Properties of co-extruded nanoclay-filled aliphatic nylon (PA6)/linear low-density polyethylene and aromatic nylon (MXD6)/ linear low-density polyethylene multilayer films

2014 ◽  
Vol 31 (1) ◽  
pp. 45-77 ◽  
Author(s):  
Maryam Fereydoon ◽  
Seyed H Tabatabaei ◽  
Abdellah Ajji
2003 ◽  
Vol 57 (1) ◽  
pp. 37-43 ◽  
Author(s):  
Shilpa Y. Sankhe ◽  
Douglas E. Hirt

The diffusion of additives in thick (∼500 μm) single layer and multilayer films has been characterized using FT-IR microspectroscopy.1,2 The objective of this research was to investigate additive migration and concentration profiles in coextruded multilayer films of industrially relevant thicknesses. In particular, the investigation focused on the migration of an erucamide slip agent in 50-μm-thick coextruded bilayer films of linear low-density polyethylene (LLDPE) and a polyolefin plastomer (POP). Erucamide concentration profiles were successfully mapped using synchrotron-based FT-IR microspectroscopy. The synchrotron radiation helped to achieve a higher spatial resolution for the thin films. Meticulous sample preparation was needed to map the thin film samples. Results with FT-IR microspectroscopy showed that the additive-concentration profiles were relatively uniform across the multilayer-film thickness irrespective of the intended initial additive distribution. For example, a bilayer planned for 1 wt % erucamide in an LLDPE layer and no erucamide in a POP layer showed significant additive migration into the POP layer at the extrusion rates used. FT-IR microspectroscopy results also showed that more erucamide migrated to the surface of a POP layer than an LLDPE layer. Attenuated total reflectance (ATR) FT-IR spectroscopy was used to confirm the time-dependent increase of erucamide surface concentration and that the increase was more pronounced at the surface of the POP layers.


1998 ◽  
Vol 38 (1) ◽  
pp. 150-155 ◽  
Author(s):  
S. Sánchez-Valdes ◽  
F. Orona-Villarreal ◽  
M. Lopez-Quintanilla ◽  
I. Yañez-Flores ◽  
L. F. Ramos De Valle ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1537
Author(s):  
Luděk Hynčík ◽  
Petra Kochová ◽  
Jan Špička ◽  
Tomasz Bońkowski ◽  
Robert Cimrman ◽  
...  

Current industrial trends bring new challenges in energy absorbing systems. Polymer materials as the traditional packaging materials seem to be promising due to their low weight, structure, and production price. Based on the review, the linear low-density polyethylene (LLDPE) material was identified as the most promising material for absorbing impact energy. The current paper addresses the identification of the material parameters and the development of a constitutive material model to be used in future designs by virtual prototyping. The paper deals with the experimental measurement of the stress-strain relations of linear low-density polyethylene under static and dynamic loading. The quasi-static measurement was realized in two perpendicular principal directions and was supplemented by a test measurement in the 45° direction, i.e., exactly between the principal directions. The quasi-static stress-strain curves were analyzed as an initial step for dynamic strain rate-dependent material behavior. The dynamic response was tested in a drop tower using a spherical impactor hitting a flat material multi-layered specimen at two different energy levels. The strain rate-dependent material model was identified by optimizing the static material response obtained in the dynamic experiments. The material model was validated by the virtual reconstruction of the experiments and by comparing the numerical results to the experimental ones.


2015 ◽  
Vol 37 (11) ◽  
pp. 3167-3174 ◽  
Author(s):  
S. Sánchez-Valdes ◽  
E. Ramírez-Vargas ◽  
L.F. Ramos de Valle ◽  
J.G. Martinez-Colunga ◽  
J. Romero-Garcia ◽  
...  

1988 ◽  
Vol 27 (2) ◽  
pp. 172-178 ◽  
Author(s):  
S. Ottani ◽  
A. Valenza ◽  
F. P. La Mantia

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