this study, fine crumb rubber with a particle size in the range of 0.3–0.6 mm, obtained from scrap tires, was added to the asphalt binder through the wet process. Crumb rubber contents of 5%, 10%, 15%, and 19% by weight of asphalt were added to the virgin binder in order to prepare the modified asphalt binder samples, while the unmodified asphalt binder was used as the control sample. The crumb rubber modified binder samples were examined for measuring viscosity indirectly using the penetration test, and temperature resistance using the softening point test. Later, both the modified and unmodified asphalt binders were used to produce HMA mixes. Two categories of HMA mix commonly used in Malaysia—namely, AC 14 (dense-graded) and SMA 14 (gap-graded)—were produced using the modified asphalt binders containing 5%, 10%, 15%, and 19% crumb rubber. Two AC 14 and SMA 14 control mixes were also produced, incorporating the unmodified asphalt binder (0% crumb rubber). All of the AC 14 and SMA 14 asphalt mixes were examined in order to determine their volumetric properties, such as bulk density, voids in total mix (VTM), voids in mineral aggregate (VMA), and voids filled with asphalt (VFA). In addition, the Marshall stability, Marshall flow, and stiffness of all of the AC 14 and SMA 14 mixes were determined. Test results indicated that the modified asphalt binders possessed higher viscosity and temperature resistance than the unmodified asphalt binder. The viscosity and temperature resistance of the asphalt binders increased with the increase in their crumb rubber content. The increased crumb rubber content also led to improvements in the volumetric properties (bulk density, VTM, VMA, and VFA) of the AC 14 and SMA 14 mixes. In addition, the performance characteristics of the AC 14 and SMA 14 mixes—such as Marshall stability, Marshall flow, and stiffness—increased with the increase in crumb rubber content. However, the AC 14 mixes performed much better than the SMA 14 mixes. The overall research findings suggest that crumb rubber can be used to produce durable and sustainable HMA mixes, with manifold environmental benefits, for use in flexible pavements carrying the heavy traffic load of highways.


2012 ◽  
Vol 193-194 ◽  
pp. 452-457 ◽  
Author(s):  
Meng Yun Huang ◽  
Jing Hui Liu ◽  
Xi Zhang ◽  
Dan Ni Li

Using the waste crumb rubber modified asphalt to pave the road surface could reduce cost and save energy. However,in order to obtain adequate workability, the mixing temperature and compaction temperature of rubberized asphalt binder and its mixture is much higher than those of conventional asphalt mixtures. Warm Mix Asphalt (WMA) is the name given to certain technologies that reduce the production and placement temperatures of asphalt mixes. One of the main benefits advertised is the increased workability at conventional and lower compaction temperatures with the WMA addition. This paper evaluates whether there are any synergy effects of using warm mix technologies and Asphalt Rubber(AR) hot mixes. This paper summarizes a lab research to evaluate the workability of Asphalt Rubber hot mixes containing warm mix technologies. Both asphalt binder and asphalt mixture were evaluated and compared. The research suggests that combining WMA technology with Asphalt Rubber mixtures is a win-win.


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